Method for preparing nano tube of some metalloid oxides and metals with size and shape being controllable

An amphoteric metal, metal nanotechnology, used in oxide/hydroxide preparation, nanotechnology for materials and surface science, nanostructure fabrication, etc.

Inactive Publication Date: 2003-12-24
NORTHEAST NORMAL UNIVERSITY
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[0007] Preparation of Cu nanotubes: 1mmol CuCl 2 ·H 2 O was dissolved in 5ml deionized water, then, this solution was slowly added dropwise to 130ml NaOH(3M) solution, stirred well, and then 3mmol C was added 16 TMABr (hexadecyl trimethyl amine bromide, condensed to CTAB), stir well at 40-50 ℃ until the surfactant is completely dissolved, a clear and transparent solution is obtained, and 1ml of hydrazine hydrate (N 2 H 4 ) Solution, the homogeneous solution obtained by stirring is further reacted at 20-70°C for 3-7 hours to obtain a dark red precipitate. The product is separated by centrifugation, and washed repeatedly with absolute ethanol and deionized water for 5-8 times to make the surface active The agent and other inorganic ions are completely removed, and then the precipitate is separated by centrifugation, and dried under vacuum at room temperature for 4-5 hours to obtain the product Cu nanotubes with a yield of 95% (calculated as Cu).

[0008] Cu 2 Preparation of O nanotu...

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Abstract

A process for preparing the size and shape controllable ampholytic metal oxides and their metallic nanotubes features that based on the principle that under existance of excessive alkali the ampholytic metal hydroxide can become coordinate anions, under the action of surfactant as "soft template", the ampholytic metal oxide and its metallic nanotubes can be prepared by direct hydrothermal reaction or redox reaction (for example, ZnO, CuO, Al2O3, PbO2, SnO2 and relative metals). Its advantages are simple process, controllable sizes of nanotube, uniform wall thickness, and high output.

Description

Technical field [0001] The invention belongs to a method for preparing nano materials. Background technique [0002] Since the discovery of carbon nanotubes by the Japanese scientist Iijima in 1991, one-dimensional nanostructures, including nanowires, nanorods, nanotubes, nanoribbons, nanofibers, etc., have attracted the attention of many domestic and foreign chemistry, physics and materials scientists. Of great interest, this is because one-dimensional nanomaterials present unique physical and chemical properties different from their bulk, and broad application prospects. In the past ten years, nanotubes with carbon nanotubes as the core have received widespread attention, and most of the work has been devoted to the development of nanotube preparation methods and the study of properties. In recent years, breakthroughs have been made in the research on nanotubes. Single-walled carbon nanotubes and multi-walled carbon nanotubes, carbides, metals, oxides, and sulfides with a diame...

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Application Information

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IPC IPC(8): C01B13/14C30B7/00C30B29/60
CPCC01P2004/13B82Y30/00C30B29/605C30B7/00C01B13/14
Inventor 胡长文曹敏花
Owner NORTHEAST NORMAL UNIVERSITY
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