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Preparation and production process of high-purity magnesium oxide

A production process and technology of magnesium oxide, applied in directions such as magnesium oxide, can solve the problems of difficult to control reaction conditions, high cost, insufficient purity of magnesium oxide, etc., and achieve the effects of easy control of process parameters, reduction of impurity content, and low production cost.

Pending Publication Date: 2021-04-16
山东信能达工程科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the methods for preparing magnesium oxide from magnesium sulfate include magnesium hydroxide precipitation method, ammonium bicarbonate method, etc. The precipitation method uses sodium hydroxide as a precipitant, which will increase production costs and is difficult to control the reaction conditions; the ammonium bicarbonate method has many process parameters and is difficult Problems such as production control, low pyrolysis efficiency, insufficient purity of magnesium oxide products, and high cost

Method used

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  • Preparation and production process of high-purity magnesium oxide

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] (1) Measure 246kg of magnesium sulfate heptahydrate, place the magnesium sulfate heptahydrate in a ventilated crucible with a top cover structure, put the crucible in a drying kiln, control the temperature of the drying kiln at 350°C, and dry it through the drying kiln After 4 hours, take out to obtain dry anhydrous magnesium sulfate, and dry the water to discharge;

[0033] (2) Anhydrous magnesium sulfate is transported in the mill, and through sufficient grinding, the particle size is controlled at 200 orders;

[0034] (3) Add 15kg of active carbon into the ground anhydrous magnesium sulfate, and after fully mixing anhydrous magnesium sulfate and active carbon, send it into the roller kiln for high-temperature calcination. The calcination temperature is 1100° C., and the calcination time is 5h, discharge sulfur dioxide;

[0035] (4) Add 80L of primary washing water into the primary washing tank, control the temperature at 50°C, put the calcined magnesium oxide into t...

Embodiment 2

[0040] (1) Measure 600kg of magnesium sulfate heptahydrate, place the magnesium sulfate heptahydrate in a ventilated crucible with a top cover structure, put the crucible in a drying kiln, control the temperature of the drying kiln at 350°C, and dry it in the drying kiln Take out after 3h to obtain dry anhydrous magnesium sulfate, and dry the water to discharge;

[0041] (2) Anhydrous magnesium sulfate is transported in the mill, and through sufficient grinding, the particle size is controlled at 250 orders;

[0042] (3) Add 37kg of active carbon into the ground anhydrous magnesium sulfate, and after fully mixing anhydrous magnesium sulfate and active carbon, send it into the roller kiln for high-temperature calcination. The calcination temperature is 1150° C., and the calcination time is 4h, discharge sulfur dioxide;

[0043] (4) Add 195L of primary washing water into the primary washing tank, control the temperature at 70°C, put the calcined magnesium oxide into the primary...

Embodiment 3

[0048] (1) Measure 100kg of magnesium sulfate heptahydrate, place the magnesium sulfate heptahydrate in a ventilated crucible with a top cover structure, put the crucible in a drying kiln, control the temperature of the drying kiln at 250°C, and dry it through the drying kiln Take out after 2h to obtain dry anhydrous magnesium sulfate, and dry the water to discharge;

[0049] (2) Anhydrous magnesium sulfate is transported in the mill, and through sufficient grinding, the particle size is controlled at 300 mesh;

[0050] (3) Add the gac of 6kg in the anhydrous magnesium sulfate after grinding, after fully mixing anhydrous magnesium sulfate and gac mix, send into the roller kiln and carry out high-temperature calcination, and the calcination temperature is 950 ℃, and the calcination time is 3.5h, sulfur dioxide discharge;

[0051] (4) Add 32.5L of primary washing water into the primary washing tank, control the temperature at 40°C, put the calcined magnesium oxide into the prim...

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Abstract

The invention belongs to the technical field of chemical industry, food and medicine, and particularly relates to a preparation and production process of high-purity magnesium oxide. The process comprises the following steps: preparing high-purity magnesium oxide by using magnesium sulfate heptahydrate, activated carbon and water as raw materials, and drying and dehydrating the magnesium sulfate heptahydrate by using a drying kiln to obtain anhydrous magnesium sulfate; grinding the dried anhydrous magnesium sulfate by using a grinding machine; calcining and decomposing the ground anhydrous magnesium sulfate in a calcining kiln at high temperature to obtain magnesium oxide; carrying out secondary washing on the calcined magnesium oxide in a washing machine to remove soluble impurities such as soluble sulfate; filtering the washed magnesium oxide turbid liquid in a filter to obtain solid magnesium oxide; and carrying out high-temperature drying on the precipitated magnesium oxide in the calcining kiln again, and calcining to obtain the high-purity magnesium oxide product. Magnesium sulfate is directly calcined, so that the production cost of high-purity magnesium oxide is reduced, and magnesium oxide with a purity of 99% or more can be prepared.

Description

technical field [0001] The invention belongs to the technical fields of chemical industry, food and medicine, and in particular relates to a preparation and production process of high-purity magnesium oxide. Background technique [0002] Magnesium oxide (MgO) is a widely used chemical raw material, and its application field is mainly determined by its purity. High-purity magnesium oxide with a magnesium oxide content greater than 98% is widely used in electronics, electrical appliances, Optics, instruments, metallurgy, national defense and aerospace and other high-tech fields. [0003] At present, the methods for preparing magnesium oxide using magnesium sulfate include magnesium hydroxide precipitation method, ammonium bicarbonate method, etc. The precipitation method uses sodium hydroxide as a precipitant, which will increase production costs and is difficult to control the reaction conditions; the ammonium bicarbonate method has many process parameters and is difficult ...

Claims

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Application Information

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IPC IPC(8): C01F5/12
Inventor 杨洪征王群王宗宝于冰
Owner 山东信能达工程科技有限公司
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