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Molybdenum selenide composite carbonized sonchus oleraceus corolla hair used as electrode material of sodium ion battery

A technology of carbonizing chicory cauliflower and sodium ion batteries, which is applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of poor cycle life of sodium ion batteries, poor electronic and ion conductivity, and low material rate performance, and achieve The effect of abundant reserves, low price, and stable cycle performance

Active Publication Date: 2021-06-25
黑龙江诺康石墨新材料科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a molybdenum selenide composite carbonized endive cabbage hair as an electrode material for sodium ion batteries, which makes up for the shortcomings of sodium ion battery materials such as low rate performance, easy agglomeration, and poor electronic and ion conductivity, and solves the problem. Solved the problems of poor cycle life and low energy density of sodium-ion batteries

Method used

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Embodiment Construction

[0010] The present invention will be further described in detail below in conjunction with specific embodiments.

[0011] A molybdenum selenide composite carbonized chicory pistil is used as an electrode material for sodium-ion batteries. Put 1g of chicory pappus powder into a porcelain boat and heat it at a heating rate of 2°C / min under the protection of argon. It was carbonized at 500° C. for two hours to obtain carbonized endive cauliflower pappus material. Dissolve 0.1532g Na2MoO4 in 5ml deionized water, add 0.1g selenium powder and dissolve with 5ml N2H2·H2O. Then slowly add 20ml of dimethylformamide (DMF) to obtain a black solution, transfer it to a 50ml polytetrafluoroethylene reactor, seal the reactor and heat at 200°C for 12h. After the reaction kettle was naturally cooled, the solution was taken out and diluted with deionized water to a neutral pH value, and the powder was obtained by suction filtration, and dried in an oven at 60°C for 12 hours to obtain a molybden...

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Abstract

The invention provides a molybdenum selenide composite carbonized sonchus oleraceus corolla hair used as an electrode material of a sodium ion battery, which comprises the steps of putting sonchus oleraceus corolla hair powder into a porcelain boat, heating to the temperature of 500 DEG C under the protection of argon, and continuously carbonizing the sonchus oleraceus corolla hair powder for two hours to obtain a carbonized sonchus oleraceus corolla hair material; dissolving Na2MoO4 in deionized water, adding selenium powder, and dissolving with N2H2.H2O; slowly adding dimethylformamide to obtain a black solution, transferring the black solution into a polytetrafluoroethylene reaction kettle, sealing the reaction kettle, and heating at temperature of 200 DEG C for 12 hours; and after the reaction kettle is naturally cooled, taking out the solution, diluting the solution with deionized water until the pH value is neutral, carrying out suction filtration to obtain powder, and drying the powder in a drying oven at the temperature of 60 DEG C for 12 hours to obtain the molybdenum selenide composite carbonized sonchus oleraceus corolla hair electrode material. The defects that a sodium ion battery material is low in rate capability, easy to agglomerate, poor in electron and ion conductivity and the like are overcome, and the problems that a sodium ion battery is short in cycle life, low in energy density and the like are solved.

Description

technical field [0001] The invention relates to an electrode material for a sodium-ion battery, in particular to an electrode material for a sodium-ion battery using molybdenum selenide composite carbonized endive cauliflower pappus. Background technique [0002] New energy vehicles and other fields are developing rapidly. In order to meet the future large-scale electrochemical energy storage demand and the increasing cost of lithium batteries, it is imminent to develop and design cheap and stable energy storage devices. Na-ion batteries have attracted extensive attention due to their excellent electrochemical performance and abundant Na resources. The cathode and anode of traditional Na-ion batteries are both slow diffusion reactions, which lead to their poor power density and cycle stability. The structure of a sodium-ion battery is similar to that of a lithium-ion battery. It is composed of a positive electrode, a negative electrode, a separator, and an electrolyte. Its ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/38H01M4/583H01M4/62H01M10/054
CPCH01M4/362H01M4/583H01M4/625H01M4/38H01M10/054Y02E60/10
Inventor 王显超夏庚磊陈野王贵领
Owner 黑龙江诺康石墨新材料科技有限公司
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