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Preparation method of aluminum-plastic composite film based on light click UV curing

An aluminum-plastic composite film, light click technology, applied in the direction of coating, primer, etc., can solve the problems of aluminized film drying time affecting production efficiency, uneven thickness of aluminized film, quality discount, etc., to shorten the drying time, Effects of excellent durability, excellent stability and viscoelasticity

Active Publication Date: 2021-12-17
SOUTH CHINA UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The time-consuming drying time of the aluminized film not only affects its production efficiency, but also makes the thickness of the aluminized film extremely uneven to a certain extent, resulting in a greatly reduced quality
However, at present, the method of rapid drying of aluminized film mainly adopts physical cooling, and it cannot be greatly shortened.

Method used

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  • Preparation method of aluminum-plastic composite film based on light click UV curing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Example 1 Select m-dibenzyl mercaptan and butyl methacrylate, which are capable of photoclick reaction, as mercapto monomers and acrylate monomers, and weigh 17.029g and 28.44g respectively. Dissolve the weighed medicine in 100 ml of absolute ethanol at the same time, stir it magnetically for 2 hours until fully mixed, and then set aside for later use.

[0025] Then 2,4,6-trimethylbenzoyl-diphenylphosphine oxide (TPO) was selected as the photoinitiator and 10% of the total mass of the mixture was weighed. Place the weighed photoinitiator into the fully mixed mixture of mercapto monomers and acrylate monomers again, and magnetically stir in a light-shielding bottle until a homogeneous phase is formed. The obtained polymerizable mixture was stored in the dark.

[0026] The polymerizable mixture is evenly coated on the polyethylene plastic film, and after being irradiated by UV light, a photoclick polymerization reaction can be initiated, and then the mixture can be parti...

Embodiment 2

[0030] 1,4-Benzene dimethyl mercaptan and 2-phenoxyethyl methacrylate, which can undergo optical click reaction, were selected as mercapto monomers and acrylate monomers, and 34.058 g and 82.496 g were weighed, respectively. Dissolve the weighed medicine in 150 ml of absolute ethanol at the same time, stir magnetically for 2 hours until fully mixed, and then set aside for later use.

[0031] Then 2,4,6-trimethylbenzoyl-diphenylphosphine oxide (TPO) was selected as the photoinitiator and 15% of the total mass of the mixture was weighed. Place the weighed photoinitiator into the fully mixed mixture of mercapto monomers and acrylate monomers again, and magnetically stir in a light-shielding bottle until a homogeneous phase is formed. The obtained polymerizable mixture was stored in the dark.

[0032] The polymerizable mixture is uniformly coated on the polyester film, and after being irradiated by UV light, a photoclick polymerization reaction can be initiated, and then the mixt...

Embodiment 3

[0035] 1,4-Benzyldimethylmercaptan and benzyl 2-propylacrylate, which can undergo optical click reaction, were selected as mercapto monomer and acrylate monomer respectively, and 34.058g and 81.704g were weighed respectively. Dissolve the weighed medicine in 150 ml of absolute ethanol at the same time, stir magnetically for 2 hours until fully mixed, and then set aside for later use.

[0036] Then 2,4,6-trimethylbenzoyl-diphenylphosphine oxide (TPO) was selected as the photoinitiator and 20% of the total mass of the mixture was weighed. Place the weighed photoinitiator into the fully mixed mixture of mercapto monomers and acrylate monomers again, and magnetically stir in a light-shielding bottle until a homogeneous phase is formed. The obtained polymerizable mixture was stored in the dark.

[0037] The polymerizable mixture is uniformly coated on the polyester film, and after being irradiated by UV light, a photoclick polymerization reaction can be initiated, and then the mix...

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Abstract

The invention discloses a preparation method of an aluminum-plastic composite film based on light click UV curing, and belongs to the technical field of printing and packaging. The method comprises the following steps: uniformly coating a plastic film with a mixture, initiating a light click polymerization reaction through UV light irradiation, and carrying out partial prepolymerization on the mixture, wherein the mixture comprises a sulfydryl monomer, an acrylate monomer, an organic solvent and a photoinitiator; then aluminizing the plastic film loaded with the prepolymerization mixture, so as to deposite aluminum steam on the surface of the plastic film; and after aluminum plating is completed, cooling the plastic film, and meanwhile continuing conducting UV irradiation, so as to completely polymerize the aluminum-plastic film. The drying time between the aluminum laminated film and the plastic film is shortened, and the production efficiency of the aluminum laminated film is improved.

Description

technical field [0001] The invention belongs to the technical field of printing and packaging, and relates to a UV curing glue used for fast drying of an aluminized film, in particular to a method for preparing an aluminum-plastic composite film based on light-click UV curing. Background technique [0002] Aluminized film is a composite material made by plating aluminum metal onto a plastic film. It has both the shading and UV protection properties of aluminum metal and the lightness and flexibility of plastic film. The extremely thin aluminum film reduces production costs, and the advantages of being flexible and rollable are more conducive to the storage and transportation of the aluminized film. In addition, its bright metallic color visual sense has broad application prospects in the field of printing and packaging. [0003] With the ever-expanding market demand for aluminized film in the fields of home improvement materials and product packaging, the production effici...

Claims

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Application Information

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IPC IPC(8): C08J7/04C08J7/043C08J7/06C08L23/06C08G75/045C09D181/02C09D5/00
CPCC08J7/0423C08J7/043C08J7/06C08G75/045C09D181/02C09D5/002C08J2323/06C08J2481/02
Inventor 陈广学蔡玲陈琳轶江子涵陈旭潮
Owner SOUTH CHINA UNIV OF TECH