The invention discloses a garnet type
composite oxide solid-state
electrolyte, a
solid-state battery and a preparation method of the garnet type
composite oxide solid-state
electrolyte, the chemical general formula of the
electrolyte is Li < 7 > La < 3-x > Zr < 2-y > M < z > O < 12 > awt% Al < 2 > O < 3 >, 0 < = x < = 3, 0 < = y < = 0.5, z = x + y, and 1.5 < = a < = 22. Through specific multi-element
doping and component regulation, the
ionic conductivity of the prepared solid electrolyte is improved to 1.95 * 10 <-2.74 > * 10 < S > / cm and is far higher than that of a traditional LLZO-based electrolyte on the premise that the pure LLZO
crystal phase structure is kept stable and the
ceramic density is kept at the excellent level of 85.4%-98.6%; and meanwhile, the
ion transmission impedance of the electrolyte is reduced to 48.5-97.3
omega.cm, and the ionic conduction dynamic characteristic is remarkably improved. The technical problems that a traditional LLZO-based electrolyte is low in
ionic conductivity and an impure phase is easy to generate are solved, and the prepared solid electrolyte has
structural stability and excellent ionic conduction performance and has important application value in the field of solid
lithium ion batteries.