2results about How to "Increase concentration difference" patented technology

This invention provides a partition wall, a partition wall assembly, and an electrolytic cell that can suppress gas accumulation even when the partition wall separating the anode and cathode chambers of the electrolytic cell has recesses. The partition wall (8) of the electrolytic cell has a first main surface (20) and a second main surface (22) located on the side opposite to the first main surface (20). The first main surface (20) includes a first flat portion (24) and a plurality of first recesses (36) that are recessed from the first flat portion (24). The edges (40) of the first recesses (36) are rounded. The second main surface (22) includes a second flat portion (30) and a plurality of second recesses (42) that are recessed from the second flat portion (30). The edges (46) of the second recesses (42) are rounded.

This invention discloses a method for preparing a TNTs / NiO@CoPi array electrode (TNCP) for photoelectrocatalytic water splitting, belonging to the field of photoelectrocatalytic new energy materials technology. The invention first prepares a highly ordered anatase TiO2 nanotube array (TNTs) using secondary anodic oxidation, then loads Ni nanoparticles onto the surface and inside the nanotubes via constant current electrodeposition, followed by high-temperature calcination to generate p-type NiO, constructing a TNTs / NiO p-n heterojunction (TN). Finally, it uses AM 1.5 simulated sunlight to selectively deposit an amorphous CoPi cocatalyst, where the CoPi only coats the NiO nanospheres without blocking the TiO2 mass transfer channels. This invention utilizes the p-n heterojunction to broaden the full-spectrum light absorption from 250 to 800 nm, and CoPi acts as a hole-trapping layer to suppress electron-hole recombination, significantly reducing interfacial charge transport impedance; the steady-state photocurrent of the TNCP deposition sample reaches 0.06 mA·cm⁻. 2 It is three times that of pure TNTs. This process involves no precious metals or highly toxic corrosive solvents, and the reaction conditions are mild. The electrodes produced can be used for photoelectric water splitting to produce hydrogen, photoelectric oxidation of organic pollutants, and ethylene glycol photoelectric fuel cells. They exhibit excellent cycle stability and have promising prospects for large-scale industrial applications.