Adhesive sheet for processing semiconductor wafers and/or substrates
A technology for semiconductors and adhesive sheets, applied in semiconductor/solid-state device manufacturing, semiconductor devices, film/sheet-like adhesives, etc., which can solve the problems of peeling, no reduction, and residual sealing resin paste.
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Embodiment 1
[0062] A resin solution as an adhesive layer was prepared in conjunction with the addition of the following substances, which were 100 parts by weight of 20 parts by weight of methyl acrylate, 10 parts by weight of acrylic acid and 80 parts by weight of 2-ethylhexyl acrylate. The obtained weight average molecular weight of 800,000 copolymer (solid content 35%), 100 parts by weight of polyfunctional acrylate oligomer (UV-1700 manufactured by Nippon Synthetic Chemicals), and 15 parts by weight of the hydroxyl value as a tackifier 160-170KOHmg / g terpene phenolic resin (YS Polyster-N125 manufactured by Yasuhara Chemical Company), phosphate ester surfactant (manufactured by Toho Chemical Industry Co., Ltd., trade name Foosfuranol RL- 210, the number of carbon atoms of the alkyl group is 18) 0.4 parts (a solution that is dissolved in toluene heated to 50° C. with a solid content concentration of 2%), 1 part by weight of a polyisocyanate compound (trade name "Corone 一トL", manufactured...
Embodiment 2
[0067] When preparing the binder solution of Example 1, a terpene phenolic resin with a hydroxyl value of 200 to 210 KOHmg / g (Maytei Ace K125 manufactured by Yasuhara Chemical Co., Ltd.) was added instead of a terpene with a hydroxyl value of 160 to 170 KOHmg / g. Except having prepared an adhesive composition using phenolic resin as a tackifier, the same operation as in Example 1 was performed to prepare an adhesive sheet, and the evaluation shown below was implemented.
Embodiment 3
[0069] When preparing the binder solution of Example 1, a terpene phenolic resin with a hydroxyl value of 130 to 140 KOHmg / g (Mayteyes G125 manufactured by Yasuhara Chemical Co., Ltd.) was added instead of a terpene with a hydroxyl value of 160 to 170 KOHmg / g Except having prepared an adhesive composition using a phenolic resin as a tackifier, it carried out the same operation as Example 1, produced an adhesive sheet, and implemented the evaluation shown below.
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