Anti-electrostatic nano compound polyester fibre and making method thereof

A nano-composite, polyester fiber technology, applied in the direction of conductive/antistatic filament manufacturing, conjugated synthetic polymer artificial filament, etc., can solve the problems of poor antistatic performance and reduced strength

Inactive Publication Date: 2002-10-02
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] As we all know, the dispersion effect of nanomaterials in the matrix greatly affects their excellent properties, and this problem is particularly prominent in fiber research, mainly reflected in poor antistatic properties and a sharp drop in strength

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Adopt direct esterification to synthesize the accelerator iPET-PEG containing 4% (relative to TPA weight ratio) of isophthalic acid and 30% (relative to TPA weight ratio) of PEG (M=1000); the antistatic masterbatch is It is made by blending and granulating commercial ATO nano powder and HCDP chips, the dispersant is PVP, and the content of nano powder is 5%. The accelerator, masterbatch, and HCDP chips are ternary blended and spun in a ratio of 12:6:82, the spinning speed is 1000 m / min, and the draw ratio of the fiber is 3.5 times.

Embodiment 2

[0024] Adopt direct esterification to synthesize the accelerator IPET-PEG containing 4% (relative to PTA weight ratio) of isophthalic acid and 30% (relative to PTA weight ratio) of PEG (M=2000); the antistatic masterbatch is It is made by blending and granulating the nanopowder of the mixture of antimony oxide and tin oxide (the trade name is ATO) and HCDP chips, the dispersant is PVP, and the content of the nanopowder is 5%. The accelerator, masterbatch, and HCDP chips are ternary blended and spun in a ratio of 10:5:85, the spinning speed is 1000 m / min, and the draw ratio of the fiber is 3.5 times.

Embodiment 3

[0026]Adopt direct esterification method to synthesize the accelerator IPET-PEG containing isophthalic acid 4% (relative to PTA weight ratio), containing PEG (M=4000) 30% (relative to PTA weight ratio); antistatic masterbatch is It is made by blending and granulating ATO nano powder and HCDP slices, the dispersant is PVP, and the content of nano powder is 5%. The accelerator, masterbatch, and HCDP chips are ternary blended and spun in a ratio of 10:5:85, the spinning speed is 1000 m / min, and the draw ratio of the fiber is 3.5 times.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The antistatic nano composite polyester fibre is made of polyester or modified polyester, promotor and nano powder body through the processes of mixing and melt-spinning, in which the promotor is a condensation product of copolyester containing metaphenylene and polyethylene glycol, and can effectively improve dispersion property of nano powder body in the polyester or modified polyester, and possesses antistatic synergistic effect, and said nano powder body is a metal oxide with good conductivity.

Description

technical field [0001] The invention relates to an antistatic nanocomposite polyester fiber and a preparation method. The fiber is made of polyester (PET) or modified polyester, accelerant and nano-powder by ternary blending and melt-spinning. The accelerator is the condensation product of m-benzene-containing copolyester and polyethylene glycol (PEG), which can effectively improve the dispersion of nano-powder in polyester or modified polyester, and has antistatic synergistic effect; The powder is a metal oxide with good electrical conductivity. The nanocomposite fiber has high mechanical properties and good antistatic effect. Background of the invention [0002] Polyester fiber is the most widely used synthetic fiber, but due to its dense crystal structure and low moisture absorption capacity, it leads to the accumulation of static charge, which brings inconvenience to production and use, so the antistatic modification of polyester fiber has been is a research hotspot. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F1/09D01F8/14
Inventor 顾利霞李鑫仲蕾兰刘润涛顾利琴
Owner DONGHUA UNIV
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