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Bricking-like bionic composite prepared ceramic reinforced aluminum matrix composite

A technology for strengthening aluminum-based and composite materials, applied in metal processing equipment, transportation and packaging, etc., can solve the problems of long cycle, complicated process, and not reaching the scale of shell nacre, and achieve comprehensive mechanical properties improvement, wide application range, Maintain the effect of high-strength plastic matching

Active Publication Date: 2021-08-10
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its process is complicated and the cycle is long, and the content of brick-like reinforcement obtained by in-situ reaction has great uncertainty
[0006] Through the search of existing patent documents, it is found that CN201710570994 discloses a high-volume ceramic-metal layered composite material and its preparation method. The preparation method involved still belongs to the aforementioned frozen casting method, and its layered thickness is still greater than 5 μm , although it structurally mimics the brick-ash structure of the shell, it does not actually reach the scale of the shell's nacre

Method used

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  • Bricking-like bionic composite prepared ceramic reinforced aluminum matrix composite
  • Bricking-like bionic composite prepared ceramic reinforced aluminum matrix composite
  • Bricking-like bionic composite prepared ceramic reinforced aluminum matrix composite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Take 100 g of pure aluminum powder with a diameter of 10 μm and place it in a stirring ball mill, use absolute ethanol as a solvent, add 4 g of titanate as a ball milling aid, the ball-to-material ratio is 20:1, and ball mill at a speed of 300 rpm for 5 hours. Obtain flaky aluminum powder with a diameter of about 25 μm and a thickness of about 300 nm;

[0039] Take 60g flake aluminum powder and 4.5g flake aluminum oxide powder and mix, wherein the thickness of the flake alumina used is 250nm, the diameter is 10μm, put the mixed powder and 1Kg of agate balls respectively in a 1L drum, and then Mix at a speed of 50 rpm to make the flake aluminum powder and flake alumina powder evenly mixed.

[0040] Finally, the mixed powder was pressed into a green body with a diameter of 40 mm under a pressure of 200 MPa, and then the green body was sintered at 580 ° C for 2 h in an argon atmosphere, and then rolled at a temperature of 440 ° C with a reduction of 80%.

[0041] The room...

Embodiment 2

[0048] Take 100g of pure aluminum powder with a diameter of 20 μm and place it in a stirring ball mill, use absolute ethanol as a solvent, add 4g of titanate as a ball milling aid, the ball to material ratio is 20:1, and ball mill at a speed of 200 rpm for 8 hours. Obtain flaky aluminum powder with a diameter of about 40 μm and a thickness of about 200 nm;

[0049] Take 60g flake aluminum powder and 10g flake alumina powder and mix, wherein the thickness of the flake alumina used is 250nm, the diameter is 10μm, put the mixed powder and 1Kg of agate balls in a 1L drum respectively, and then use 60 Mix at a speed of revolution per minute, so that the flake aluminum powder and flake alumina powder are evenly mixed.

[0050] Finally, the mixed powder was pressed into a green body with a diameter of 40 mm under a pressure of 200 MPa, and then the green body was sintered at 600 ° C for 2 h in an argon atmosphere, and then rolled at a temperature of 500 ° C with a reduction of 80%. ...

Embodiment 3

[0053] Take 100g of pure aluminum powder with a diameter of 5 μm and place it in a stirring ball mill, use absolute ethanol as a solvent, add 4g of titanate as a ball milling aid, the ball to material ratio is 20:1, and ball mill at a speed of 300 rpm for 5 hours. Obtain flaky aluminum powder with a diameter of about 10 μm and a thickness of about 100 nm;

[0054] Get 60g flake aluminum powder and mix with 10g flake boron nitride powder, the thickness 100nm of wherein used flake boron nitride, diameter is 5 microns, the agate ball of mixed powder and 1Kg is placed in the cylinder of 1L respectively, Then mix at a speed of 60 rpm, so that the flake aluminum powder and flake boron nitride powder are uniformly mixed.

[0055] Finally, the mixed powder was pressed into a green body with a diameter of 40 mm under a pressure of 300 MPa, and then the green body was sintered at 540 ° C for 2 h in an argon atmosphere, and then rolled at a temperature of 300 ° C with a reduction of 70%....

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Abstract

The invention provides a bricking-like bionic composite prepared ceramic reinforced aluminum matrix composite. Micro-nano aluminum sheet elements with preferred orientation are prepared in advance and evenly mixed with sheet-shaped ceramic elements, in the densification process, the two sheet-shaped elements are alternately stacked in a bricking mode under the dual action of gravity and external force, and the bricking-like bionic ceramic reinforced aluminum matrix composite can be obtained through further processing deformation, wherein the thickness of the aluminum sheets and the ceramic sheets is only hundreds of nanometers, and a pearl layer structure is effectively simulated from the structure and the dimension. The matrix of the bricking-like bionic composite material is of an ultra-fine grain layered structure, and the flaky ceramic sheets can effectively hinder the expansion of cracks, so that the matching of high strength and plasticity is maintained under the condition that the dual mechanisms of ultra-fine grain strengthening and crack deflection are fully exerted. The prepared ceramic reinforced aluminum matrix composite is low in cost, wide in application range and higher in comprehensive mechanical property.

Description

technical field [0001] The invention relates to the field of metal-based composite materials, in particular to a brick-like bionic composite preparation of ceramic-reinforced aluminum-based composite materials. Background technique [0002] After long-term evolution, many biological materials in nature have reached a near-perfect level of structure and performance, such as multi-level laminated bone, gradient layered bamboo, and laminated shell nacre. So far, the nacre of the shell is the hottest structural bionic object at present, this is because it uses calcium carbonate (~95vol.%) nano-sheets (thick ~500nm) as "bricks", organic matter (~5vol.%, thick ~30nm) is "mud", and the "brick-mud" laminated structure formed by self-assembly not only does not sacrifice the overall strength of the shell, but also greatly improves the plasticity and toughness, and obtains very excellent strength and plasticity. comprehensive performance. Therefore, the mother-of-pearl layer of shell...

Claims

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Application Information

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IPC IPC(8): C22C1/05B22F9/04B22F1/00C22C21/00C22C32/00
CPCB22F1/0003C22C1/05C22C1/0416B22F9/04C22C21/00C22C32/00C22C32/0036C22C32/0068B22F2009/043B22F1/068
Inventor 范根莲张志明李志强谭占秋张荻
Owner SHANGHAI JIAO TONG UNIV