205 results about "Nylon 12" patented technology

The present invention relates to a sinter powder composed of polyamide which also comprises metal salts of weak acids, in particular metal carbonates, and fatty acid derivatives, in particular fatty acid esters or fatty acid amides, to a process for laser sintering, and also to moldings produced from this sinter powder. The moldings formed using the powder of the invention have marked advantages in appearance and in surface finish when compared with conventional products, especially when recyclability in the selective laser sintering (SLS) process is taken into account. Moldings produced from recycled sinter powder of the invention moreover also have markedly improved mechanical properties when compared with moldings based on recycled conventional nylon-12 powders, in particular in terms of modulus of elasticity and tensile strain at break. These moldings also have a density approaching that of injection moldings.

A multi-layer structure excellent in the barrier properties against alcohol gasoline, particularly hydrocarbon components, and also excellent in the interlayer adhesion, low-temperature impact resistance, heat resistance and chemical resistance is provided. The stractive is a multi-layer structure comprising two or more layers including at least a layer (a) comprising (A) nylon 11 and/or nylon 12 and a layer (b) comprising (B) a polyamide resin (nylon 9T) consisting of a dicarboxylic acid component and a-diamine component, with 60 to 100 mol % of the dicarboxylic acid component being a terephthalic acid and 60 to 100 mol % of the diamine component being a diamine component selected from 1,9-nonanediamine and 2-methyl-1,8-octanediamine, and preferably further including a layer (c) comprising (A) nylon 11 and/or nylon 12 or (C) nylon 6.

The present invention relates to a sinter powder composed of polyamide which also comprises PMMI, PMMA, or copolymers with PMMI, in particular PMMI-PMMA copolymers, to the use of this sinter powder for laser-sintering, and also to moldings produced from this sinter powder. The moldings made from the powder of the invention have marked advantages over conventional products in their appearance and in their surface quality, especially as far as roughness and dimensional stability during selective laser sintering (SLS) are concerned. In addition, moldings produced from the sinter powder of the invention also have better mechanical properties than moldings based on conventional nylon-12 powders, in particular in terms of modulus of elasticity and tensile strength. These moldings also have a density close to that of injection moldings.

A copolymer of nylon 6 (caprolactam mer units) and nylon 12 (dodecanolactam mer units) and/or nylon 11 (undecanolactam mer units), which has been modified to provide improved physical properties, such as flex modulus, elastic modulus, and yield strength, serves as a layer of a hose suited to use in airbrake applications. The modified copolymer is resistant to degradation by zinc chloride and moisture and thus may be used as a peripheral layer of the hose in place of a conventional protective layer comprising a pure polyamide, such as nylon 11 or 12. Alternatively, the modified copolymer may be used as a tie layer for rendering a peripheral layer comprising nylon 12 or 11 compatible with a layer of nylon 6, allowing the less expensive nylon 6 material to comprise the bulk of the hose thickness. The layer includes a compatibilizer, such as a maleic anhydride grafted polyethylene, and may also include plasticizers and impact modifiers.

The invention relates to a high-temperature resistant PTC electroconductive composition, which comprises 20 to 70 percent of organic polymers, 25 to 75 percent of electroconductive filler, 1 to 30 percent of inorganic filler and 0.1 to 10 percent of additive, wherein the preferred melting point of the organic polymers is more than 150 DEG C; the organic polymers are one or more crystalline or semi-crystalline polymers and made of one or more of nylon 11, nylon 12, polyvinylidene fluoride, soluble poly(tetrafluoroethylene), ethylene-tetrafluoroethylene copolymers, perfluoroethylene-propylene, ethylene-chlorotrifluoroethylene and copolymers thereof. The invention also provides a high-temperature resistant PTC device containing the composition and a manufacturing method thereof. The high-temperature resistant PTC device containing the composition has low resistance, high PTC strength and superior resistance stability, so that the high-temperature resistant PTC device can be used for overcurrent protection of circuits in high-temperature environments such as automobile motors and the like. Moreover, the high-temperature resistant PTC device is simple and convenient to manufacture and has high efficiency.

Elongate, flexible catheter includes an elongated shaft having a proximal end, a distal end, and a lumen defined therein. The shaft includes a tubular member having an outer layer and an inner layer. The outer layer includes a first polymer selected from the group consisting of nylon 12, polyether block amide, and combinations thereof. The inner layer includes a second polymer having a heat deflection temperature greater than about 53° C. selected from the group consisting of nylon 11, nylon 6, nylon 6,6, nylon 6,12, polyamide-imide, polyetherimide, polypropylene, polyethylene terephthalate, polybutylene terephthalate, polyethereetherketone, and combinations thereof. Method of making an elongate, flexible catheter is also provided.

This invention relates to a high molecular weight nylon powder composition for 3D printing, its preparation method and use. The composition comprises: 100 parts by weight of high-viscosity nylon powder, 1-5 parts by weight of a flow agent, and 0.1-1 parts by weight of an antioxidant; the high-viscosity nylon powder is one or more selected from nylon 6, nylon 66, nylon 11, nylon 12, nylon 612 and nylon 610; or the powder composition is obtained via polymerization reaction of the raw materials comprising the following components, based on the weight parts of lactam monomers or amide monomers: 100 parts by weight of lactam monomers or amide monomers, 0.005-1 parts by weight of a catalyst, and 0.1-1 parts by weight of an antioxidant. The high molecular weight nylon powder composition prepared in the present invention has a particle diameter in the range of 20-100 micrometers, good powder spreading performance, and is suitable for the 3D printing process, and the product of the high molecular weight nylon powder composition has good mechanical properties, good dimensional stability and low manufacturing cost.

The invention discloses a 125 DEG C irradiation crosslinking oil-resistant low-smoke halogen-free flame retardant cable material which is characterized in that a raw material formula consists of the following materials in parts by weight: 100 parts of ethylene vinyl acetate copolymer EVA, 5-15 parts of nylon 12 elastomer, 4-12 parts of nylon 12 grafted maleic anhydride copolymer, 120-165 parts of a magnesium hydrate flame retardant, 1.5-6.0 parts of a montmorillonoid synergic flame retardant, 2-4 parts of silicone master batch, 0.8-1.2 parts of a lubricant, 2-3 parts of a crosslinking sensitizing agent triallyl isocyanuric acid ester TAIC, 0.7-1.5 parts of a silane coupling agent, 0.7-1.2 parts of an antioxidant 1010, 0.7-1.2 parts of an antioxidant DLTP and 0.3-0.8 part of an anti-aging agent RD. By adopting the scheme, a halogen-free flame retardant insulating mixture material and a sheath mixture material which meet the EN50264 standard can be produced, the materials are good in comprehensive properties such as oil resistance, wearing resistance, flame retardancy, a machining process of a locomotive cable is simplified, and social values are achieved when the oil-resistant locomotive cable is used.

The invention composed of following component: ferrite magnetic powder, 80.0wt%-95.0wt%; nylon 12, 4.0wt%-20.0wt%; additive, 0.01wt%-3.0wt%; Its feature is:The additive consists of organic outside lubricant and inorganic inner lubricant, which can increase the fluidity of ingredients in tube, reduce decompose and oxidation of nylon 12 and palletizing temperature.

The invention relates to the technical field of polymer composites and particularly relates to a low-temperature nylon powder material for selective laser sintering. The low-temperature nylon powder material mainly comprises nylon 12 particles, dodecanedioic acid, double amino-terminated polyethylene glycol, deuterated trifluoroacetic acid, an antioxidant, a solvent, a nucleating agent, a plasticizer and a silane coupling agent. The low-temperature nylon powder material is prepared by the following steps: uniformly mixing the dodecanedioic acid and nylon 12 particles and putting into a reaction kettle; adding the double amino-terminated polyethylene glycol and deuterated trifluoroacetic acid into the reaction kettle; heating and starting stirring to obtain a product; putting the product together with the antioxidant, solvent, nucleating agent, plasticizer and silane coupling agent into the reaction kettle, and closing the kettle with a cover; vacuumizing the reaction kettle and introducing nitrogen displacement for protection; starting stirring and reducing the temperature of the kettle body to room temperature; taking out the materials, drying and performing ball milling; and drying the powder to obtain powder with good sphericity and fluidity. The low-temperature nylon powder material provided by the invention has the characteristics of low preheating temperature, wide preheating window, good aging resistance and adaptability to table boards of various specifications.

The invention provides a special nylon 66 composition for an automobile engine hood. The composition contains the following components by weight percent: 18-79% of nylon 66, 5-20% of copolymer nylon or long-chain nylon, 15-35% of alkali-free short glass fiber, 0-20% of mineral filler and 1.0-7% of auxiliaries, wherein the copolymer nylon is a polymer which is prepared through reaction, dehydration and polymerization of two or more monomer units, contains an amide group and is selected from one of or the mixture of more of a nylon6/66 copolymer, a nylon 6/12 copolymer and a nylon 6/10 copolymer; and the long-chain nylon is a polymer which is prepared through polymerization of monomers with carbon contents greater than or equal to 10 in polymer monomer units and other monomer units, contains an amide group and is selected from one of or the mixture of more of a nylon 11, a nylon 12 and a nylon 1010. The invention provides the special nylon 66 composition for the automobile engine hood and a preparation method thereof. The composition has the beneficial effects that the composition has quite high impact resistance and super strength and excellent chemical properties and dimensional stability; and products have smooth and clean surfaces and are cheap.

The present invention relates to a polymeric adhesive matrix and to a process for producing such a polymeric adhesive matrix, wherein the matrix comprises either: 1) a substantially uniform thickness nonwoven web comprising Nylon 12 or Nylon 11 polymer, or blends thereof, with up to 40 weight percent of another compatible thermoplastic polymeric material; or 2) a substantially uniform thickness fibrous or non-fibrous matrix comprising an amine-terminated low moisture absorbing polyamide, preferably an amine-terminated Nylon 12 or amine-terminated Nylon 11 polymer, or blends thereof, with up to 40 weight percent of another compatible thermoplastic polymeric material. The subject invention also relates to a multi-layer composite laminate comprising at least one layer of the polymeric adhesive matrix of the present invention positioned between a plurality of reinforcing fibrous layers impregnated with a binder resin and to a process for producing such a multi-layer composite laminate.

Disclosed is a composition comprising polyamide comprising nylon-6 and optionally nylon-6,66, nylon-66, nylon-610, nylon-612, nylon-11, nylon-12 and an ionomer comprising an ethylene carboxylic acid copolymer, wherein 30 to 90% of the total carboxylic acid functionalities are neutralized to salts with a mixture of zinc cations and cations of a second metal selected from Group 1 of the Periodic Table of the Elements wherein the salts comprise from 20 to 90% equivalents of zinc. Articles prepared from the composition have improved salt stress crack resistance when exposed to zinc chloride solutions.

The invention discloses a method for preparing environment-friendly thermo-activatable self-adhesive paint. It takes dimethylbenzene, natural methyl phenol and butyl alcohol as solvent, takes nylon 12, coploymerized nylon and phenoxy resin as main raw material, takes parting compound, levelling agent and lubricating agent as addictive auxiliary, prepares intermediate product by adding nylon 12 and ploymerized nylon into solvent, then adds additive auxiliary agent and phenoxy resin into solvent to produce final product. The invention is characterized in that it takes dimethylbenzene, natural methyl phenol and butyl alcohol as solvent, which avoids peculiar smell generation, all raw material possess good thermal stability and volatize lttle smell, which meets environment- friendly RoHS standard promulgated by European Union; the solubility between phenoxy resin and nylon is pretty good, and it is convenient for japanning in enamelcovered wire preparation process; the added proper addictive auxiliary ensures excellent demoulding for wire shaping and metal.

The present invention relates to a multilayer tube comprising, in its radial direction from the outside inwards: an optional layer (1) made of nylon-11 or nylon-12 polyamide; an intermediate layer (2) comprising by weight, the total being 100%: 50 to 100% of at least one polyamide A1 of formula X,Y/Z or 6,Y2/Z, in which X denotes residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms, Z denotes at least one unit chosen from residues of a lactam, residues of an α,Ω-aminocarboxylic acid, the unit X1,Y1, in which X1 denotes residues of a diamine and Y1 denotes residues of a diacid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%, and 0 to 50% of nylon-11 or nylon-12 polyamide; an optional layer (3) made of nylon-11 or nylon-12 polyamide, with the condition that at least one of the layers (1) and (3) is present; the layers being successive and adhering to one another, the inner layer being the layer in contact with the fluid transported.

A laminated body having a thermoplastic resin layer (I) and a polyamide resin layer (II) which is made of nylon 11 and/or nylon 12. The thermoplastic resin layer (I) includes 100 parts by weight of a polyamide resin composition (A) and 0.1 to 10 parts by weight of a carbodiimide compound (B) having two or more carbodiimide groups. The polyamide resin composition (A) contains a polyamide resin (a-1) having diamine units 70 mol % or more of which are derived from m-xylylenediamine and dicarboxylic acid units 70 mol % or more of which are derived from a C₄ to C₂₀ α,ω-linear aliphatic dicarboxylic acid and a nylon 12 and/or nylon 11 component (a-2) in an amount of 5 to 95% by weight of the component (a-1) and 95 to 5% by weight of the component (a-2) each based on a total weight of the components (a-1) and (a-2). The laminated body is excellent in the barrier property, peeling resistance and mechanical properties such as strength, impact resistance and elongation, particularly in the barrier property to alcohol-containing fuels.

The invention discloses a modified nylon powder coating and a preparation method thereof. The preparation method comprises the following steps of: firstly preparing a polymerization product by performing polymerization reaction on the following main synthetic materials in parts by mass: 50 to 80 parts of caprolactam or nylon 6 resin, 20 to 50 parts of nylon 66 salt, nylon 66 resin or equal mole ratio of hexamethylene diamine and hexanedioic acid, and 0.02 to 1.7 parts of an auxiliary agent; and then preparing the modified nylon powder coating through the processes of extrusion modification, deep cooling crushing and treatment with a powder surface treatment agent. The auxiliary agent comprises an antioxidant, a nucleating agent and a molecular weight adjusting agent. The modified nylon powder coating prepared by the method is lower in melting point, simple in process control and stable in product quality, can partially substitute nylon 11 and nylon 12 powder products, can effectively reduce the using cost of nylon powder, is favorable for application popularization of the nylon powder, and has a great market potential.

The present invention relates to a novel preparation method of a nylon 12 composite, which comprises technical steps as follows: (1). 20 to 40wt percent of polyolefin is added into melted nylon 12 monomer to be dispersed by stirring; (2). 0.5 to 2w percent of montmorillonite is dispersed into the melted nylon 12 monomer; (3). after the two materials are mixed, 0.5 to 2wt percent of initiator and 0.5 to 2wt percent of cocatalyst are added for the anionic ring-opening polymerization of the monomer to obtain the composite. Compared with the prior art, the present invention has the characteristics of simple technology, short flow, high efficiency, no pollution, etc.

Disclosed is a member of nylon 12 having a relative viscosity of from 1.9 to 3.5 when measured in 98% sulfuric acid at a concentration of 10 g/dm.sup.3 and at 25.degree. C. and a melt flow rate of 0.1 g/10 min. or more when measured at 235.degree. C. under a load of 2,160 g, wherein said relative viscosity and said melt flow rate have a relationship of the following formula (I): wherein .eta..sub.r is relative viscosity and MFR is melt flow rate. The nylon 12 has excellent extrusion moldability and creep characteristics, fatigue characteristics and the like mechanical properties and is suited for tubular molds. A nylon 12 composition comprising the nylon 12 having the above-described specific relationship between .eta..sub.r and MFR and a plasticizer is also disclosed.