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Steel-plastic film for lithium battery flexible package and preparation method of film

A flexible packaging and lithium battery technology, applied in battery pack parts, chemical instruments and methods, circuits, etc., can solve the problems of insufficient surface roughness of stainless steel foil, poor drawing performance of steel-plastic film, insufficient interlayer peeling force, etc. , to achieve good strength and hardness, deal with volume expansion, slow down the effect of aging

Pending Publication Date: 2021-04-30
SUZHOU FIRST PV MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are two problems in the actual use of stainless steel foil: one is that the surface roughness of the stainless steel foil is insufficient, the reaction with the adhesive is slow, and the interlayer peeling force is not enough; The drawing performance of steel-plastic film is not good
However, how to use rare earth elements to make steel-plastic films for flexible packaging of lithium batteries has not yet been reported.

Method used

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  • Steel-plastic film for lithium battery flexible package and preparation method of film
  • Steel-plastic film for lithium battery flexible package and preparation method of film
  • Steel-plastic film for lithium battery flexible package and preparation method of film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032]Such asfigure 1As shown, a lithium battery soft package steel film includes a plastic substrate layer 1, a first adhesive layer 2, a modified stainless steel foil layer 3, a second adhesive layer 4, and a plastic heat sealing layer 5; The modified stainless steel foil layer 3 is obtained by a rare earth oxide particle layer 32 by a magnetron-controlled sputtering method with a rare earth element. The modified stainless steel foil layer 3 is bonded to the plastic heat sealing layer 5 and the substrate layer 1 by the first adhesive layer (2) and the second adhesive layer (4).

[0033]In the present embodiment, the content of the rare earth element contained in the stainless steel foil base layer 31 is ruthenium, the content is 10 ppm; the rare earth oxide containing the rare earth oxide particles 32 is cerium oxide, thickness of 2 μm; stainless steel foil base layer The thickness of 31 is 50 μm.

[0034]The preparation of the plastic substrate layer 1 may be a polyamide, a polyester, ...

Embodiment 2

[0041]In the present embodiment, the rare earth element contained in the stainless steel foil base layer 31 is cerium, the content is 50 ppm; the rare earth oxide layer of magnetron sputter is made of cerium oxide, the thickness is 2 μm; the stainless steel foil base layer 31 has a thickness of 10 μm.

[0042]The preparation of the plastic substrate layer 1 may be a polyamide, a polyester, a polyimide; the present embodiment is a polyimide. The first adhesive layer 2 may be one or more of a polyurethane adhesive, an epoxy resin adhesive, an acrylic resin adhesive, a polyester adhesive; the present embodiment is a polyurethane adhesive. The second adhesive layer 4 may be one or more of an acrylic resin adhesive, an epoxy resin adhesive, an acid-modified polypropylene resin; an acrylic resin adhesive. The plastic thermal sealing layer 5 may be one or more of polyolefin, cyclic polyolefin; the present embodiment is a cyclic polyolefin.

[0043]The above feedstock was prepared according to th...

Embodiment 3

[0045]In the present embodiment, the rare earth element contained in the stainless steel foil base layer 31 is ruthenium, the content is 100 ppm; the rare earth oxide layer of magnetron sputter is made of cerium oxide, the thickness of 2 μm; the thickness of the stainless steel foil base 31 is 100 μm.

[0046]The preparation of the plastic substrate layer 1 may be a polyamide, a polyester, a polyimide; the present embodiment is a polyamide. The first adhesive layer 2 can be one or more of a polyurethane adhesive, an epoxy resin adhesive, an acrylic resin adhesive, a polyester adhesive; the present example is an epoxy resin adhesive. The second adhesive layer 4 may be one or more of an acrylic resin adhesive, an epoxy resin adhesive, an acid modified polypropylene resin; the present embodiment is an acid-modified polypropylene resin. The plastic heat sealing layer 5 may be one or more of polyolefin, cyclic polyolefin; the present embodiment is a polyolefin.

[0047]The above feedstock was ...

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Abstract

The invention discloses a steel-plastic film for a lithium battery flexible package and a preparation method of the steel-plastic film. The steel-plastic film comprises a plastic base material layer (1), a first bonding layer (2), a modified stainless steel foil layer (3), a second bonding layer (4) and a plastic heat sealing layer (5) which are stacked in sequence, the modified stainless steel foil layer comprises a stainless steel foil base layer (31) containing rare earth elements and rare earth oxide particle layers (32) arranged at the two sides of the stainless steel foil base layer, and the modified stainless steel foil layer is bonded with the first bonding layer and the second bonding layer through the rare earth oxide particle layers; the content of rare earth elements in the stainless steel foil base layer is 10-500 ppm; the thickness of the rare earth oxide particle layer is 0.5-2 mu m; the steel-plastic film is prepared by sequentially stacking the plastic base material layer, the first bonding layer, the modified stainless steel foil layer, the second bonding layer and the plastic heat sealing layer. The steel-plastic film disclosed by the invention has high corrosion resistance and deep-drawing resistance and relatively high interlayer stripping force.

Description

Technical field[0001]The present invention relates to the field of lithium battery preparation, and more particularly to a steel plastic film for a lithium battery soft package and a preparation method thereof.Background technique[0002]The soft packaging material has the advantages of light, highly controlled and safety coefficients, and is a wide range of lithium battery packaging materials. The soft package material is bonded by an outer substrate layer, an intermediate metal foil layer, and an inner heat sealing layer to be bonded by an adhesive, and a material commonly used in the metal foil layer includes two types of aluminum foil and stainless steel foil. As the lithium battery develops towards thin, lightweight direction, the thickness and quality of soft packaging materials have also put forward higher requirements. During the thickness of the metal foil, the ductility of the aluminum foil will be significantly decreased, and the needle hole will inevitably produce, the ste...

Claims

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Application Information

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IPC IPC(8): B32B15/18B32B7/12B32B27/34B32B27/32B32B33/00B32B38/16B32B37/12B32B37/06B32B37/10B32B27/28H01M50/129H01M50/119H01M50/117H01M50/145H01M50/134
CPCB32B7/12B32B15/18B32B27/281B32B27/32B32B27/325B32B27/34B32B33/00B32B37/06B32B37/10B32B37/12B32B38/162B32B2307/536B32B2307/714Y02E60/10
Inventor 范开成余小玉沈丽梅魏晓东
Owner SUZHOU FIRST PV MATERIAL CO LTD