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All-organic composite material film and preparation method and application thereof

A composite film and organic filler technology, applied in the field of all-organic composite film and its preparation, can solve the problems of high breakdown strength, high energy density mechanical properties, simple preparation process, and reduced breakdown field strength. Achieve the effects of good physical and mechanical properties, high discharge energy density and high breakdown strength

Pending Publication Date: 2021-07-16
TSINGHUA UNIV +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In this composite material, when the graphene filler is 1.5vol%, the dielectric constant of the composite material can reach 65 at 1000 Hz, but the breakdown field strength will decrease significantly with the increase of conductive filler
[0006] However, the currently reported polymer-based dielectric composites cannot meet the requirements of high breakdown strength, high energy density, excellent mechanical properties, and simple preparation processes.

Method used

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  • All-organic composite material film and preparation method and application thereof
  • All-organic composite material film and preparation method and application thereof
  • All-organic composite material film and preparation method and application thereof

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preparation example Construction

[0067] According to an embodiment of the present invention, a method of preparing the above full organic composite material is obtained by a polymer as a substrate, a solution scraping technique is prepared by a solution scraping technique, and the obtained whole organism-based dielectric composite material is prepared. The film has a lower dielectric loss, high breakdown strength, high discharge energy, good physical mechanical properties, high electrical insulation performance, simple preparation process is simple and suitable for industrial production and engineering applications. Further, the preparation of the whole organic composite film of the present invention is easy to acquire, and the preparation process is simple and easy to provide large quantities. The existing polymer-based dielectric composites with inorganic ceramics are unable to balance dielectric constant and insulation performance, and is not suitable for large-scale industrialization.

[0068] In a third aspe...

Embodiment 1

[0071] MBs of 0.0063 g of a particle size of 1-2 μm was added to 10 ml of DMF, and after stirring at 50 ° C for 30 min, the power of the MBS was solened to obtain a dispersion of MBS; 0.5 g of VDF-HFP) was added to 10 ml In DMF, it was stirred at 50 ° C for 60 min, and the p (VDF-HFP) solution was obtained; after mixing the two, the magnetic force was stirred at 50 ° C for 5 hours to obtain a mixed solution; and the film was applied to the glass plate after a solution The temperature was 12 hours at 70 ° C, and the volume fraction of MBS was 2%, and the thickness of 8 μm was obtained. Such as figure 1 As shown, the granular substance in the figure is MBS filler, from figure 1 As can be seen, there is no defects such as agglomeration and micropores between the filler and the substrate, whereby the MBS filler is uniform in the P (VDF-HFP) matrix. The dielectric constant, dielectric loss, and strong internet extension field under different frequency conditions at room temperature, an...

Embodiment 2

[0073] MBs of 0.0129 g of a particle diameter of 1-2 μm was added to 10 ml of DMF, and after 30 min at 50 ° C, it was soaked that the dispersion of MBS was allowed to obtain a dispersion of MBS; 0.5 g p (VDF-HFP) was added to 10 ml In DMF, it was stirred at 50 ° C for 60 min, and the p (VDF-HFP) solution was obtained; after mixing the two, the magnetic force was stirred at 50 ° C for 5 hours to obtain a mixed solution; and the film was applied to the glass plate after a solution The temperature was 12 hours at 70 ° C, and the volume fraction of MBs was 4%, and the thickness of 8 μm was obtained. The dielectric constant, dielectric loss, and strong internet extension field under different frequency conditions at room temperature, and the discharge energy density is as figure 2 , 3 Curve 2 in 4, 5.

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Abstract

The invention discloses an all-organic composite material film and a preparation method and application thereof. The all-organic composite material film comprises a polymer matrix and an organic filler, the polymer matrix is polyvinylidene fluoride-co-hexafluoropropylene, and the organic filler is a terpolymer of methyl methacrylate, butadiene and styrene. The polymer is used as a matrix, the organic filler is used as a dispersion phase, and the obtained all-organic composite material film has the advantages of being low in dielectric loss, high in breakdown strength, high in discharge energy density, good in physical and mechanical performance, high in electrical insulation performance, simple in preparation process, suitable for industrial production and engineering application and the like.

Description

Technical field [0001] The present invention belongs to the field of dielectric materials, and more particularly to a fully organic composite film and a preparation method thereof. Background technique [0002] In recent years, with the high-performance demand and e-energy system of the electronic electrical industry, the metallized organic dielectric thin film capacitors of the electronized insulating properties, excellent flexibility and processability, excellent flexibility and processability, excellent flexibility and processability. Follow and research. At present, commercial biaxial pulling polypropylene capacitor (BOPP) is usually below 3J / cm 3 This limits the application of thin film capacitors under electrical equipment miniaturization. [0003] At present, in order to increase the energy density of the film capacitor, a ceramic particle or a conductive particle having a high dielectric constant is usually added to the polymer matrix, and the preparation method of the ...

Claims

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Application Information

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IPC IPC(8): C08L27/16C08L51/04C08J5/18H01G4/18H01G4/33
CPCC08J5/18C08J2327/16C08J2451/04H01G4/18H01G4/33
Inventor 党智敏冯启琨钟少龙张翀邢照亮戴熙瀛李飞
Owner TSINGHUA UNIV