Erosion resistant pattern forming method, micro-pattern forming method using the same
A technology for resist patterning and micropatterning, applied in microlithography exposure equipment, instruments, electrical components, etc., can solve the problems of difficulty in resist patterning, difficulty in maintaining shapes with different thicknesses, deterioration in heat resistance, etc. The number of engraving steps, the effect of excellent etching resistance and good heat resistance
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Embodiment 1
[0156] Prepare a positive photoresist composition.
[0157] Preparation (A) component: Cresol novolac resin [Weight average molecular weight (Mw) obtained by condensation reaction of mixed phenols of m-cresol / p-cresol=4 / 6 (molar ratio) and formaldehyde by conventional methods =5000 resin] 100 parts by mass, component (B): [bis(2,3,5-trimethyl-4-hydroxyphenyl)-2-hydroxyphenylmethane] 10 parts by mass, component (C): [Esterification reaction product of 1 mol of 2,3,4,4'-tetrahydroxybenzophenone and 2.34 mol of 1,2-naphthoquinonediazide-5-sulfonyl chloride] 29.7 parts by mass, (D) component: [PGMEA] 430 parts by mass, after uniformly dissolving the above-mentioned components (A) to (D), as a surfactant, 400 ppm of BYK-310 (manufactured by Bikchemi) was blended, and the above-mentioned substances were filtered using a membrane filter with a pore size of 0.2 μm. Prepare a positive photoresist composition.
[0158] Using a resist coating device [TR-36000 (manufactured by Tokyo Ohka Kogy...
Embodiment 2
[0164] Using the same positive photoresist composition as in Example 1, the same steps as in Example were used to form a stepped resist pattern. Among them, the stepped resist pattern is formed into a convex cross-sectional shape, and its dimensions are as follows: the thickness of the thick part is 2.0 μm, the thickness of the thin part is 0.8 μm, the entire width is 13 μm, and the width of the thin part is 5μm.
[0165] The results of evaluating the heat resistance, dry etching resistance, and wet etching resistance of this stepped resist pattern are shown in Table 1 below.
Embodiment 3
[0167] After forming a stepped resist pattern in the same manner as in Example 1, on the other hand, a post-baking treatment was performed at 130°C for 300 seconds.
[0168] The results of evaluating the heat resistance, dry etching resistance, and wet etching resistance of the step-shaped resist pattern after the post-baking treatment are shown in Table 1 below.
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