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A kind of wear-resistant polyethylene and preparation method thereof

A technology of polyethylene and graphene, which is applied in the field of wear-resistant polyethylene and its preparation, can solve problems such as unsatisfactory wear resistance, achieve the effects of reducing the rate of peeling, improving friction performance, and reducing friction area

Active Publication Date: 2022-06-28
东营市东达机械制造有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, when the existing polyethylene materials are in contact with metals, the wear resistance is often not ideal. Therefore, it is necessary to research and develop a polyethylene material that is wear-resistant when it is in contact with metal materials.

Method used

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  • A kind of wear-resistant polyethylene and preparation method thereof

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Embodiment 1

[0032] A wear-resistant polyethylene, in parts by weight, mainly comprising: 70 parts of modified polyethylene, 10 parts of modified sodium lignin, 10 parts of chitosan-modified graphene oxide and 10 parts of cellulose-modified graphite oxide ene.

[0033] A preparation method of wear-resistant polyethylene, the preparation method of wear-resistant polyethylene mainly comprises the following preparation steps:

[0034] (1) Mix chitosan and acetic acid solution with a mass fraction of 1% in a beaker at a mass ratio of 1:100, adjust the pH of the material in the beaker to 6.5 with a sodium hydroxide solution with a concentration of 0.5mol / L, and add to the beaker. Add 50 times the mass of chitosan into a beaker with a mass fraction of 1% graphene oxide dispersion, stir and mix for 4 hours, and filter to obtain pretreated chitosan-modified graphene oxide. Graphene is mixed with a phosphate solution with a pH of 5 in a mass ratio of 1:100, and ethylenediamine and 1-(3-dimethylamino...

Embodiment 2

[0042] A wear-resistant polyethylene, in parts by weight, mainly comprises: 70 parts of modified polyethylene, 10 parts of chitosan-modified graphene oxide and 10 parts of cellulose-modified graphene oxide.

[0043] A preparation method of wear-resistant polyethylene, the preparation method of wear-resistant polyethylene mainly comprises the following preparation steps:

[0044] (1) Mix chitosan and acetic acid solution with a mass fraction of 1% in a beaker at a mass ratio of 1:100, adjust the pH of the material in the beaker to 6.5 with a sodium hydroxide solution with a concentration of 0.5mol / L, and add to the beaker. Add 50 times the mass of chitosan into a beaker with a mass fraction of 1% graphene oxide dispersion, stir and mix for 4 hours, and filter to obtain pretreated chitosan-modified graphene oxide. Graphene is mixed with a phosphate solution with a pH of 5 in a mass ratio of 1:100, and ethylenediamine and 1-(3-dimethylaminopropyl)- 3-ethylcarbodiimide hydrochlor...

Embodiment 3

[0051] A wear-resistant polyethylene, in parts by weight, mainly comprises: 70 parts of modified polyethylene, 10 parts of modified sodium lignin and 10 parts of cellulose modified graphene oxide.

[0052] A preparation method of wear-resistant polyethylene, the preparation method of wear-resistant polyethylene mainly comprises the following preparation steps:

[0053] (1) The aldehyde-based cellulose and graphene oxide are mixed in the flask at a mass ratio of 1:1, and N,N'-dimethylformamide with 80 times the mass of graphene oxide is added to the flask, and after stirring and mixing , add ceric ammonium nitrate with 0.06 times the mass of aldehyde-ylated cellulose and ammonium persulfate with 0.06 times the mass of aldehyde-ylated cellulose into the flask, stir and react for 10 minutes at a temperature of 50 ° C, and then add aldehyde to the flask The triethylenediamine with 5 times the mass of the base cellulose was continuously stirred and reacted at a temperature of 50 ° ...

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Abstract

The invention discloses a wear-resistant polyethylene and a preparation method thereof, and relates to the technical field of new materials. In the present invention, chitosan is first used to coat graphene oxide and then aminated to obtain chitosan-modified graphene oxide, and then react with graphene oxide under the action of a catalyst after the cellulose is alkylated , to obtain cellulose-modified graphene oxide, and secondly, sodium lignosulfonate is bridged with 1,6-dibromohexane to obtain modified sodium lignin, and finally, chitosan-modified graphite oxide After mixing cellulose-modified graphene oxide with maleic anhydride-modified polyethylene, adding modified sodium lignin, melt-extruding, and granulating to obtain wear-resistant polyethylene. The wear-resistant polyethylene prepared by the invention has excellent wear-resistant performance when rubbing against metal.

Description

technical field [0001] The invention relates to the technical field of new materials, in particular to a wear-resistant polyethylene and a preparation method thereof. Background technique [0002] As a synthetic polymer compound, plastic is a material that uses monomer raw materials to polymerize by synthesis or condensation reaction. It is composed of synthetic resins and additives such as fillers, plasticizers, stabilizers, lubricants, and colorants. Most plastics have the advantages of light weight, chemical stability, no rust, good impact resistance, and good insulation. Therefore, plastics are widely used in stationery, catering, packaging and other fields. Among them, polyethylene plastic products have a wide range of applications. The disposable products made of polyethylene blown film are waterproof, oil-proof and dust-proof. They are widely used in home kitchen conditioning, clean and hygienic, easy to wear, economical and practical, and acid-resistant. Alkali resi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L51/06C08L97/00C08K9/04C08K3/04
CPCC08L51/06C08L2205/14C08L97/005C08K3/042C08K9/08
Inventor 张健
Owner 东营市东达机械制造有限责任公司
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