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Nano antibacterial aqueous woodenware paint and preparing method thereof

A water-based wood lacquer and nanotechnology, applied in the field of coatings, can solve the problems of unsuitable topcoat varnish, easy oxidation and discoloration of silver, degradation of organic components, etc., and achieve the effects of easy mixing and processing, good pollution resistance, and low VOC value.

Inactive Publication Date: 2009-06-24
RESEARCH INSTITUTE OF TSINGHUA UNIVERSITY IN SHENZHEN +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In patent applications 200410075486.1 and 200410065860.X, nano-titanium dioxide (actually anatase nano-titanium dioxide, also known as photocatalyst) is used as the main antibacterial component. The disadvantage is that photocatalyst reaction needs to occur under the irradiation of ultraviolet light (including the ultraviolet band in natural light) , and will cause degradation of organic components including the paint itself
[0006] Patent application 02120734.8 uses an organic antibacterial agent, which has the disadvantages of poor stability, easy degradation, and harmful residues
In patent 200510102460.6, a mixed dispersion of nano-silver powder and photocatalyst powder is used as an antibacterial component. The main problem is that silver is easily oxidized and discolored, and its stability is poor. Nano-silver powder and nano-titanium dioxide powder are also easy to agglomerate and settle, which is especially not suitable for topcoat varnishes.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The following is an implementation (topcoat) preparation formula composition (W / W):

[0027] Water-based polyurethane resin emulsion 20%

[0028] Waterborne Acrylic Modified Polyurethane Resin Emulsion 20%

[0029] Nano water-based acrylic resin emulsion 40%

[0030] Nano-composite inorganic antibacterial agent 0.5%

[0031] Nano anti-settling thickener 0.2%

[0032] Nano Stain Resistant 1.0%

[0033] Nano anti-aging agent 1.0%

[0034] Nano amphoteric agent 1.0%

[0035] Nano Abrasion Hardener 2.0%

[0036] Wetting and dispersing agent 0.8%

[0037] Defoamer 0.4%

[0038] Leveling agent 0.4%

[0039] Emulsifying wax 0.8%

[0040] water 12%

[0041] The preparation process of above-mentioned embodiment is:

[0042] (1) Mix the three emulsions in proportion and stir for 10 minutes at a speed of 600-700rpm.

[0043] (2) Mix and stir water, wetting agent and defoamer, add nano-composite inorganic antibacterial agent, nano-stain-resistant agent, nano-anti-aging...

Embodiment 2

[0050] Nano antibacterial water-based wood lacquer floor finish preparation formula composition (W / W):

[0051] Water-based polyurethane resin emulsion 20%

[0052] Waterborne Acrylic Modified Polyurethane Resin Emulsion 20%

[0053] Nano water-based acrylic resin emulsion 40%

[0054] Nano-composite inorganic antibacterial agent 0.8%

[0055] Nano anti-settling thickener 0.2%

[0056] Nano Stain Resistant 2.0%

[0057] Nano anti-aging agent 1.0%

[0058] Nano amphoteric agent 1.0%

[0059] Nano wear hardener 3.0%

[0060] Wetting and dispersing agent 1.0%

[0061] Defoamer 0.4%

[0062] Leveling agent 0.3%

[0063] Slip agent 0.5%

[0064] Negative ion generator 0.5%

[0065] Water 9.4%

Embodiment 3

[0067] Preparation formula composition of nano antibacterial water-based wood furniture matte finish (W / W):

[0068] Water-based polyurethane resin emulsion 10%

[0069] Waterborne Acrylic Modified Polyurethane Resin Emulsion 10%

[0070] Nano water-based acrylic resin emulsion 60%

[0071] Nano-composite inorganic antibacterial agent 1.5%

[0072] Nano anti-settling thickener 0.2%

[0073] Nano Stain Resistant 3.0%

[0074] Nano anti-aging agent 3.0%

[0075] Nano amphoteric agent 3.0%

[0076] Wetting and dispersing agent 1.0%

[0077] Defoamer 0.2%

[0078] Leveling agent 0.4%

[0079] Negative ion generator 0.5%

[0080] Matting agent 1.0%

[0081] Water 6.2%

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PUM

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Abstract

The invention relates to a paint, in particular to a single-component nanometer antibacterial water-based wood paint and a preparation method thereof. In the present invention, three different water-based polyurethane resin emulsions, water-based acrylic modified polyurethane resin emulsions and nanometer water-based acrylic resin emulsions are mixed in different proportions as a film-forming material, and while successfully reducing product costs, it also has a low VOC value , anti-adhesion, scratch resistance, pollution resistance, yellowing resistance and good sealing characteristics. The composite inorganic antibacterial agent used in the present invention uses organic expansive soil prefabricated sol as a carrier, contains a variety of inorganic nano-components, not only has the advantages of environmental protection, broad-spectrum antibacterial and strong antibacterial function durability, but also is easy to mix and process, solving the problem of ordinary inorganic antibacterial agents. The technical problems of easy sedimentation, easy discoloration and easy agglomeration during the production and processing of antibacterial agents.

Description

【Technical field】 [0001] The invention relates to a paint, in particular to a single-component nanometer antibacterial water-based wood paint and a preparation method thereof. 【Background technique】 [0002] At present, most of the traditional wood lacquers are solvent-based wood lacquers, mainly solvent-based polyurethane and nitro-lacquer. Due to the relatively high total volatile organic compound (VOC), this kind of wood lacquer has relatively large environmental pollution and affects people's health. Especially with the widespread use of computers, people's lifestyles have gradually changed from outdoors to indoors, which is more likely to cause serious "indoor environmental pollution". [0003] Internationally, the use of solvent-based wood lacquers has been strictly restricted. In Europe, the production and sales of solvent-based paints were completely banned in 2004. my country also plans to completely ban solvent-based wood lacquers by 2008. And water-based wood ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/00C09D7/12C09D5/14C09D5/02B05D7/06C09D175/04
Inventor 杜磊李荣先缪国元刘恒权刘红波
Owner RESEARCH INSTITUTE OF TSINGHUA UNIVERSITY IN SHENZHEN
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