Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Antibiotic dental prosthetic materials and preparation method thereof

A restorative material and dental technology, applied in dental preparations, dentistry, dental prosthesis, etc., can solve the problems of discoloration, less suitable monomers, and not durable, and achieve long-term antibacterial effects without destroying oral flora

Inactive Publication Date: 2008-07-02
EAST CHINA UNIV OF SCI & TECH
View PDF5 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Titanium dioxide is also a commonly used inorganic antibacterial agent. Adding titanium dioxide can make a resin composition with bactericidal effect or a deodorizing dental resin composition. The sterilization is based on the photocatalytic activity of titanium dioxide, but it is the photocatalytic activity. It can also decompose the resin itself, causing strength deterioration, or discoloration and deterioration, and there is a problem of not being durable
[0006] U.S. Patent No. 5,408,022 and U.S. Patent No. 5,733,949 prepare antibacterial dental materials by polymerizing monomers with antibacterial properties, but this method has fewer suitable monomers and is expensive

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Antibiotic dental prosthetic materials and preparation method thereof
  • Antibiotic dental prosthetic materials and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Take 50 grams of bisphenol A type epoxy resin with an epoxy value of 0.22, dilute it with 5 grams of acetone, then add 2.7 grams of triethylenetetramine, 20nm-40nm SiO 2 Granules 12g, 1μm-3μm SiO 2 8 grams of granules, stir evenly. Take 3 grams of polyhexamethylenediamine guanidine hydrochloride, molecular weight 5000, heat up to 100°C-150°C, make it melt, slowly add into the system, and stir rapidly. After being evenly stirred, the mixture is injected into a specific mold, and cured at room temperature for 12 hours to obtain an antibacterial dental restorative material of the present invention.

Embodiment 2

[0028] Take 5 grams of polyethylenediamine guanidine carbonate, molecular weight 3000, heat up to 100°C-150°C, and make it melt. Add 50 grams of bisphenol F epoxy resin with an epoxy value of 0.3, 10 grams of phthalic anhydride, and 20nm-40nm SiO 2 Granules 12g, 1μm-3μm SiO 2 8 grams of granules, heated up and maintained at 120°C, and stirred quickly and evenly. The mixture is injected into a specific mold, heated to 150° C. for 5 hours and then cooled to obtain an antibacterial dental restorative material of the present invention.

Embodiment 3

[0030] Take 10 grams of polyhexamethylenediamine guanidine nitrate, molecular weight 1500, heat up to 100 DEG C-150 DEG C, make it melt. Add 50 grams of bisphenol S-type epoxy resin with an epoxy value of 0.5, 8 grams of maleic anhydride, and SiO of 20nm-40nm 2 Granules 12g, 1μm-3μm SiO 2 8 grams of granules, heated up and maintained at 120°C, and stirred quickly and evenly. The mixture is injected into a specific mold, heated to 160° C. for 5 hours, cured for 5 hours, and then cooled to room temperature to obtain an antibacterial dental restorative material of the present invention.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Particle sizeaaaaaaaaaa
Particle sizeaaaaaaaaaa
Particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention discloses an antibacterial dental prosthetic material and a preparation method thereof. The antibacterial dental prosthetic material is obtained by injecting the raw materials in a specific mold for curing and forming after even mixing of 25 percent to 94 percent (by weight) of epoxy resin, 0.5 percent to 40 percent (by weight) of polyamine and guanidine oligomer, 5 percent to 65 percent (by weight) of curing agent, the amount which is equivalent to 10 to 50 percent of the total weight of the three matters of filler and the amount which is equivalent to 0 to 20 percent of the weight of the epoxy resin of epoxy thinner. The dental prosthetic material prepared by the ingredients and the method of the invention is safe for the human body, does not damage the oral bacteria group and has the long-term antibacterial property; the antibacterial rate of the invention on staphylococcus aureus is more than 98 percent, and the antibacterial rate on Escherichia coli is more than 98 percent. The invention can be used as dental base material, adhesive, filling material, closure agent and other dental materials.

Description

technical field [0001] The invention relates to a polymer material and a preparation method thereof, in particular to an antibacterial dental restoration material and a preparation method thereof. Background technique [0002] Polymer materials have long been used as dental restoration materials due to their good processability and aesthetics. The main polymer species are acrylic acid, methacrylic acid, methyl methacrylate polymers or epoxy resins, etc. . However, in the restoration of teeth or the use of dentures, bacteria will grow in the repaired position, causing tooth discomfort or new infection problems. [0003] For this reason, in dental restorative materials, it is a common method to add antibacterial agents to make the restorative materials have certain antibacterial properties. [0004] U.S. Patent No. 5,385,728 discloses a method in which the quaternary ammonium compound benzalkonium chloride is mixed with an etchant to obtain an etchant with antibacterial prop...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): A61K6/087A61K6/891
Inventor 危大福郑安呐肖瑞胡福增
Owner EAST CHINA UNIV OF SCI & TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products