Method for removing chlorine from zinc sulfate solution

A zinc sulfate solution and removal technology, applied in directions such as zinc sulfate, can solve the problems of high production cost, high production cost, complicated operation, etc., and achieve the effects of increasing waste residue, reducing consumption and simplifying operation procedures.

A zinc sulfate solution and removal technology, applied in directions such as zinc sulfate, can solve the problems of high production cost, high production cost, complicated operation, etc., and achieve the effects of increasing waste residue, reducing consumption and simplifying operation procedures.

CN101113015AInactive Publication Date: 2008-01-30ZHUZHOU SMELTER GRP
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  • Method for removing chlorine from zinc sulfate solution

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The chemical composition of zinc sulfate solution: Cl 1.1g / l, Zn 140g / l, Cu 0.3g / l, Fe 0.02g / l, Cd 0.8g / l, the production process conditions are shown in Table 1:

[0037] Table 1: Process conditions for removing chlorine in zinc sulfate solution

[0038] Copper slag weight

(kg)

pulped water

Product (m 3 )

Potassium permanganate

Weight (kg)

Electrolytic waste acid

Volume (m / 3 )

copper immersion time

(h)

Zinc sulfate solution

Liquid volume (m 3 )

Dechlorination time

(h)

800

5

20

3

2

40

1

[0039] The results of leaching copper slag and zinc sulfate solution to remove chlorine:

[0040] Copper slag leachate contains Cu 2+ 5.8g / l, acid 110g / l, chemical composition of zinc sulfate solution after chlorine removal: Cl 0.22g / l, Zn 132g / l, Cu 2.1g / l, Fe 0.02g / l, Cd 1.42g / l. Chemical composition of chlorine residue: Cl 3.2%, Cu 34.2%.

Embodiment 2

[0042] The chemical composition of zinc sulfate solution: Cl 1.36g / l, Zn 130g / l, Cu 0.2g / l, Fe 0.025g / l, Cd 0.7g / l, the production process conditions are shown in Table 2:

[0043] Table 2: Process conditions for removing chlorine in zinc sulfate solution

[0044] Copper slag weight

(kg)

pulped water

Product (m 3 )

Potassium permanganate

Weight (kg)

Electrolytic spent acid

Volume (m 3 )

copper immersion time

(h)

Zinc sulfate solution

Volume (m 3 )

Dechlorination time

(h)

1100

5

25

4

3

40

1.5

[0045]The results of leaching copper slag and zinc sulfate solution to remove chlorine:

[0046] Copper slag leachate contains Cu 2+ 14g / l, acid 130g / l, chemical composition of zinc sulfate solution after chlorine removal: Cl 0.28g / l, Zn 120g / l, Cu 1.5g / l, Fe 0.02g / l, Cd 1.6g / l. Chemical composition of chlorine residue: Cl 5.42%, Cu 34.07%.

Embodiment 3

[0048] Chemical composition of zinc sulfate solution: Cl 1.5g / l, Zn 130g / l, Cu 0.8g / l, Fe 0.2g / l, Cd 1.2g / l. The production process conditions are shown in Table 3:

[0049] Table 3: Process conditions for removing chlorine in zinc sulfate solution

[0050] Copper slag weight

(kg)

pulped water

Product (m 3 )

Potassium permanganate

Weight (kg)

Electrolytic spent acid

Volume (m 3 )

copper immersion time

(h)

Zinc sulfate solution

Volume (m 3 )

Dechlorination time

(h)

600

5

20

2

1.5

40

1.5

[0051] The results of leaching copper slag and zinc sulfate solution to remove chlorine:

[0052] Copper slag leachate contains Cu 2+ 7.2g / l, acid 90g / l, chemical composition of zinc sulfate solution after chlorine removal: Cl 0.24g / l, Zn 124g / l, Cu 3.1g / l, Fe 0.23g / l, Cd 1.56g / l. Chemical composition of chlorine residue: Cl 3.2%, Cu 34.2%.

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Abstract

A method to remove chlorine from zinc sulfate solution pertains to nonferrous metallurgy. The chlorine in the zinc sulfate solution is removed through elementary copper in copper slug and Cu2+ generated from oxidation of copper slug react with chloride ion to get insoluble CuCl precipitation. The invention makes a further use of copper slug generated from wet zinc melting method, first partial elementary copper in the copper slug is oxidized and then Cu2+ ion is obtained without adding copper sulfate, realizing the effect that elementary copper and Cu2+ ion are both supplied by the slug to involve in chlorine removal reaction. When in the chlorine removal process, no copper sulfate is added and the copper slug is made a full use, therefore, production cost is reduced, operation process is simplified, no waste slug, waste gas and waste water are added and no pollution is done to the environment and as materials involved in the invention are ordinary materials and are not needed and consumed in a large amount, the invention has remarkable economic effect.

Description

technical field [0001] The invention relates to a method for removing chlorine in zinc sulfate solution, belonging to the field of nonferrous metal smelting. Background technique [0002] In the process of zinc hydrometallurgy, chlorine is a harmful impurity element, mainly derived from chlorides in zinc concentrate and zinc fume. The concentration of chlorine in the electrolytic circulating solution is high (Cl - >0.3g / L), the corrosion speed of electrolytic cathode and anode plates is greatly accelerated, which increases energy consumption and reduces the quality of electrolytic zinc. Therefore, before the zinc sulfate solution is sent to electrolysis, most of the chlorine in the solution must be removed. At present, some factories usually use the pre-fire method (such as multi-hearth furnace) roasting to remove the chlorine in the zinc fume, so that most of the chlorine does not enter the wet system, and when the chlorine in the zinc sulfate solution in the wet syste...

Claims

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Application Information

Patent Timeline
30 Jan 2008
Publication
CN101113015A
IPC
C01G9/06
Inventors
θ‚–εŠŸζ˜Ž; εˆ˜ζœ—ζ˜Ž