Organic synthesis method based on green chemistry

A technology of organic synthesis and green chemistry, applied in organic chemistry methods, organic chemistry, etc., can solve problems such as aggravated environmental pollution, pollution, and ozone layer destruction, and achieve the effects of fast reaction rate, simple process, and high-efficiency chemical reaction

Inactive Publication Date: 2022-01-21
GUANGXI NORMAL UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] However, the chemical industry discharges a large amount of toxic and harmful substances to the environment, which leads to increasing environmental pollution, such as acid rain, the greenhouse effect, the destruction of the ozone layer, marine pollution, freshwater resource pollution, etc. Environmental problems have become one of the urgent international problems to be solved in the 21st century.

Method used

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Embodiment

[0026] A kind of organic synthesis method based on green chemistry, described organic synthesis method based on green chemistry comprises the following steps:

[0027] S1: Select green synthetic raw materials: dimethyl carbonate can be selected for use, and dimethyl carbonate can replace phosgene and dimethyl sulfate for organic synthesis; it also has many other uses such as the production of long-chain alkyl carbon esters and hydrazine carbonate; In step S1, the oxygen content of dimethyl carbonate molecule is high, up to 53%, which can replace methyl tert-butyl ether as a petroleum additive to reduce the environmental problems caused by MTBE;

[0028] S2: Select a non-toxic and harmless solvent: allylation reaction, aldol condensation, Michael addition, Mannich reaction, allylation of indium intervention, can choose to react in water; in step S2, the organic reaction operation in water It is simple, safe, and has no flammability and explosion problems of the medium; in organ...

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Abstract

The invention discloses an organic synthesis method based on green chemistry. According to the invention, a selected biocatalyst has the advantages of capability of reacting at normal temperature and normal pressure, high reaction rate, high catalytic efficiency, strong specificity, lower price and the like; and a heteropoly compound has an outstanding effect when being used as an environment-friendly solid acid catalyst with excellent performance for alkylation. And a supported heteropolyacid has the advantages of high activity, high selectivity, high product purity, reusable catalyst, simple process, easiness in continuous production and the like on esterification reaction, so that the supported heteropolyacid has a relatively great industrial prospect, conforms to the concept of green chemistry, increases the green environmental protection property in organic synthesis, and is suitable for industrial production. According to the method, high-selectivity and high-efficiency chemical reaction is realized, few byproducts are produced, zero emission is realized, and the reaction with high atom economy is realized. Compared with the chemical equivalent reaction, the high-selectivity and efficient catalytic reaction better meets the basic requirements of green chemistry.

Description

technical field [0001] The invention belongs to the technical field of organic synthesis, in particular to an organic synthesis method based on green chemistry. Background technique [0002] Organic synthesis refers to the process of making simple substances, simple inorganic substances or simple organic substances into more complex organic substances by chemical methods. For example, methanol is made from hydrogen and carbon dioxide; vinyl chloride is made from acetylene, and then polyvinyl chloride resin is obtained by polymerization; adipic acid and hexamethylenediamine are made from phenol through a series of reactions, and the two are condensed into polyamide 66 fiber . Most organic substances such as resins, rubber, fibers, dyes, medicines, fuels, spices, etc. can be obtained through organic synthesis. [0003] However, the chemical industry discharges a large amount of toxic and harmful substances to the environment, which leads to increasing environmental pollution...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07B61/00
CPCC07B61/00
Inventor 廖委聪李坤梁旺福韦锦松
Owner GUANGXI NORMAL UNIV
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