Titanium-base scale-proof coating and preparation method thereof
A coating and fouling technology, which is applied in coating, liquid chemical plating, metal material coating technology, etc., can solve the problem of performance degradation of electric heating devices, reduced service life of electric heating devices, and inability to eliminate scaling on the surface, etc. Problems, to achieve the effect of improving anti-corrosion performance, preventing surface scaling, and lower environmental requirements
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Embodiment 1
[0019] Using pure titanium material as the base material, the purity is 99wt%, and the anti-scaling layer is plated on the surface. When coating, ruthenium chloride, palladium chloride, nickel sulfate, cobalt sulfate, and ytterbium nitrate are mixed in a certain amount to form a plating solution. , the plating solution is proportioned according to the weight ratio of the main components forming the anti-scaling coating, and the weight ratio of the main components in the anti-scaling coating is ruthenium: palladium: nickel: cobalt: ytterbium=0.2:0.5:0.1:0.07:0.2, The weight of sodium hypophosphite and sodium borohydride in the plating solution is 1 times the weight of other metal salts. After heating the plating solution to 50°C, immerse the base material for electroless plating, and plate for 20 minutes to form an anti-scaling coating, then annealing, the temperature is controlled at 300 °C, so that the anti-fouling coating and the outer surface of the base material are effecti...
Embodiment 2
[0021] A titanium alloy material is used as the base material, wherein the titanium content is 90 wt%, and the balance is vanadium. Plating anti-fouling layer on its surface, adopting method is similar to embodiment 1. A plating solution is formed by mixing ruthenium chloride, palladium chloride, nickel sulfate, cobalt sulfate, samarium nitrate, sodium hypophosphite, and sodium borohydride in a certain amount, and a small amount of lactic acid is also added. The plating solution is proportioned according to the weight ratio of the main components forming the anti-scaling coating, and the weight ratio of the main components in the anti-scaling coating is ruthenium: palladium: nickel: cobalt: samarium = 0.5: 0.2: 0.4: 0.1: 0.05, The weight of sodium hypophosphite and sodium borohydride in the bath is 1.3 times that of other metal salts. During the plating process, after heating the plating solution to 70°C, immerse the base material for electroless plating, and plate for 40 min...
Embodiment 3
[0023] The titanium alloy material is used as the base material, wherein the titanium content is 95wt%, and the balance is vanadium and aluminum. Anti-scaling layer is plated on its surface. A plating solution is formed by mixing ruthenium chloride, palladium chloride, nickel sulfate, cobalt sulfate, cerium chloride, sodium hypophosphite, and sodium borohydride in a certain amount, in which a small amount of citric acid is added. The plating solution is proportioned according to the weight ratio of the main components forming the anti-scaling coating, and the weight ratio of the main components in the anti-scaling coating is ruthenium: palladium: nickel: cobalt: cerium = 0.7: 0.6: 0.6: 0.05: 0.3, The weight of sodium hypophosphite and sodium borohydride in the bath is 1.6 times that of other metal salts. During the plating process, after heating the plating solution to 100°C, immerse the base material for electroless plating, and plate for 60 minutes to form an anti-scaling c...
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