Asphalt road interlayer adhesive and preparation method thereof
An adhesive and road technology, applied in the direction of adhesive types, polyurea/polyurethane adhesives, polymer adhesive additives, etc. Low stability and other problems, to achieve the effect of promoting repair, improving waterproof performance, improving shear strength and bond strength
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Embodiment 1
[0028] A preparation method for an asphalt road interlayer adhesive, comprising the steps of:
[0029] Cyclodextrin polyrotaxanes were prepared with reference to the method in the literature Liu Y, Yang Y W, Chen Y, Zou HX.Polyrotaxane with Cyclodextrinsas Stoppers and Its Assembly Behavior[J].Macromolecules,2005,38(13):5838-5840;
[0030] Add oil-based asphalt repair agent to styrene maleic anhydride (surfactant) aqueous solution, disperse and emulsify at a high speed for 10 minutes and mix to obtain an emulsion; slowly add methyl etherified hexamethylolmelamine prepolymer solution dropwise to the emulsion to Stir and mix at a speed of 500r / min. After the dropwise addition, raise the temperature to 65°C, then adjust the pH to 5 with acetic acid aqueous solution, then raise the temperature to 80°C, keep stirring and react for 2 hours, cool to room temperature, filter, wash, and dry to obtain self-healing Microcapsules, wherein the weight ratio of the methylated hexamethylolmel...
Embodiment 2
[0033] A preparation method for an asphalt road interlayer adhesive, comprising the steps of:
[0034] Cyclodextrin polyrotaxanes were prepared with reference to the method in the literature Liu Y, Yang Y W, Chen Y, Zou HX.Polyrotaxane with Cyclodextrinsas Stoppers and Its Assembly Behavior[J].Macromolecules,2005,38(13):5838-5840;
[0035] Add oil-based asphalt repair agent to styrene maleic anhydride (surfactant) aqueous solution, disperse and emulsify at a high speed for 10 minutes and mix to obtain an emulsion; slowly add methyl etherified hexamethylolmelamine prepolymer solution dropwise to the emulsion to Stir and mix at a speed of 500r / min. After the dropwise addition, raise the temperature to 65°C, then adjust the pH to 5 with acetic acid aqueous solution, then raise the temperature to 80°C, keep stirring and react for 2 hours, cool to room temperature, filter, wash, and dry to obtain self-healing Microcapsules, wherein the weight ratio of the methylated hexamethylolmel...
Embodiment 3
[0038] A preparation method for an asphalt road interlayer adhesive, comprising the steps of:
[0039]The cyclodextrin polyrotaxane was obtained by referring to the method in the literature Liu Y, Yang Y W, Chen Y, Zou HX.Polyrotaxane with Cyclodextrinsas Stoppers and Its Assembly Behavior[J].Macromolecules,2005,38(13):5838-5840;
[0040] Add oil-based asphalt repair agent to styrene maleic anhydride (surfactant) aqueous solution, disperse and emulsify at a high speed and mix for 10 minutes to obtain an emulsion; slowly add methyl etherified hexamethylolmelamine prepolymer solution dropwise to the emulsion to Stir and mix at a speed of 500r / min. After the dropwise addition, raise the temperature to 65°C, then adjust the pH to 5 with acetic acid aqueous solution, then raise the temperature to 80°C, keep stirring and react for 2 hours, cool to room temperature, filter, wash, and dry to obtain self-healing Microcapsules, wherein the weight ratio of the methylated hexamethylolmela...
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