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Method for synergistically modifying polytetrafluoroethylene wear-resistant material by using multi-scale organic/inorganic filler

A technology of polytetrafluoroethylene and inorganic filler, which is applied in the fields of lubricating materials and composite materials, can solve the problem of undiscovered wear resistance of polytetrafluoroethylene, and achieve the effect of improving comprehensive performance and improving wear resistance.

Active Publication Date: 2021-06-11
LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, it has been reported in the literature that the synergistic effect of lubricants and rare earth compounds is used to improve the wear resistance of polytetrafluoroethylene, but no public documents and documents have been found to improve the wear resistance of polytetrafluoroethylene synergistically with polyamide-imide and nano-yttrium oxide. Patent report

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Raw material ratio: polytetrafluoroethylene 94.5 g, polyamide imide 5 g, nano oxide 0.5 g.

[0023] Preparation Process:

[0024] (1) Low temperature freezing mix screen: Plurifluoride, polyamide imide, nano oxide is placed in a low temperature freezing mixing body, and the mixing chamber temperature is adjusted to -10 ° C, stirring speed 650 r / min, stir Mix for 10 min, mixed with uniform oscillation, dry, dry, resulting in a uniform mixture;

[0025] (2) Dry: Put the mixture into the oven, temperature 100 ° C, dry time 8 h;

[0026] (3) Pressure molding: Put the dry mixture into the metal mold, is placed horizontally on the hydraulic press, suppressed 10 minutes, released to the preformed blank under pressure of 35 MPa; add the preformed blank into flexible silicone rubber In the set, it is pressed into the cold and dispersion machine to obtain a static pressure blank of the cold and disasters; the static pressure molding conditions of cold and other: medium: water; pres...

Embodiment 2

[0030] Raw material ratio: polytetrafluoroethylene 94 g, polyamideimide 5g, nano oxide 1g.

[0031] Preparation Process:

[0032] (1) Low temperature freezing mix screen: Pluriflufluoroethylene, polyamideimide, nano oxide is placed in a low temperature freezing mixing part, and the mixing chamber temperature is adjusted to -5 ° C, stirring speed 1300R / min, stir Mix 15min, mixed with uniform oscillation, dry, dry, resulting in a uniform mixture;

[0033] (2) Drying: Put the mixture into the oven, temperature 110 ° C, dry time 6 h;

[0034] (3) Pressure molding: Put the dry mixture into the metal mold, placed horizontally on the hydraulic press, pressed for 5 minutes under pressure of 50 MPa, and the preformed blank is obtained after being released; the preformed blank is placed in a flexible silicone rubber. In the set, it is pressed in the cold and dispersion machine to obtain a static pressure blank of the cold and equal; cold and medium static pressure molding conditions: medi...

Embodiment 3

[0038] Raw material ratio: polytetrafluoroethylene 89g, polyamide imide 10g, nano oxide 1g.

[0039] Preparation Process:

[0040] (1) Low temperature freezing mix screen: Polytetrafluoroethylene, polyamide imide, nano oxide is placed in a low temperature freezing mixture, and the mixing chamber temperature is adjusted to -8 ° C, stirring speed 1300R / min, stir Mix for 20 min; mixed and uniformly oscilled, dried, and even uniform mixture;

[0041] (2) Dry: Put the mixture into the oven, temperature 105 ° C, dry time 7 h;

[0042](3) Pressure molding: Put the dry mixture into the metal mold, is placed horizontally on the hydraulic press, suppressed for 10 minutes under pressure of 45 MPa, and the preformed blank is obtained after being released; the preform is placed in a flexible silicone rubber. In the set, it is pressed into the cold and dispersion machine to obtain a static pressure blank of the cold. Cold and other static pressure molding conditions: Media: water; pressure: 5...

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Abstract

The invention discloses a method for synergistically modifying a polytetrafluoroethylene wear-resistant material by using an organic / inorganic filler. The method comprises the following steps: putting polytetrafluoroethylene, polyamide-imide and nano yttrium oxide into a low-temperature freezing and mixing all-in-one machine for low-temperature freezing, mixing, screening and drying to obtain a mixture; putting the mixture into a drying oven, completely drying, pre-pressing on a hydraulic machine, and pressing in a cold isostatic pressing machine to obtain a cold isostatic pressing blank; and performing staged sintering in a sintering furnace, and cooling to room temperature after sintering is finished. According to the invention, the polytetrafluoroethylene is compositely filled with the micrometer-scale organic filler polyamide-imide and the inorganic nano-particle yttrium oxide, so that the wear resistance of the polytetrafluoroethylene composite material is greatly improved; and by adopting staged heating sintering, controlling the sintering heating speed and the sintering temperature and strictly controlling the cooling rate, the comprehensive performance of the polytetrafluoroethylene is well improved, and the polytetrafluoroethylene is a valuable lubricating, wear-resistant and sealing material.

Description

Technical field [0001] The present invention relates to a method of preparing a modified polytetrafluoroethylene wear material, and more particularly to a method of preparing a micro-nanometer multi-scale organic / inorganic filler synergistic modified polytetrafluoroethylene wear-resistant material, which belongs to the technical field of composite materials and Lubricating material technology. Background technique [0002] Polytetrafluoroethylene has the smallest friction coefficient in plastic, which is an ideal oil-free lubricating material. However, the pure polytetrafluoroethylene carrying capacity is low, the creep, abrasion resistance is poor, and the material composite is improved by the improvement of polytetrafluoroethylene wear resistance is an important way to expand the harsh conditions. With inorganic, organic filler is used to fill modification is the most common and effective modified means, while the wear resistance of the modified polytetrafluoroethylene compos...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/18C08L79/08C08K3/22
CPCC08L27/18C08K2003/221C08K2201/011C08K2201/005C08L79/08C08K3/22
Inventor 张新瑞谢海李宋王齐华王廷梅
Owner LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI