Microemulsion type imbibition agent, and preparation method thereof and oil displacement type fracturing fluid system
A technology of imbibition agent and microemulsion, which is applied in chemical instruments and methods, composition of drilling holes, etc., can solve problems such as poor fracturing effect and so on.
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Embodiment 2
[0106] In percent by weight, 45% of the fatty alcohol ether grafted comb polymer active agent obtained in Example 1, 25% of 18 alkyl hydroxypropyl ethyl sulfobetaine, 2.2% of 10 carbon perfluoroalkyl polyoxygen Mix vinyl ether with 27.8% water, react at 65° C. for 2 hours, and obtain the emulsifier used in the present invention through self-assembly reaction.
[0107] At a temperature of 60°C, add 25% of 200# solvent naphtha and 20% of the emulsifier prepared above and stir for 1 hour; then raise the temperature to 70°C, and react while adding 54% of water dropwise until the addition of water is complete. Add 1% urotropine, continue to stir and react for 1 hour, and obtain the microemulsion type osmotic agent.
[0108] The surface tension of 0.1% is 24.77mN / m, the surface tension of 0.2% is 23.42mN / m, and the surface tension of 0.3% is 22.82mN / m.
Embodiment 3
[0110] By weight percent, the fatty alcohol ether that 40% embodiment 1 obtains is grafted comb polymer active agent, and 25% main chain is 18 alkyl hydroxypropyl ethyl sulfobetaine, 3% 10 carbon perfluoroalkane Mix base polyoxyethylene ether with 32% water and react at 65°C for 2 hours to obtain the emulsifier used in the present invention.
[0111] Add 30% diene terpene and 20% of the emulsifier prepared above and stir for 1 hour at a temperature of 60°C; then raise the temperature to 70°C, and react while adding 49% of water dropwise until the addition of water is complete, add 1% urotropine, continue to stir and react for 1 hour, and obtain the microemulsion type osmotic agent.
[0112] The surface tension of 0.1% is 21.45mN / m, the surface tension of 0.2% is 20.94mN / m, and the surface tension of 0.3% is 19.64mN / m.
Embodiment 4
[0114] 1. Synthesis of Fatty Alcohol Ether Grafted Comb Polymer
[0115] S1 synthesis of monomer A:C 8 h 17 (OCH 2 CH 2 ) 7 OOCCH=CHCOONHR 2
[0116] (1) maleic anhydride adds naphthalene sulfonic acid amine, does solvent with toluene, and hydroquinone is made inhibitor, in N 2 Under protection, carry out reaction at 60 ℃ for 8-10 hours, and the reaction equation is:
[0117] C 4 h 2 o 3 +R 2 NH 2 →HOOCCH=CHCOONHR 2 +H 2 O, R 2 : naphthalenesulfonic acid group;
[0118] (2) The product obtained by the reaction uses toluene as a solvent, hydroquinone as a polymerization inhibitor, and p-toluenesulfonic acid as a catalyst, and at 60 ° C with fatty alcohol polyoxyethylene ether C 8 h 17 (OCH 2 CH 2 ) 7 OH reaction, the reaction equation is: HOOCCH=CHCOONHR 2 +C 8 h 17 (OCH 2 CH 2 ) 7 OH→C 8 h 17 (OCH 2 CH 2 ) 7 OOCCH=CHCOONHR 2 +H 2 O, denoted as monomer A;
[0119] S2 Synthesis of Monomer B: Ph(OH)C 10 h 21 OOCCH=CHCOOC 6 h 13 o 5
[0120]...
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