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This invention relates to a pyrrolopyrrole organic small molecule photothermal material with high photothermal conversion efficiency, its preparation method, and its application. The invention belongs to the field of organic small molecule photothermal materials. It aims to solve the problems of poor thermal stability and low photothermal conversion efficiency in existing photothermal materials. Preparation method: BrDPPBr, R-boronate, potassium carbonate, and a high-boiling-point solvent are mixed, then heated, and a phosphine compound is added. The mixture is heated and stirred continuously. After the reaction, it is cooled to room temperature, and then pure water is added to precipitate the solid. The solid is then recrystallized and purified to obtain the pyrrolopyrrole organic small molecule photothermal material. Application: It is used for water evaporation. This invention relates to pyrrolopyrrole organic small molecule photothermal materials with high photothermal conversion efficiency, their preparation, and their applications.