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Method of preparing coiled polybutene pipe with high heat conductivity

A polybutene and coil technology, which is applied in the field of high thermal conductivity polybutene coil and its preparation, can solve the problems of high brittleness of heat-conducting pipes and inability to realize coil processing, and achieves the effects of low price and convenient installation.

Inactive Publication Date: 2009-07-29
ZHEJIANG UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a coil with good heat resistance, high pressure resistance and good creep resistance, which can meet the requirements of chemical equipment such as reaction kettles, that is, the high thermal conductivity polybutene coil described in the present invention , to solve the shortcomings of polymer-based heat-conducting pipes filled with heat-conducting materials such as graphite, which are brittle and cannot be processed into coils

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] The expanded graphite with a particle size of 50 microns and the N-octyltriethoxysilane coupling agent were added to a high-speed mixer in a mass ratio of 100:1 and mixed for 10 minutes to obtain the treated graphite. The polybutene resin (melt flow rate 0.3 g / 10 min) was mixed with the treated graphite in a high-speed mixer for 8 minutes according to the mass percentage of the polybutene and the treated graphite at 60% and 40%, respectively. The material is added to the twin-screw extruder for mixing, and the temperature of the extruder barrel is controlled at 165°C to 185°C, so that the polybutene resin and graphite are evenly mixed in the twin-screw extruder, and then extruded and cut into pellets to obtain special materials. . The special material is added to the single-screw extruder for melting and extrusion, and the high thermal conductivity polybutene pipe is obtained by die forming and cooling and shaping. ℃~175℃, cooling setting temperature 45℃~60℃. The pipe...

Embodiment 2

[0022] Formula (mass percentage): polybutene: 30%, graphite 70%.

[0023] The expanded graphite with a particle size of 30 microns and the dodecyltrimethoxysilane coupling agent were added to a high-speed mixer in a ratio of 100:1 and mixed for 10 minutes to obtain the treated graphite. According to the mass ratio of polybutene resin: treated graphite is 30%: 70%, polybutene resin (melt flow rate 0.7 g / 10 minutes) and treated graphite are mixed in a high-speed mixer for 8 minutes, and the mixed The material is added to the twin-screw extruder for mixing, and the temperature of the extruder barrel is controlled at 165°C to 185°C, so that the polybutene resin and graphite are evenly mixed in the twin-screw extruder, and then extruded into pellets to obtain high thermal conductivity. Tube special material. Then the special material is added to the single-screw extruder for melting and extrusion, and the high thermal conductivity polybutene pipe is obtained by die forming and coo...

Embodiment 3

[0026] Formula (mass percentage): polybutene: 30%, graphite 70%.

[0027] The expanded graphite with a particle size of 10 microns and monoglyceryl stearate in a ratio of 100:1.5 were added to a high-speed mixer and mixed for 10 minutes to obtain treated graphite. According to the mass ratio of polybutene resin: treated graphite is 30%: 70%, polybutene resin (melt flow rate 1.0 g / 10 minutes) and treated graphite are mixed in a high-speed mixer for 8 minutes, and the mixed The material is added to the twin-screw extruder for mixing, and the temperature of the extruder is controlled at 165°C to 185°C, so that the polybutene resin and graphite are mixed evenly in the twin-screw extruder, and then extruded and cut into pellets to obtain high thermal conductivity pipes. material. Then the special material is added to the single-screw extruder for melting and extrusion, and the high thermal conductivity polybutene pipe is obtained by die forming and cooling and shaping. 160℃~175℃,...

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Abstract

The present invention relates to coiled polybutene pipe with high heat conductivity and its preparation process. The pipe is made with the material comprising polybutene in 30-60 wt % and surface modified expansion graphite of size below 50 micron in 40-70 wt %, and through mixing, extrusion pelletizing at 160-185 deg.c, smelting and extruding at 160-185 deg.c, molding at 160-175 deg.c, cooling to 45-60 deg.c for setting and machining. The coiled polybutene pipe has high pressure resistance, high corrosion resistance, high heat resistance, low cost and easy installation.

Description

(1) Technical field [0001] The invention relates to the modification of thermally conductive polymer materials and the processing of pipe materials, in particular to a high thermal conductivity polybutene coil pipe and a preparation method thereof. (2) Background technology [0002] In the process of chemical production, a large number of heat exchange units are required in equipment such as reactors and heat exchangers to complete the heat exchange of materials. The materials for making heat exchange units are generally carbon steel, stainless steel and copper. Although these materials have good thermal conductivity It has the advantages of high material strength and low price, but also has the disadvantage of poor corrosion resistance, which leads to leakage of heat exchangers, short service life, and even affects safe production. If the heat exchange tube is made of titanium alloy material, although it can solve the shortcomings of the heat exchange tube made of carbon st...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/20C08K9/06B29C47/20B29C47/92B29C47/38B29B9/06C08K3/04C08K5/54B29C48/32B29C48/395B29C48/92
CPCB29C2947/92704B29C47/0011B29C48/04B29C48/92B29C2948/92704
Inventor 王旭张扩潮唐伟
Owner ZHEJIANG UNIV OF TECH