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Soya protein/polyurethane/polyacrylonitrile blended composite fiber and its preparing method

A technology of soybean protein and polyacrylonitrile, which is applied in the field of preparation for wearing comfort

Inactive Publication Date: 2007-02-07
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a soybean protein / polyurethane / polyacrylonitrile blended composite fiber to overcome the defects of a single material;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Add 10 kg of soybean protein into 90 kg of dimethyl sulfoxide / urea mixed solvent, stir and slowly heat up to dissolve it fully, and obtain a transparent soybean protein solution; in the mixed solvent, the weight concentration of co-solvent urea is 10%;

[0026] 17 kilograms of polyacrylonitrile are dissolved in 83 kilograms of dimethylsulfoxide;

[0027] The weight solid content of synthetic polyurethane is 25% resin solution.

[0028] The above three solutions were mixed in proportion to prepare a spinning dope, wherein the soybean protein was 15 parts by weight, the polyurethane was 5 parts by weight, and the polyacrylonitrile was 80 parts by weight.

[0029] The total solid content of the terpolymer in the spinning dope is 18%.

[0030] The above-mentioned spinning stock solution was degassed and filtered through the spinneret and then pressed into the coagulation bath. The coagulation bath was 50% dimethyl sulfoxide aqueous solution, the bath temperature was 25° C....

Embodiment 2

[0032] Add 12 kg of soybean protein into 88 kg of dimethyl sulfoxide / urea mixed solvent, stir and slowly raise the temperature to fully dissolve it, and obtain a transparent soybean protein solution; in the mixed solvent, the weight concentration of co-solvent urea is 14%;

[0033] 20 kilograms of polyacrylonitrile are dissolved in 80 kilograms of dimethylsulfoxide;

[0034] Synthetic polyurethane solid content is 28% resin solution. The above three solutions were mixed in proportion to prepare a spinning dope, wherein the parts by weight of soybean protein were 12 parts by weight, the parts by weight of polyurethane were 8 parts by weight, and the parts by weight of polyacrylonitrile were 80 parts.

[0035] The total solid content of the terpolymer in the spinning dope is 20%.

[0036]The above-mentioned spinning stock solution was degassed and filtered through the spinneret and then pressed into the coagulation bath. The coagulation bath was 55% dimethyl sulfoxide aqueous s...

Embodiment 3

[0038] Add 15 kg of soybean protein into 85 kg of dimethyl sulfoxide / urea mixed solvent, stir and slowly heat up to fully dissolve it, and obtain a transparent soybean protein solution; in the mixed solvent, the weight concentration of co-solvent urea is 14%;

[0039] 20 kilograms of polyacrylonitrile are dissolved in 80 kilograms of dimethylsulfoxide;

[0040] Synthetic polyurethane solid content is 30% resin solution.

[0041] The above three solutions were mixed in proportion to prepare a spinning dope, wherein the soybean protein was 15 parts by weight, the polyurethane was 10 parts by weight, and the polyacrylonitrile was 75 parts by weight.

[0042] The total solid content of the terpolymer in the spinning dope is 20%.

[0043] The above-mentioned spinning stock solution was degassed and filtered through the spinneret and then pressed into the coagulation bath. The coagulation bath was 50% dimethyl sulfoxide aqueous solution, the bath temperature was 30° C., and the spi...

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Abstract

The invention discloses a manufacturing method for soyabean protein, polyammonia fats and polyacrylonitrile commixture compounding fiber. It takes dimethyl sulfoxide as solution to fully dissolving the three groups and forms the raw liquid for filature. The fiber would be produced by wet method. Using soyabean protein and polyammonia fat improves the moisture absorption, chromaticity, anti-static performace, resilience and comfort of the polyacrylonitrile. The invention could use the original device to manufacture the commixture compounding fiber and is benefit for the application for soyabean protein.

Description

technical field [0001] The invention belongs to the technical field of polymer synthetic fibers, and in particular relates to adding soybean protein and polyurethane to polyacrylonitrile fiber spinning stock solution to improve the dyeability, antistatic property and resilience of polyacrylonitrile fibers, and to improve the consumption of polyacrylonitrile fibers A preparation method for comfort. Background technique [0002] As a cheap substitute for silk and wool, the regenerated protein fiber based on protein has attracted great attention from the United States, Europe and Japan at the end of the 19th century. The industrialized production has not been realized due to reasons such as poor performance and high technical difficulty in preparation. Later, due to the development of the petrochemical industry and other reasons, researchers turned the research direction of new fibers to the development of synthetic fibers and regenerated cellulose fibers. Synthetic fibers hav...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/02D01F8/16D01F8/08D01D5/06D01D5/12
Inventor 顾利霞肖茹陈大俊朱庆芳
Owner DONGHUA UNIV