The present invention relates to a method for pretreatment of a substrate containing
copper and / or its alloys, comprising at least step 1), i.e., contacting at least one surface of at least one substrate (the surface being made of
copper and / or at least one of its alloys) with an aqueous composition in at least a portion thereof, thereby forming a film on at least a portion thereof, wherein the aqueous composition comprises water and at least one of components a1) and a2), i.e., as component a1), at least one of
zirconium cation,
titanium cation, and
hafnium cation, each calculated as a
metal in the respective case, preferably in an amount in the range of 5 to 2000 mg / L, and / or as component a2), at least one organosilane and / or at least one
hydrolysate and / or condensate thereof, wherein the contact step 1) is performed in an
electrolytic cell apparatus in which the substrate made of
copper and / or its alloys serves as the
cathode during the execution of step 1). The present invention also relates to a method for applying at least one
coating film onto the surface of a pre-treated substrate, a substrate that can be obtained by any of these methods, a
current collector, conductor, copper-clad laminate,
anode material, and
battery cell that can be obtained from the substrate, and a method for using the aforementioned aqueous composition for electrolytically forming a film on a substrate made of copper and / or its
alloy.