Gel plugging material and preparation method thereof

A plugging material and gel technology, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve problems such as endangering construction safety and personnel life, affecting water injection development effect, poor construction effect, etc., to achieve plugging Strong adaptability, excellent plugging effect, and the effect of avoiding broken failure

Active Publication Date: 2021-03-12
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to many geological and engineering factors, as well as long-term scour after water injection, coupled with clay expansion, particle migration and sand production in oil and gas wells, the pore structure of oil and gas reservoirs has changed greatly, and the physical properties of reservoirs have also changed. High-permeability zones or large pores are gradually formed in connected thick oil and gas layers, and even a dominant channel for channeling of injected water will be formed in the later stage, causing a large amount of injected water to circulate ineffectively along the high-permeability zone, seriously affecting the water injection development effect, resulting in only Decreased efficiency, poor construction effect, etc., which may even lead to major accidents such as blowouts that endanger construction safety and personnel lives

Method used

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  • Gel plugging material and preparation method thereof
  • Gel plugging material and preparation method thereof
  • Gel plugging material and preparation method thereof

Examples

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preparation example Construction

[0034] figure 1 Flowchart for the preparation method of gel sealing material of the present invention, such as figure 1 As shown, the preparation method of the gel seal material of the present invention includes the following steps:

[0035] S101: Non ion-type water-soluble monomer, ionic water-soluble monomer, hydrophobic monomer, function monomer, to obtain a monomer mixture;

[0036] Specifically, the nonionic water-soluble monomer is selected from one or more of acrylamide, N, N-dimethylacrylamide and methacrylamide. When a nonionic water soluble monomer is selected from one or more of the above substances, the present invention does not limit the ratio of each substance.

[0037] Ion-type water-soluble monomers include anionic water-soluble monomers and cationic water-soluble monomers, wherein the anionic water-soluble monomer is selected from the group consisting of acrylic acid, methacrylic acid and 2-acrylamide-2-methylpropulfonic acid. One or more of them;

[0038] Cat...

Embodiment 1

[0075] The preparation method of the gel sealing material of the present embodiment includes the following steps:

[0076] 1) Preparation of monomer mixed liquid

[0077] The nonionic water-soluble monomer, ion-type water-soluble monomer, hydrophobic monomer, functional monomer is added to water to obtain a monomer mixture;

[0078] Among them, the nonionic water soluble monomer is acrylamide;

[0079] Anionic water soluble monomer is acrylic acid;

[0080] Cationic water-soluble monomers are acryloyloxyethyltrimethyl ammonium chloride;

[0081] The hydrophobic monomer is hexholide;

[0082] Functional monomer is allyl amine;

[0083] Non ion-type water-soluble monomers, ionic water-soluble monomers, hydrophobic monomers of 30: 10: 0.2;

[0084] The molar ratio of the anionic water-soluble monomer and the cationic water soluble monomer is 1: 1;

[0085] The functional monomer is 5% of the total mass of the nonionic water soluble monomer, ionic water soluble monomer, and the total ...

Embodiment 2

[0098] The preparation method of the gel sealing material of the present embodiment is the same as step 1) in Embodiment 1, and step 3) is different, and step 3) specifically:

[0099] 3) Preparation of gel blockage materials

[0100] Select 7% of the gel base fluid in Example 1 was used as the preparation of gel blockage materials;

[0101]The crosslinking agent was added to a gel base solution to a mass fraction of 7%, and after stirring, the pH value was adjusted to 5, and the gel blockage material of the present embodiment was allowed to obtain a gel blockage material of the present embodiment.

[0102] Among them, the crosslinking agent is chromium sulfate, and the mass of the crosslinking agent is 0.14% of the mass of the gel base.

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Abstract

The invention provides a gel plugging material and a preparation method thereof. The preparation method comprises the following steps: adding a non-ionic water-soluble monomer, an ionic water-solublemonomer, a hydrophobic monomer and a functional monomer into water so as to obtain a monomer mixed solution; adjusting the pH value of the monomer mixed solution to 2-6, mixing the monomer mixed solution, an aqueous solution or dispersion solution of a branched polysaccharide polymer and a nano-clay dispersion solution to obtain a mixed solution, adding an initiator into the mixed solution in a protective atmosphere, and carrying out a reaction at 30-50 DEG C for 3-12 h to obtain a gel base solution; and diluting the gel base solution, adding a cross-linking agent, adjusting a pH value to 4-6,and conducting standing at 35-80 DEG C for 4-12 hours to obtain the gel plugging material. The gel plugging material has good interface adhesive force and compression strength, can be applied to prevention and treatment of oil and gas channeling in the construction process oil and gas wells, and effectively guarantees exploitation efficiency.

Description

Technical field [0001] The present invention relates to a gel blockage material, and more particularly to a gel seal material and a preparation method thereof, which is a field of chemical engineering technology in oilfield. Background technique [0002] Oil and gas exploration gradually develops towards deep wells, high temperature wells and complex scriptures, often have a complex accident in drilling. Among them, well drain and oil and gas rhabbing are the complexity of common underground in drilling operations. [0003] During the drilling, well, testing various wells, various working fluids penetrate into the formation under differential pressure. Once the fluid drain occurs, not only the drilling time will be delayed, and the drilling fluid is not only damaged, but also damage the oil and gas layer, causing significant economic losses. Handling these well-drain problems, generally takes about 10% of the drilling cycle, and the treatment time is more than 70% of the drilling...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/02C08F220/56C08F251/00C08F289/00C09K8/467
CPCC08F251/02C08F251/00C08F289/00C08K3/346C09K8/426C09K8/467C08K2201/011C08F220/56
Inventor 刘德基陈超尹玉川陶媛刘小军贺永殿祝洪爽李爱英温海霞李论
Owner PETROCHINA CO LTD
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