A kind of wear-resistant polyethylene and preparation method thereof
A technology of polyethylene and graphene, which is applied in the field of wear-resistant polyethylene and its preparation, can solve problems such as unsatisfactory wear resistance, achieve the effects of reducing the rate of peeling, improving friction performance, and reducing friction area
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Embodiment 1
[0032] A wear-resistant polyethylene, in parts by weight, mainly comprising: 70 parts of modified polyethylene, 10 parts of modified sodium lignin, 10 parts of chitosan-modified graphene oxide and 10 parts of cellulose-modified graphite oxide ene.
[0033] A preparation method of wear-resistant polyethylene, the preparation method of wear-resistant polyethylene mainly comprises the following preparation steps:
[0034] (1) Mix chitosan and acetic acid solution with a mass fraction of 1% in a beaker at a mass ratio of 1:100, adjust the pH of the material in the beaker to 6.5 with a sodium hydroxide solution with a concentration of 0.5mol / L, and add to the beaker. Add 50 times the mass of chitosan into a beaker with a mass fraction of 1% graphene oxide dispersion, stir and mix for 4 hours, and filter to obtain pretreated chitosan-modified graphene oxide. Graphene is mixed with a phosphate solution with a pH of 5 in a mass ratio of 1:100, and ethylenediamine and 1-(3-dimethylamino...
Embodiment 2
[0042] A wear-resistant polyethylene, in parts by weight, mainly comprises: 70 parts of modified polyethylene, 10 parts of chitosan-modified graphene oxide and 10 parts of cellulose-modified graphene oxide.
[0043] A preparation method of wear-resistant polyethylene, the preparation method of wear-resistant polyethylene mainly comprises the following preparation steps:
[0044] (1) Mix chitosan and acetic acid solution with a mass fraction of 1% in a beaker at a mass ratio of 1:100, adjust the pH of the material in the beaker to 6.5 with a sodium hydroxide solution with a concentration of 0.5mol / L, and add to the beaker. Add 50 times the mass of chitosan into a beaker with a mass fraction of 1% graphene oxide dispersion, stir and mix for 4 hours, and filter to obtain pretreated chitosan-modified graphene oxide. Graphene is mixed with a phosphate solution with a pH of 5 in a mass ratio of 1:100, and ethylenediamine and 1-(3-dimethylaminopropyl)- 3-ethylcarbodiimide hydrochlor...
Embodiment 3
[0051] A wear-resistant polyethylene, in parts by weight, mainly comprises: 70 parts of modified polyethylene, 10 parts of modified sodium lignin and 10 parts of cellulose modified graphene oxide.
[0052] A preparation method of wear-resistant polyethylene, the preparation method of wear-resistant polyethylene mainly comprises the following preparation steps:
[0053] (1) The aldehyde-based cellulose and graphene oxide are mixed in the flask at a mass ratio of 1:1, and N,N'-dimethylformamide with 80 times the mass of graphene oxide is added to the flask, and after stirring and mixing , add ceric ammonium nitrate with 0.06 times the mass of aldehyde-ylated cellulose and ammonium persulfate with 0.06 times the mass of aldehyde-ylated cellulose into the flask, stir and react for 10 minutes at a temperature of 50 ° C, and then add aldehyde to the flask The triethylenediamine with 5 times the mass of the base cellulose was continuously stirred and reacted at a temperature of 50 ° ...
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