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Method for preparing oxidation resistant Ti-Al-Ag ternary coating

An anti-oxidation and coating technology, applied in the direction of coating, metal material coating process, melt sputtering, etc., can solve the problems of high cost and low efficiency of sputtering technology, and achieve improved anti-oxidation performance, low production cost, The effect of simple equipment and process

Active Publication Date: 2010-05-19
SHANGHAI JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problem of low efficiency and high cost of sputtering technology, the present invention proposes a method for preparing an anti-oxidation Ti-Al-Ag ternary coating

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The γ-TiAl powder has a purity of 99.95%, 30-50 μm, and the Al element accounts for 55% of the atomic percentage of the TiAl alloy. Ag purity 99.95%, 30-50 microns. Mix the two powders so that the moles of Ag account for 5% of the total moles of the three elements Al, Ti, and Ag, use chemically pure ethanol as the medium for wet ball milling, the frequency is 35HZ, the ball-to-material ratio is 3:2, and the mechanical Ball mill for 12 hours, dry at 100°C, and sieve through a vibrating sampling sieve with 300 meshes. The technical indicators of the obtained γ-TiAl and Ag composite powder are: the particle size of γ-TiAl is 0.1-5 microns, the particle size of Ag is 0.5-5 microns, and the Ag particles are evenly distributed in the γ-TiAl particles, or mixed with γ-TiAl particles. -TiAl embedded into larger particles. The above-mentioned composite powder is prepared into a powder suitable for spraying by atomization and drying method, and deposited on the titanium alloy s...

Embodiment 2

[0031] The purity of the γ-TiAl powder is 99.9%, 50-70 μm, and the Al element accounts for 53% of the atomic percentage of the TiAl alloy. Ag purity 99.9%, 50-70 microns. Mix the two powders so that the molar number of Ag accounts for 3% of the total molar number of the three elements of Al, Ti, and Ag, use chemically pure ethanol as the medium for wet ball milling, the frequency is 40HZ, the ball-to-material ratio is 3:2, and the mechanical Ball mill for 16 hours, dry at 200°C, and sieve through a vibrating sampling sieve with 300 meshes. The technical indicators of the obtained γ-TiAl and Ag composite powder are: the particle size of γ-TiAl is 1-5 microns, the particle size of Ag is 1-5 microns, and the Ag particles are evenly distributed in the γ-TiAl particles, or mixed with γ-TiAl -TiAl embedded into larger particles. The above-mentioned composite powder is prepared into a powder suitable for spraying by atomization and drying method, and deposited on the titanium alloy...

Embodiment 3

[0034] The purity of γ-TiAl powder is 99.5%, 70-100 μm, and the Al element accounts for 51% of the atomic percentage of TiAl alloy. Ag purity 99.5%, 70-100 microns. Mix the two powders so that the moles of Ag account for 2% of the total moles of Al, Ti, and Ag, use chemically pure ethanol as the medium for wet ball milling, the frequency is 45HZ, the ball-to-material ratio is 3:1, and the mechanical Ball mill for 24 hours, dry at 100°C, and sieve through a vibrating sampling sieve with 300 meshes. The technical indicators of the obtained γ-TiAl and Ag composite powder are: the particle size of γ-TiAl is 1-20 microns, the particle size of Ag is 1-20 microns, and the Ag particles are evenly distributed in the γ-TiAl particles, or mixed with γ-TiAl -TiAl embedded into larger particles. The above-mentioned composite powder is prepared into a powder suitable for spraying by atomization and drying method, and deposited on the titanium alloy substrate by vacuum plasma spraying tech...

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Abstract

The process of preparing antioxidant ternary Ti-Al-Ag coating includes the following steps: 1. spray pelletizing to form spherical particle suitable for hot spraying with the material composite gamma-TiAl / Ag powder; 2. low pressure plasma spraying the powder to the surface of substrate to form gamma-TiAl / Ag coating; and 3. polishing the coating with waterproof abrasive paper and heat treatment inside a furnace first in vacuum and then under protection of filled Ar to obtain ternary Ti-Al-Ag coating. The present invention converts the composite powder into ternary alloy through vacuum heat treatment causing high temperature diffusion, and has simple technological process, low investment for apparatus and high coating preparing efficiency.

Description

technical field [0001] The invention relates to a preparation method in the technical field of anti-oxidation materials, in particular to a preparation method for an anti-oxidation Ti-Al-Ag ternary coating. Background technique [0002] The intermetallic compound γ-TiAl has excellent high-temperature comprehensive properties, and its mechanical properties including yield strength and elastic modulus are relatively excellent within a certain temperature range. It has a low density and high specific strength, and is a lightweight alloy with heat resistance close to superalloys. It is considered to be a high-quality material suitable for the fields of automobiles, aviation and aerospace. However, long-term exposure of γ-TiAl to air above 700 °C will generate Al / Ti mixed scale on the surface, which is loose and easy to peel off, which does not help to improve the oxidation resistance of the substrate. However, Shemet et al. found that when the atomic percentage of Al is about 5...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C4/08C23C4/18B22F9/04C23C4/134
Inventor 何博李飞孙宝德王俊周洪
Owner SHANGHAI JIAOTONG UNIV