Reversible thermochromic functional composite phase change material as well as preparation method and application thereof

A composite phase change material and thermochromic technology, applied in the direction of color-changing fluorescent materials, heat exchange materials, chemical instruments and methods, etc., can solve the problems of poor shape-setting packaging effect, low cost, and lack of color memory function, etc., to achieve Good anti-leakage effect and high phase change enthalpy

Pending Publication Date: 2022-07-08
GUILIN UNIV OF ELECTRONIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Aiming at the above-mentioned problems existing in the prior art, the present invention provides a reversible thermochromic functional composite phase-change heat storage material and a preparation method thereof. The raw materials used in the phase-change material are green and safe, and the cost is low. The combination of phase change materials, temperature triggers the phase change process and color change process at the same time, which effectively solves the problems in the prior art such as no color memory function, poor shape-setting packaging effect and poor reversible color stability.

Method used

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  • Reversible thermochromic functional composite phase change material as well as preparation method and application thereof
  • Reversible thermochromic functional composite phase change material as well as preparation method and application thereof
  • Reversible thermochromic functional composite phase change material as well as preparation method and application thereof

Examples

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Embodiment 1

[0048] A preparation method of a reversible thermochromic functional composite phase change material, comprising the following steps:

[0049] Step 1, preparation of the reversible thermochromic blend, the operation of step 1 was carried out under the condition of maintaining 60 ° C, firstly 3.48 g of stearyl alcohol was melted into a liquid state, and then, under stirring conditions, 0.17 g of crystal violet was added to the solution. The ester was added to the liquid stearyl alcohol and stirred for 10 min until the crystal violet lactone was completely dissolved. Then, 0.35 g of bisphenol A was added and stirred for 10 min until the bisphenol A was completely dissolved. The addition was stopped and cooled to 25°C naturally. , 4 g of reversible thermochromic blends with dark blue color at 25 °C can be obtained;

[0050] Step 2, the preparation of the reversible thermochromic functional composite phase change material, using a hot pressing method, under the condition of a hot ...

Embodiment 2

[0078] A preparation method of a reversible thermochromic functional composite phase change material with a stearyl alcohol content of 40%, the specific steps are the same as in Example 1, except that the addition of the stearyl alcohol in the step 1 is: 2.32 g, the added amount of olefin block copolymer OBC was 3.02 g, and the obtained sample was named TCPCM-40.

[0079] The phase change heat storage performance test results of TCPCM-40 are as follows image 3 As shown, the phase transition temperature of TCPCM-40 is 33.7-51.5°C, and the phase transition enthalpy value is 99.7-101.2 J / g. The phase transition enthalpy is lower than that of TCPCM-60.

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Abstract

The invention provides a reversible thermochromic functional composite phase change material which is prepared by the following steps: by taking crystal violet lactone, bisphenol A, stearyl alcohol and an olefin block copolymer OBC as raw materials, firstly melting and blending the crystal violet lactone, the bisphenol A and the stearyl alcohol to obtain a reversible thermochromic blend; and carrying out hot press molding on the reversible thermochromic blend and the olefin block copolymer OBC by adopting a hot press method, and naturally cooling to obtain the reversible thermochromic functional composite phase change material which has both the reversible thermochromic function and the phase change function and has the difference between the reversible thermochromic temperature and the phase change temperature less than 5 DEG C. The thermochromism process is a reversible process, crystal violet lactone provides a color-changing color base, bisphenol A causes thermochromism, and stearyl alcohol serves as a cosolvent to adjust the color-changing temperature. The preparation method has the advantages that the phase change material stearyl alcohol is used as a connecting bridge of a color change system and a phase change system, reversible thermochromism and phase change temperature are adjusted, and the phase change heat storage material has the phase change heat storage performance and the photothermal conversion performance at the same time.

Description

technical field [0001] The invention belongs to the technical field of reversible thermochromic functional composite phase change materials, and particularly relates to a reversible thermochromic functional composite phase change material and a preparation method and application thereof. Background technique [0002] In recent years, with the development of the economy, the problem of environmental pollution has gradually increased, and the energy crisis has become increasingly prominent. It is imminent to find efficient and environmentally friendly energy storage devices. Phase change materials, as a kind of efficient thermal energy storage methods, can absorb the heat of the environment and release heat to the environment when needed, so as to achieve the purpose of controlling the temperature of the surrounding environment. It has been used in solar energy utilization, waste heat recovery, intelligent air-conditioning buildings, agricultural greenhouses, battery thermal m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/06C09K9/02
CPCC09K5/063C09K9/02C09K2211/1088C09K2211/1007Y02E60/14
Inventor 徐芬杨瑜锴孙立贤管彦洵廖鹿敏周天昊劳剑浩王颖晶王瑜
Owner GUILIN UNIV OF ELECTRONIC TECH
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