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A kind of hydrous manganese carbonate slag-based liquid gelling material and its preparation method and application

A technology based on manganese carbonate slag and manganese carbonate slag is applied in the field of building cementitious materials, which can solve the problems of long operation process, high cost and long process line, and achieve the effects of short operation process, low cost and quality reduction.

Active Publication Date: 2022-06-21
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method has excellent performance, but the cost is too high
[0006] The Chinese invention patent application with the publication number CN110903046A discloses a method for preparing building cementitious materials with electrolytic manganese metal leaching slag. Improving the activity of electrolytic manganese slag can fully stimulate its gelling performance, and the prepared building cementitious materials are It can be made into cement masonry mortar, plastering mortar, dry-mixed mortar, external wall plastering mortar, unburned brick, etc., which reduces the amount of cement in the cementitious material, can adjust the setting time of the cementitious material, and has high strength , health and environmental protection, reduce costs, and improve the economic benefits of enterprises, but the preparation process is complicated and the operation process is long
[0007] The above three gelling materials all have the following defects, the preparation process is complicated, the process line is long and the economy is not high, the gelling material produced is not resistant to high temperature and has poor thermal stability, and the gelling material is easy to degrade at high temperature

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  • A kind of hydrous manganese carbonate slag-based liquid gelling material and its preparation method and application

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Example 1 is used to illustrate a preferred embodiment of the present invention.

[0025] 80 parts by mass of hydrous manganese carbonate slag, 300 parts by mass of zirconia grinding body, 112 parts by mass of phosphoric acid, 32 parts by mass of water, 8 parts by mass of titanium slag, 8 parts by mass of iron ore powder and 2 parts by mass of abrasives Put it into a stirring ball mill for sealing and grinding, and remove the zirconia grinding body to obtain a slurry with a median particle size of 2.68 μm, and obtain a water-containing manganese carbonate slag-based liquid heat-resistant cementitious material. The solid content is 67%, the rapid stirring is for 2 minutes, and the test blocks are made and tested according to GB / T50081-2016 "Standards for Mechanical Properties of Ordinary Concrete".

[0026] The characteristics of placing zirconia grinding bodies of different diameters in the grinding jar are: the mass ratio of 0.8mm zirconia grinding bodies, 1.4mm zircon...

Embodiment 2

[0028] Example 2 is used to illustrate a preferred embodiment of the present invention.

[0029] 100 parts by mass of hydrous manganese carbonate slag, 300 parts by mass of zirconia grinding body, 112 parts by mass of phosphoric acid, 40 parts by mass of water, 10 parts by mass of titanium slag, 10 parts by mass of iron ore powder and 3 parts by mass of abrasives Put it into a stirring ball mill to seal, grind, and remove the zirconia grinding body to obtain a slurry with a median particle size of 2.88 μm, and obtain a water-containing manganese carbonate slag-based liquid heat-resistant cementitious material with a solid content of 68%, and rapidly stir for 2 minutes. GB / T50081-2016 "Standards for Experimental Methods of Mechanical Properties of Ordinary Concrete" to make test blocks and test their properties.

[0030] The characteristics of placing zirconia grinding bodies of different diameters in the grinding jar are: the mass ratio of 0.8mm zirconia grinding bodies, 1.4mm...

Embodiment 3

[0032] Example 3 is used to illustrate a preferred embodiment of the present invention.

[0033]80 parts by mass of hydrous manganese carbonate slag, 300 parts by mass of zirconia grinding body, 112 parts by mass of phosphoric acid, 32 parts by mass of water, 8 parts by mass of titanium slag, 8 parts by mass of iron ore powder and 2 parts by mass of grinding The agent is put into a stirring ball mill for sealing and grinding, and the zirconia grinding body is removed to obtain a slurry with a median particle size of 2.68 μm, and a liquid heat-resistant cementitious material based on water-containing manganese carbonate slag is obtained. The solid content is 69%, the rapid stirring is for 2 minutes, and the test blocks are made and tested according to GB / T50081-2016 "Standards for Experimental Methods of Mechanical Properties of Ordinary Concrete".

[0034] The characteristics of placing zirconia grinding bodies of different diameters in the grinding jar are: the mass ratio of ...

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Abstract

The invention discloses a hydrous manganese carbonate slag-based liquid gelling material and its preparation method and application. Parts of water, 112-140 parts by mass of phosphoric acid, 8-10 parts by mass of titanium slag, 8-10 parts by mass of iron ore powder and 2-3 parts by mass of grinding aid are packed into a stirring ball mill for sealing, grinding, removing the grinding body, and stirring quickly 2-4min, one-step method to obtain hydrous manganese carbonate slag-based liquid gelling material. The prepared hydrous manganese carbonate slag-based liquid gelling material has high strength, high temperature resistance, strong corrosion resistance and excellent mechanical properties. It can be used in the field of tunnel engineering and solves the problem of thermal degradation of concrete materials at high temperatures. The hydrous manganese carbonate slag-based liquid gelling material has excellent high temperature resistance, simple preparation process, and realizes sustainable utilization of resources while reducing costs.

Description

technical field [0001] The invention relates to the technical field of building cementitious materials, in particular to a water-containing manganese carbonate slag-based liquid cementitious material and a preparation method and application thereof. Background technique [0002] With the accelerating pace of highway construction in the western region, the number of deep-buried tunnel projects has increased. Construction projects in a buried deep environment with complex geological conditions will face the problems of high geothermal heat and high geostress, which seriously affect the normal progress of the project construction. As the construction depth of tunnel engineering increases, the problems of high geothermal heat and high geostress have become urgent problems to be solved by researchers skilled in the art. A large number of studies have shown that heating of traditional cement-based materials at high temperatures will lead to the degradation of cement materials, wh...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/34C04B40/02C04B12/02
CPCC04B28/342C04B40/0281C04B40/0263C04B12/02C04B2111/00724C04B18/144C04B18/12
Inventor 杨进张强贺行洋苏英王铁唐袁珍于肖雷白行曾令豪马梦阳
Owner HUBEI UNIV OF TECH
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