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Continuous modification and visbreaking process for crude oil

A crude oil and upgrading technology, which is applied in the petroleum industry, hydroprocessing process, and hydrocarbon oil treatment, can solve the problems of time difference advantage annihilation, etc., and achieve the effect of adjustable cracking depth, wide range of sources, and better product properties and distribution

Pending Publication Date: 2022-05-13
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the visbreaking of heavy oil into a liquid phase reaction, the hindered diffusion is the controlling step of the reaction of hydrocarbon molecules, and the advantage of this time difference is annihilated.

Method used

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  • Continuous modification and visbreaking process for crude oil
  • Continuous modification and visbreaking process for crude oil
  • Continuous modification and visbreaking process for crude oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] With Venezuelan super heavy oil as raw material and supercritical benzene as solvent, Venezuelan super heavy oil takes 400°C as the cut point, and is cut into two stages of <400°C distillate oil and 400°C+residue through distillation tower A. 400°C + residual oil is preheated by heating furnace B, mixed with benzene preheated by heating furnace A at a ratio of 1:3 (wt%) to obtain the target reaction temperature, and then the mixture enters an upflow vis-reducing reactor with a reaction pressure of 10MPa , the reaction temperature is 400°C, and the reaction residence time is 5 minutes. After the reaction, leave the visbreaking reactor from the top of the reactor, the visbreaking product enters the flash tower, and the solvent separated from the top of the tower is recycled back to the visbreaking reactor, and the bottom oil of the flash tower enters the distillation tower B, which is cut into IBP-180 The light distillate at the top of the tower, the side stream at 180-39...

Embodiment 2

[0067] Using Canadian oil sand bitumen as raw material and supercritical toluene as solvent, the oil sand bitumen takes 350°C as the cut point, and passes through distillation tower A to cut distillate oil <350°C and 350°C+residue. 350℃+residual oil is preheated by the heating furnace, and mixed with the preheated benzene solvent in a certain proportion, and the temperature after mixing can reach the reaction temperature. The mixture then enters an upflow vis-reducing reactor with a reaction pressure of 10 MPa, a reaction temperature of 410° C., and a reaction residence time of 3 minutes. After the reaction, the visbroken product leaves the visbroken reactor from the top of the reactor, and after heat exchange, the visbroken product is lowered to a suitable temperature and enters the flash tower. The product enters the distillation tower B, which is cut into IBP-200°C distillation tower B overhead distillate, 200-350°C side cut and 350°C+distillation tower B viscosity-reduced ...

Embodiment 3

[0091] Chadian crude oil is used as raw material, and Chadian crude oil is paraffinic base crude oil. Using supercritical benzene as the solvent and 540°C as the cut point, after distillation A, it is cut into distillation tower A distillate oil and distillation tower A residue oil. After the 540℃+ vacuum residue is preheated by the heating furnace, it is mixed with heated benzene in a certain proportion, and the temperature after mixing can reach the reaction temperature. The mixture then enters an upflow vis-reducing reactor for vis-reducing reaction, with a reaction pressure of 10 MPa, a reaction temperature of 360° C., and a reaction residence time of 5 minutes. After the reaction, the visbroken product leaves the visbroken reactor from the top of the reactor and enters the flash tower, and the benzene separated from the top of the tower is recycled back to the visbroken reactor, and the product obtained at the bottom of the flash tower enters the distillation tower B and ...

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Abstract

The invention relates to a continuous modification visbreaking process for crude oil. Crude oil such as oil sand asphalt firstly enters a distillation tower A to obtain light distillate oil and heavy distillate oil; the heavy fraction enters a visbreaking reactor, and rapid and efficient visbreaking is completed with the assistance of a solvent represented by aromatic hydrocarbon. Separating out a solvent from a visbreaking product through a flash tower, circulating the solvent back to the visbreaking reactor for recycling, feeding flash tower bottom oil into a distillation tower B, separating out tower top light oil, side distillate oil and tower bottom residual oil, and feeding the tower top light oil and the side distillate oil into a hydrogenation reactor for hydrogenation saturation of olefin. And mixing hydrogenated distillate oil, residual oil at the bottom of the visbreaking tower and light distillate oil obtained by cutting of the distillation tower A to finally obtain a crude oil visbreaking and modifying product. Crude oil can be directly transported for a long distance by adopting a pipeline or an oil tanker after being subjected to modification and viscosity reduction by the process. The process has the characteristics of low gas yield, low asphaltene increment, no coke generation, low reaction temperature, short reaction time, controllable cracking depth, low loss rate and the like, and the solvent can be easily separated from the product for cyclic utilization.

Description

technical field [0001] The invention relates to a modification and viscosity reduction process, in particular to a continuous modification and viscosity reduction process of crude oil. The modified product after deep and efficient viscosity reduction and hydrogenation can be directly transported by pipelines or tankers for long distances. Background technique [0002] In 2018, China's crude oil processing volume exceeded 600 million tons, of which the dependence on foreign countries reached 70%. In order to ensure national energy security, heavy crude oil including Venezuela, Ecuador, Chad, Sudan, and Canadian oil sand bitumen is also listed as an important potential energy source. [0003] The premise of processing unconventional crude oil such as heavy crude oil, heavy oil, ultra-heavy crude oil, oil sand bitumen, lake bitumen is to transport the oil sand bitumen to refineries in China or other countries through long-distance pipelines or tankers. Super-heavy oil is gener...

Claims

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Application Information

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IPC IPC(8): C10G67/02
CPCC10G67/02
Inventor 王丽涛袁佩青王路海刘银东李艳宋海朋韩爽许倩杨行袁渭康
Owner PETROCHINA CO LTD
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