Method for extracting copper for copper containing sulfurized ore

A mineral and sulfuric acid technology, applied in the field of copper extraction from copper-bearing sulfide minerals, can solve problems such as ineffectiveness, inability to handle copper concentrates alone, excess sulfuric acid, etc.

Inactive Publication Date: 2002-07-17
BEIJING GENERAL RES INST OF MINING & METALLURGY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the following major problems still exist in pyrometallurgy: 1) In order to reduce the investment cost and operating cost of unit product, the scale of copper smelting plants is very large now, and it is necessary to transport the concentrate from other ore-producing places, even from abroad, so it is necessary to Pay the freight of the concentrate, and also bring the metal loss caused by the concentrate during the long-distance transportation; 2) The flue gas SO produced by the pyrometallurgy plant 2 and soot must be processed at a lot of co...

Method used

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  • Method for extracting copper for copper containing sulfurized ore
  • Method for extracting copper for copper containing sulfurized ore

Examples

Experimental program
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Effect test

example 1

[0048] Composition (%) of copper minerals used for leaching: Cu 10.58, Zn 2.57, Fe 31.93, S39.33.

[0049] Pressure leaching conditions are as follows: Grind the copper concentrate until the particle size is -44μm and account for more than 90%, take 200g ore sample, leaching temperature 110°C, oxygen partial pressure 100kPa, initial sulfuric acid concentration = 20g / l, [NaCl] = 85g / l, the liquid-solid ratio is 5 / 1, and the reaction time is 2 hours.

[0050] Leaching rate (%)

example 2

[0052] Composition (%) of copper minerals used for leaching: Cu 10.58, Zn 2.57, Fe 31.93, S39.33.

[0053] Pressure leaching conditions are as follows: Grind the copper concentrate until the particle size is -44μm and account for more than 90%, take 200g ore sample, leaching temperature 105°C, oxygen partial pressure 150kPa, initial sulfuric acid concentration = 25g / l, [NaCl] = 90g / l, the liquid-solid ratio is 5 / 1, and the reaction time is 2 hours.

[0054] Leaching rate (%)

example 3

[0056] Composition (%) of the leached copper concentrate used: Cu 25.82, Zn 2.91, Fe 29.10, S35.02.

[0057] Pressure leaching conditions are as follows: Grind the copper concentrate until the particle size is -44μm and account for more than 90%, take a 50g ore sample, leaching temperature 110°C, oxygen partial pressure 100kPa, initial sulfuric acid concentration = 60g / l, [NaCl] = 90g / l, the liquid-solid ratio is 5 / 1, and the reaction time is 2 hours.

[0058] Leaching rate (%)

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Abstract

The method for extracting copper from copper-bearing sulfide mineral is characterized by leaching copper-bearing mineral under the condition of introduction of oxygen and in the presence of sulfuric acid and chlorine ion, the liquid-solid ratio of leaching-out liquor is 1-8:1, primary concentration of sulfuric acid is 5-70 g/L, leaching total pressure is 200-1000 kPa, partial pressure of oxygen is 100-800 kPa, temp. is 100-130 deg.C and time is 1-4 hr. The leaching temp. and pressure of said method are low, its selectivity is good, the pyrite can not be oxidated, and the harmful impurity, for example arsenic, can be solidifed in arsenic-ion slag, so that it is a process friendly to environment.

Description

(1) Technical field [0001] A method for extracting copper from copper-containing sulfide minerals, relating to a method for extracting copper from copper-containing sulfide minerals or concentrates by pressure leaching, especially suitable for extracting copper-containing sulfide minerals or refractory copper-containing minerals, Such as the process of extracting copper from chalcopyrite, arsenic-containing copper sulfide ore, and copper-zinc mixed sulfide ore. (2) Background technology [0002] So far, pyrometallurgy still occupies a dominant position in the copper industry, especially for copper concentrates with chalcopyrite as the main mineral, ore dressing and pyrometallurgy are still the only industrialized technical routes. Although in recent years, the world's copper smelting technology has made great progress, flash smelting and various molten pool smelting technologies have basically replaced the traditional blast furnace, reverberatory furnace and electric furnace...

Claims

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Application Information

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IPC IPC(8): C22B3/08C22B3/30
CPCY02P10/20
Inventor 蒋开喜刘大星王海北王春谢福标李岚林江顺
Owner BEIJING GENERAL RES INST OF MINING & METALLURGY
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