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Finish for pre-coating coiled material

A technology for topcoats and coils, applied in coatings, polyester coatings, etc., can solve the problems of inability to cure the paint film and high curing temperature, and achieve the effect of suitable hardness, flexibility and reasonable matching

Inactive Publication Date: 2004-02-11
CNOOC CHANGZHOU PAINT & COATINGS IND RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

European patent EP686678 discloses a precoated coil topcoat prepared with polyester resin, amino resin or urea-formaldehyde resin, catalyst, pigment, wax, polysiloxane, polyacrylic acid, etc., although a thickness of 40-55 μm can be obtained However, the curing temperature of this topcoat is higher than 260 °C, and the paint film cannot be completely cured in the oven that usually produces pre-coated coils.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment 1 prepares saturated polyester resin A

[0015] 1. See Table 1 for the formula

[0016]

components

raw material

Dosage

(kg)

name

Specification

Triols

diol

Trimethylolpropane

Propylene Glycol

Industrial products

Industrial products

46

318

Aromatic dibasic acid

Aliphatic dibasic acid

Isophthalic acid

Adipic acid

Industrial products

Industrial products

500

147

catalyst

Dibutyltin dilaurate

Analytical pure

1

solvent

High boiling point aromatic solvent oil 1500 #

Industrial products

272

High boiling point aromatic solvent oil 2000 #

Industrial products

272

[0017] 2. Craft

[0018] In a clean reaction kettle equipped with a thermometer, agitator, reflux condenser, and head tank, add all the other components in the formula except the catalyst into the reaction ...

Embodiment 2

[0019] Embodiment 2 prepares fully blocked polyisocyanate A

[0020] 1. See Table 2 for the formula

[0021]

[0022] In a clean reactor equipped with a thermometer, agitator, reflux condenser, and head tank, add xylene, N3390, and dibutyltin dilaurate and stir evenly, then add caprolactam at one time, keep warm with ice water, and make the reaction temperature lower than 50°C, then keep warm for 2-3 hours to ensure the complete reaction. Then add ethylene glycol ethyl ether dropwise and control the dropping speed to ensure that the temperature is lower than 50°C. Finally, add polyether N-220, raise the temperature to 100-120°C, and keep it warm for 2-3 hours. When the measured NCO value is less than 0.5%, it is Qualified, cool down and discharge, and keep away from light for future use. 19% of the NCO groups of the obtained fully blocked isocyanate are blocked by polyether N-220, and the solid content is 65.1%.

Embodiment 3

[0023] Embodiment 3 prepares pigment slurry A

[0024] 1. See Table 3 for the formula

[0025]

components

raw material

Dosage(kg)

name

Specification

saturated polyester resin

Example 1

Homemade, 65% solids

200

paint

Rutile titanium dioxide 2310

Produced by Kronos

400

Dispersant

BYK180

Produced by BYK

8

solvent

High boiling point aromatic solvent oil

1500 #

Industrial products

100

[0026] 2. Craft

[0027] Add the saturated polyester resin, pigment, dispersant and solvent in the formula in sequence in a clean tank, and use a high-speed disperser to disperse at a high speed while controlling the temperature below 40°C. Measure the fineness after 1 hour, discharge when it is less than 10 μm, and store it in the dark for future use. The solid content of the pigment slurry is 75.9%, and the pigment-base ratio is 3:1.

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PUM

PropertyMeasurementUnit
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Abstract

The finish for pre-coating coiled material consists of saturated polyester resin with linear and / or branched chain structure and acid value less than 5 mg KOH / g 10-50 wt%, amino resin 1-30 wt%, polyisocyanate closed with at least two kinds of closing agent with active hydrogen 1-30 wt%, pigment slurry 40-87 wt% and assistant 0.1-5.0 wt%. It is homogeneous white ropy liquid mixture, and has coating-4 viscosity at 23 deg.c 20-200 sec and solid content 40-80 wt%. It is coated and stoved at 200-260 deg.c for 20-90 sec to form dry film of 8-35 micron thickness. The film can fulfill the requirement for pre-coating coiled material.

Description

technical field [0001] The invention relates to a topcoat for precoated coils. Background technique [0002] Since the pre-coated coil entered industrialization in the 1940s, its usage has continued to expand. Pre-coated coil coatings have also been continuously developed with the large number of applications of pre-coated coils, and their varieties have developed from a single variety to dozens of varieties at present. In different fields of use, the performance requirements for precoated coil coatings are also different. At present, the types of coatings used for pre-coated coil topcoats are mainly polyester coatings, and there are many varieties according to different application fields. European patent EP686678 discloses a precoated coil topcoat prepared with polyester resin, amino resin or urea-formaldehyde resin, catalyst, pigment, wax, polysiloxane, polyacrylic acid, etc., although a thickness of 40-55 μm can be obtained However, the curing temperature of this topc...

Claims

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Application Information

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IPC IPC(8): C09D167/00
Inventor 胡靖暐罗志刚李大鸣甘崇宁杨春娣
Owner CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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