Nano inorganic gel modifier and preparation method thereof

A technology of nano-modifier and gel modifier, which is applied in the direction of cement production, etc., can solve the problems of high cost, difficulty in fire prevention and high temperature resistance of organic materials, and easy aging, etc., and achieves simple preparation method, environmental protection and green performance, low cost low effect

Pending Publication Date: 2022-01-21
华筑绿建北京科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Existing science and technology generally believe that only the polymer structure formed by organic matter has the characteristics of resin, which manifests film-forming compactness, high cohesiveness, flexibility, etc. This characteristic is formed by crystallization and bonding of coarse and fine aggregates to form concrete What cement does not have, and therefore, for ultrafine aggregates such as tailings and aeolian sand, ordinary cement concrete can be added in a very limited amount and cannot be used on a large scale. However, organic polymer resins belong to the chemical industry and cause environmental pollution. Huge impact, at the same time the cost is extremely expensive, and at the same time, it is difficult for organic materials to achieve fire resistance and high temperature resistance, and at the same time, it is easy to age, and the performance of resistance to salt spray and acid-base salt solution is relatively insufficient, so it is possible to modify inorganic substances into organic polymer resins. It has become a new prospect in the field of new materials
[0003] The inventors have found that the surface activation energy can be stimulated by grinding the industrial and mining solid waste to the quasi-nano level through modern grinding equipment, but at this time the activation energy still cannot generate a strong adhesive force similar to that of polymer resin.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A nano-inorganic gel modifier provided in the embodiment of the present invention comprises the following components in terms of weight percentage: 20-30 parts of nano-inorganic resin, 10-20 parts of nano-modifier, made of lanthanide soluble rare earth salt 4-12 parts of water-soluble rare earth water-retaining agent, 0-0.6 parts of dispersant made of inorganic airgel, 0-0.4 parts of defoamer made of water-soluble silane defoamer, and different viscosities 0-3 parts of thickener mixed with hydroxypropyl methylcellulose, 40-60 parts of deionized water, the nano-inorganic resin is fused with inorganic silicon and organic silicon under strong alkali environment at high temperature, and mixed It is prepared by chemical grafting, and the nano-modifier is made of active silicon dioxide and active aluminum oxide processed into 20-100 nanometers, and dispersed in a strong alkaline liquid according to the ratio of 2:1-5:1 ;

[0021] Using the nano-inorganic gel modifier as the ...

Embodiment 2

[0029] A kind of nanometer inorganic gel modifying agent, is prepared according to the following method:

[0030] (1) Get the following raw materials according to the weight percentage:

[0031] 30 parts of nano-inorganic resin, 15 parts of nano-modifier, 10 parts of water-soluble rare earth, 0.3 part of dispersant, 0.2 part of soluble silane defoamer, 1.5 parts of various cellulose composite thickeners, 43 parts of water;

[0032] Dissolve in the order of nano-modifiers, thickeners, inorganic resins, dispersants, and defoamers. Stir for at least 10 minutes after each addition of a raw material, and ensure that each time before adding the next material, the Stir the mixture until it is in a solution state, and stir the mixture evenly for later use after the addition is complete;

[0033] (3) Stir the mixed solution obtained in step (2) evenly, add it to a constant temperature water bath reactor, set the temperature of the reactor water bath to 65°C, adjust the stirring speed ...

Embodiment 3

[0035] A kind of nano-inorganic gel modifier provided in this embodiment is prepared according to the following method:

[0036] (1) Get the following raw materials according to the weight percentage:

[0037] 26 parts of nano-inorganic resin, 20 parts of nano-modifier, 8 parts of water-soluble rare earth, 0.3 part of dispersant, 0.2 part of soluble silane defoamer, 1.5 parts of various cellulose composite thickeners, 44 parts of water;

[0038] (2) Dissolve in the order of nano-modifier, thickener, inorganic resin, dispersant, and defoamer. Stir for no less than 10 minutes after each raw material is added, and pay attention to ensure that each raw material is added before adding the next material. Stir the mixture to a solution state at a time; after the addition is complete, stir the mixture evenly for later use;

[0039]Stir the mixed solution obtained in step (2) evenly, add it to a constant temperature water bath reactor, set the temperature of the reactor water bath to ...

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PUM

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Abstract

The invention provides a nano inorganic gel modifier and a preparation method thereof, and relates to the field of engineering materials, the nano inorganic gel modifier comprises the following components in percentage by weight: 20-30 parts of nano inorganic resin, 10-20 parts of a nano modifier, 4-12 parts of a water-retaining agent water-soluble rare earth prepared from lanthanide series soluble rare earth salt, 0-0.6 part of a dispersing agent prepared from inorganic aerogel, 0-0.4 part of a defoaming agent prepared from a water-soluble silane defoaming agent, 0-3 parts of a thickening agent formed by mixing various hydroxypropyl methyl cellulose with different viscosities, and 40-60 parts of deionized water. In the invention, the nano inorganic gel modifier is used as a core material, is added into highly mechanically activated inorganic materials such as fly ash, saw mud, brick ash, steel slag, petuntse, red mud and the like, and is stirred at a high speed, so that a resin-like viscous inorganic new material can be synthesized, and the nano inorganic gel modifier is a novel material which has an application prospect and excellent environment-friendly performance.

Description

technical field [0001] The invention relates to the field of engineering materials, and in particular to an inorganic gel modifier and a preparation method thereof. Background technique [0002] Existing science and technology generally believe that only the polymer structure formed by organic matter has the characteristics of resin, which manifests film-forming compactness, high cohesiveness, flexibility, etc. This characteristic is formed by crystallization and bonding of coarse and fine aggregates to form concrete What cement does not have, and therefore, for ultrafine aggregates such as tailings and aeolian sand, ordinary cement concrete can be added in a very limited amount and cannot be used on a large scale. However, organic polymer resins belong to the chemical industry and cause environmental pollution. Huge impact, at the same time the cost is extremely expensive, and at the same time, it is difficult for organic materials to achieve fire resistance and high temper...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/42C04B28/00C04B7/26C04B111/27C04B111/20
CPCC04B40/0039C04B28/00C04B7/243C04B2111/27C04B2111/20C04B2111/00008C04B22/06C04B2103/465C04B2103/408C04B24/42C04B24/383C04B24/405C04B18/12C04B18/141C04B14/068Y02P40/10
Inventor 邓福南傅锋辉姚二小刘守辉李志浩
Owner 华筑绿建北京科技有限公司
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