Polishing pad and polishing device
A polishing pad and polishing layer technology, which is applied in the direction of grinding devices, electrical components, circuits, etc., can solve the problems that are not fully resolved, the surface flatness of the semiconductor substrate is poor, and the bending tracking of the semiconductor substrate is poor.
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Embodiment 1
[0068] A foamed polyurethane sheet with a thickness of 5 mm (microrubber A hardness = 50 degrees, density; 0.77, average diameter of independent cells: 110 μm) was immersed in methyl methacrylate to which 0.1 parts by weight of azobisisobutyronitrile was added 24 hours. The foamed polyurethane sheet swollen with methyl methacrylate was sandwiched between glass plates and heated at 70° C. for 24 hours. After heating, it took out from a glass plate, vacuum-dried at 50 degreeC, and this was cut, and the polished layer of thickness 1.2mm was obtained. The microrubber A hardness of this polishing layer was 98 degrees, the density: 0.79, the average closed cell diameter: 150 μm, and the content ratio of polymethyl methacrylate was 69% by weight. Use Nitto Denko's double-sided adhesive tape No.591 (tensile modulus of elasticity below 0.1Mpa) to place 1mm of nitrile rubber (bulk modulus of elasticity = 140Mpa,; tensile modulus of elasticity = 4.5MPa) buffer layer Paste with the poli...
Embodiment 2
[0070] The polypropylene glycol of 30 parts by weight and the diphenylmethane diisocyanate of 40 parts by weight and the water of 0.8 parts by weight and the triethylamine of 0.3 parts by weight and the silicon defoamer of 0.3 parts by weight and the tin octoate of 0.9 parts by weight utilize RIM forming machine mixes, presses into the mold, press molding, makes the foamed polyurethane sheet material of thickness 1.5mm (hardness of microrubber A=50 degree, density; 0.51, the average diameter of independent cell: 40 μm). This foamed polyurethane was immersed in methyl methacrylate to which 0.1 parts by weight of azobisisobutyronitrile was added for 15 hours. The foamed polyurethane sheet swollen with methyl methacrylate was sandwiched between glass plates and heated at 70° C. for 24 hours. After heating, it was taken out from the glass plate, vacuum-dried at 50° C., and both sides of the obtained hard foam sheet were cut to prepare a polishing pad with a thickness of 1.2 mm. T...
Embodiment 3
[0073] 78 parts by weight of polyether-based polyurethane polymer (Aciprene L-325 manufactured by Yuniro-Al Corporation), 20 parts by weight of 4,4'-methylene-bis-2-chloroaniline and 18 parts by weight of hollow polymer Microspheres (Expancell 551 DE manufactured by Kemano-Bell Co., Ltd.) were mixed with a RIM molding machine, and pressed into a mold to form a polymer molded body. This polymer molded body was sliced to a thickness of 1.2 m using a microtome to obtain a polished layer. Micro rubber A hardness of the polishing layer=98 degrees, density: 0.80, average independent cell diameter: 33 μm). With 1mm neoprene (bulk modulus=100Mpa, tensile modulus=12MPa) as buffer layer, utilize Sumitomo 3M (strain) double-sided adhesive tape Y-949 (tensile modulus is 10Mpa) and The polishing layers are pasted to each other to make a polishing pad. Using a silicon dioxide-based polishing agent, the oxide film polishing rate was evaluated under the evaluation condition C of the plate...
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