Barrier coating material for food paper and paperboard, food paper and paperboard
A food paper and coating technology, which is applied in the field of food paper, cardboard, barrier coating for cardboard and food paper, can solve the problems of easy adhesion and insufficient barrier performance, achieve good ethanol resistance, good continuity and airtightness, and improve Effect of water and oil repellency
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[0040] In some embodiments, the preparation method of the component A comprises the following steps:
[0041] ① Add water and emulsifier to the reaction bottle. ②Heating to raise the temperature, adding the pre-emulsified monomer mixture with a calculated Tg of -20-10°C and an initiator to initiate polymerization. ③Add neutralizer to adjust pH value, and obtain emulsion with particle size range of 0.02-0.2 microns through selection and matching of emulsifiers and adjustment of hydrophilic-lipophilic balance of monomers.
[0042] In some embodiments, the preparation method of the component B comprises the following steps:
[0043] ① Add water and emulsifier to the reaction bottle. ②Heating to raise the temperature, adding the pre-emulsified monomer mixture with a calculated Tg of 10-120°C and an initiator to initiate polymerization. The addition method of its monomer and initiator can be the same as the preparation process of component A, or a different addition method can b...
Embodiment 1
[0071] This embodiment is used to illustrate the barrier coating for food paper disclosed by the present invention, food paper and its preparation method, including the following steps:
[0072] Step 1: Prepare acrylate copolymer emulsion component A and acrylate copolymer emulsion component B by means of emulsion polymerization, and obtain acrylate emulsion component C by dispersion polymerization in an alcohol-water mixed solvent, wherein it has been determined that in component A: The solid content is 38.8%, the average particle size of the polyacrylate is 65nm, and the Tg value is -7°C. In component B: the solid content is 40.1%, the average particle diameter of polyacrylate is 71nm, and the Tg value is 50°C. In component C: the solid content is 20.7%, the average particle size of polyacrylate is 3.6 μm, and the Tg value is 103°C.
[0073] Step 2: Mix component A, component B and component C with a mass ratio of 46:46:8, add wetting agent, thickener, defoamer and pH regulat...
Embodiment 2
[0076] This embodiment is used to illustrate the barrier coating for food paper disclosed by the present invention, food paper and its preparation method, including the following steps:
[0077] Step 1: Prepare acrylate copolymer emulsion component A and acrylate copolymer emulsion component B by means of emulsion polymerization, and obtain acrylate emulsion component C by dispersion polymerization in an alcohol-water mixed solvent, wherein it has been determined that in component A: The solid content is 45.2%, the average particle diameter of the polyacrylate is 76nm, and the Tg value is -16°C. In component B: the solid content is 46.1%, the average particle diameter of polyacrylate is 52nm, and the Tg value is 58°C. In component C: the solid content is 25.3%, the average particle diameter of polyacrylate is 4.7 μm, and the Tg value is 95°C.
[0078] Step 2: Mix component A, component B and component C with a mass ratio of 65:35:7, add wetting agent, thickener, defoamer and ...
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