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Method of Producing Hybrid Tubular Metal/Ceramic Composites and Resulting Products

a technology of ceramic composites and tubular metals, applied in the direction of bars, protective equipments, coatings, etc., can solve the problems of ceramic composites, ceramics, ceramic composites, inherently brittle, metals are inherently ductile, etc., and achieve the effect of improving the mechanical properties of the metal structure, improving the mechanical properties, and improving the mechanical properties

Inactive Publication Date: 2007-11-15
THOR TECH CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This approach results in hybrid metal / ceramic composites with enhanced durability and thermal stability, allowing for longer service life and improved performance under high temperature and pressure conditions, as the ceramic matrix provides load-bearing properties and the metal maintains structural integrity.

Problems solved by technology

Ceramics, including ceramic composites, are inherently brittle, while metals are inherently ductile.
These inherent properties render the attachment of ceramics and ceramic composites to metal structures problematic.
While chemical vapor infiltration (CVI) technology is currently viewed as the industry leader, it is a slow, complex process with many inherent difficulties, including a corrosive gas environment, a high cost for process tooling and a substantial amount (15-25%) of residual porosity.
Although some of these issues have been mitigated by new CVI methods, few metals can tolerate the highly corrosive CVI atmosphere, and those that can (e.g., tungsten alloys) have very high specific gravities, adding substantial weight to the structure.
Although fiber-reinforced ceramics are much less brittle than their monolithic counterparts, they are not ductile like metal components.
In addition, dense ceramics and ceramic composites are difficult to machine.
For these and other reasons, conventional attachment strategies are inadequate.
However, because of the change in density associated with the conversion of the matrix precursor to the finished ceramic, repeated infiltration / firing cycles are required to produce a dense finished ceramic product.
Further, it has not been possible to utilize these prior procedures to include metallic elements as an integrally formed part of the finished ceramic product.
This is due to the fact that the CVI and conventional PIP processes require such high temperatures to convert the preceramic to the finished ceramic product that metallic elements processed therewith are adversely affected.
A particular problem encountered with tubular metal items such as gun barrels is that their service life is limited by erosion, which degrades the weapon's performance.
The high temperature and pressure which results when firing the weapon, together with the aggressive nature of the propellant combustion products, combine to produce thermochemical erosion in the chamber, while friction caused by the exiting projectiles, particularly tracer rounds, induces mechanical erosion in the rest of the barrel and muzzle.
These operating conditions often cause failure of the gun barrel due to thermal expansion of the metal, causing rupturing and / or distortion so as to make the barrel unusable.

Method used

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  • Method of Producing Hybrid Tubular Metal/Ceramic Composites and Resulting Products
  • Method of Producing Hybrid Tubular Metal/Ceramic Composites and Resulting Products

Examples

Experimental program
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example 1

[0039] Composite gun barrels were made utilizing four metallic materials. These included a steel alloy used in guns (5CR—Mo—V), molybdenum (TZM), niobium, and rhenium. Six different ceramic braids included a ±80° Sylramic / CVI SiC, a ±80° Nicalon / CVI SiC, ±80° T300 / CVI SiC, 0 / ±80° Sylramic / CVI SiC, 0 / ±80° Nicalon / CVI SiC, and 0 / ±80°

T300 / CVI SiC. All the composites assumed a fiber volume fraction of 50%. 0 represents the axial direction and therefore ±80° is hoop dominant fiber orientation.

[0040] These gun barrels were tested for thermal and structural results as were gun barrels made completely of a steel alloy used in making guns. The best thermal results were obtained utilizing the 0.00 inch±80° Sylramic / CVI SiC overwrap configuration.

[0041] Structural results showed that at the test temperature attained, the all steel barrels deform plastically. The steel liner in the hybrid steel / ceramic barrels would also deform plastically under the same thermal conditions, but the lower the...

example 2

[0044] It has been found with certain carbon compounds that not enough heat is generated to satisfactorily convert the preceramic polymer to a ceramic. In such cases, a sacrificial overcoat can be utilized.

[0045] The gun barrel, prepared as in Example 1 but before being placed in the GYROTRON, is infiltrated with VL20 polysilazane (a preceramic resin) by standing in liquid resin, under vacuum, for several hours. The barrel is removed from the liquid and allowed to drip drain before being sealed in a vacuum bag. The assembly is placed in an autoclave and cured at 200° C. for four hours with an applied overpressure of 100 psi.

[0046] The cured barrel is then reintroduced to the liquid VL20 to coat the outer surface. A partial, gel-stage, cure is preformed on the barrel by placing in a preheated vacuum oven, above 130° C., for several minutes. The gel-stage barrel is brought into physical contact with Silicon Carbide grinding media (size range: 2 micron to 60-grit) by dusting the surf...

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Abstract

There are disclosed inventions relating to tubular hybrid metal / ceramic composites and the methods of making them wherein the ceramic chosen has a lower thermal expansion than that of the metal.

Description

CROSS REFERENCE TO RELATED APPLICATIONS [0001] The present invention is a continuation application of U.S. patent application Ser. No. 10 / 764,662, issuing as U.S. Pat. No. 7,153,465, entitled “Method of Producing Hybrid Tubular Metal / Ceramic Composites”, filed on Jan. 26, 2004, which application is a continuation-in-part application of U.S. patent application Ser. No. 09 / 929,873, now U.S. Pat. No. 6,699,810, entitled “Method of Producing Hybrid Metal / Ceramic Composites and Resultant Products”, filed on Aug. 14, 2001, and which application claims the benefit of the filing of U.S. Provisional Patent Application Ser. No. 60 / 442,932, entitled “Method of Producing Hybrid Metal / Ceramic Composites and Resultant Products”, filed on Jan. 27, 2003. The specifications and claims of all said applications are incorporated herein by reference. FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT [0002] The U.S. government has a paid-up license in this invention and the right in limited circumstances to re...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C04B35/584
CPCC04B35/589F41H5/0421C04B35/806C04B37/021C04B2235/483C04B2235/5244C04B2235/5248C04B2235/5276C04B2235/667C04B2235/94C04B2237/363C04B2237/365C04B2237/38C04B2237/403C04B2237/404C04B2237/406F41A21/20C04B35/6269C04B35/80
Inventor SCHWAB, STUART T.DUDEK, KEVIN W.
Owner THOR TECH CORP