192 results about "Guanidine nitrate" patented technology

A fire-extinguishing aerosol not generating harmful substance for electric equipment (computer, communication equipment, electric generator, etc) is prepared from oxidant (strontium nitrate or strontium nitrate/potassium nitrate), reducer (guanidine nitrate or dicyandiamide) and modifier (potassium ferrocyanide, aluminium powder, carbon powder and phenolic resin). After it is ignited by sensor, alot of fire-extinguishing particles are generated to cover on the object to be protected while the inert gas is generated for extinguishing fire.

A material for a pyrotechnic composition and related pyrotechnic compositions are provided in which the material includes a substituted basic metal nitrate including a reaction product of an acidic organic compound and a basic metal nitrate. A method for enhancing a burn rate of a gas generant composition and a burn rate enhanced gas generant composition including a reaction product of basic metal nitrate and tetrazoles, tetrazole derivatives, and combinations thereof, and a nitrogen-containing co-fuel such as guanidine nitrate are also disclosed. The burn rate enhance gas generant composition may optionally include an additional oxidizer such as basic copper nitrate.

Nondetonable, or low detonation sensitivity, substantially nontoxic liquid monopropellants are provided. The liquid propellants are formed from aqueous solutions of solid oxidizers in liquid oxidizers and water soluble liquid fuels and formulated to have a freezing point less than −10° C. Liquid oxidizers may be inorganic or organic aqueous solutions, with hydrogen peroxide being preferred. Preferred solid oxidizers are water soluble nitrates including ammonium dinitramide, aminoguanidine dinitrate, ammonium nitrate, hydroxylamine nitrate, hydrazine nitrate, guanidine nitrate and aminoguanidine nitrate. Preferred liquid fuels are water soluble alcohols, amines and amine nitrates, hydroxyethyl hydrazine, hydroxyethylhydrazine nitrate, cyanoguanidine, guanidines, aminoguanidines, triaminoguanidines, and their nitrate salts, ethanolamine dinitrate, ethylenediamine dinitrate, polyvinyl nitrate, and aziridine.

The invention provides a steam hot aerosol fire-extinguishing composite which contains 30-80wt percent of oxidant, 10-60wt percent of fuel additive and 2-30wt percent of cohesion solidification molding auxiliary agent. The oxidant can be one or more of the following substances: potassium salt, strontium salt, ammonium salt, magnesium salt, nitrocellulose and nitroglycerin; the fuel additive can be one or more of the following substances: azos, azoles, amino-guanidine nitrate, sodium bicarbonate, melamine, cyanoguanidine, carbamide, hexamine, triaminoguanidine nitrate, olefin, saccharose, aluminium powder, magnesite powder and magnesium-aluminium alloy power; the cohesion solidification molding auxiliary agent can be one or more of the following substances: phenol formaldehyde resin, ethoxyline resin, glycidyl azide, urethane rubber, hydroxyl-terminated polybutadiene, polyisobutylene, acetyl tributyl citrate, carboxymethyl cellulose, polyvinyl alcohol phenolic resin and acrylic resin. The invention also provides a fire extinguishing method and a fire extinguishing device adopting the composite. The invention has strong fire extinguishing capacity and fewer hazardous materials and can be applied to different places.

The invention relates to an aluminum alloy surface phosphatizing fluid and a phosphatizing method, belonging to the technical field of processing of chemical conversion coatings on metal surfaces. The method of the invention mainly comprises the following steps: (1) determining the formula of the phosphatizing fluid, wherein the formula comprises the following components and contents: 4.0-8.0g/L of Zn<2+>, 15.0-30.0g/L of PO4<3->, 1.5-1.8g/L of F<->, 0.7-0.9g/L of Ni<2+>, 1.0-1.2g/L of ammonium molybdate, 0.4-0.8g/L of guanidine nitrate and 0.2-0.6g/L of salicylic acid; preparing the phosphatizing fluid from deionized water, and regulating the pH value of the phosphatizing fluid to 3.5-3.7 by 30wt% of NaOH solution; (2) grinding and polishing an aluminum alloy sheet, removing grease by acetone, etching the aluminum alloy sheet by 0.1mol/L of sodium hydroxide solution, soaking the aluminum alloy sheet into 5g/L of surface adjustment fluid to carry out surface adjustment for 1-2min, and then, putting the aluminum alloy sheet into the phosphatizing fluid; (3) controlling the temperature of the phosphatizing fluid at about 40 DEG C, and carrying out phosphatizing reaction for 5min; and (4) cleaning the aluminum alloy sheet by deionized water, and drying the aluminum alloy sheet by hot air. The phosphatizing film formed after phosphatizing has better corrosion resistance and is uniform and compact.

A non-laminated gas producing agent and its production are disclosed. The non-laminated gas producing agent consists of oxygen-enriched carbamidine nitrate 40-60% with granularity 0.5-6mu, basic copper nitrate 10-28% as oxidant with granularity 0.5-6mu, copperon oxide of catalyst with primary oxidant 15-30% with granularity 0.1-6mu, and clay or paraffin wax 0.1-3% as process assistant with granularity 1-20mu. The production is carried out by: breaking the materials, adding into mixer by proportioning, mixing, sieving by screen, adding water 10-30%, agitating, drying, sieving the dried materials by screen with 20-80 mesh to obtain medicine particles, pressing into tablets, and drying the tablets under 100-120deg.C for 1.5-2.5hrs with water content <0.4%. It achieves wide regulating range, high gas output efficiency, and clean gas composition.

The invention relates to a method for synthesizing 2-amino-4,6-dimethoxypyrimidine serving as a fine chemical raw material. The method comprises the following steps of: performing cyclization and hydrolysis on guanidine nitrate, diethyl malonate, sodium methoxide, methanol and dimethyl carbonate serving as raw materials to generate 2-amino-4,6-dyhydroxypyrimidine, and performing methylation on the 2-amino-4,6-dyhydroxypyrimidine and dimethyl carbonate to generate the 2-amino-4,6-dimethoxypyrimidine. The raw materials are cheap; and the method is simple and convenient to operate, facilitates large-scale industrialized production, and has high application value. By using the dimethyl carbonate which is a green raw material as a methylation reagent, the reaction process is shortened, and generation of three wastes is greatly reduced; and because the route is shortened, the energy consumption is also reduced.

A gas generating composition is obtained in which an amount of a combustion residue based on a unit amount of a gas generated is reduced.A gas generating composition comprising nitroguanidine, guanidine nitrate or a mixture thereof as a fuel and further an oxidizing agent. The oxidizing agent is a perchloric acid salt, a nitric acid salt or a mixture thereof, and when the oxidizing agent is ammonium perchlorate, a chlorine neutralizer is further incorporated.

The invention discloses a synthesis method for guanine, which includes the following steps: carrying out a cyclization reaction of guanidine nitrate and ethyl cyanoacrylate to obtain the compound of 2, 4-diamino-6-hydroxypyrimidine in formamide solvent, adding sodium nitrite, formamide and concentrated formic acid in turn, and carrying out nitrosation and reduction reaction with reducing agent and cyclization reaction to obtain the final product. The invention is the use of ''one-pot'', and the raw materials are fat chain ethyl cyanoacrylate and guanidine nitrate, which are directly from market, cheap and easy to get, without need of separation and purification of pyrimidine intermediates. Guanine is prepared by one step through effective control of reaction conditions, feeding sequence and ratio. The product is purified through adjusting pH, which has high yield and is easy to operate.

The invention discloses a one-step safety production method of guanidine nitrate. The guanidine nitrate product is prepared through the following steps: adding ammonium nitrate, urea and a catalyst which is silicon dioxide or inorganic silica gel or aluminum oxide into a reaction kettle, heating to ensure that urea and ammonium nitrate are molten; controlling the temperature of the reaction liquid in the reaction kettle to maintain a reaction at the temperature; and cooling after the reaction, adding process water, heating the solution, performing hot filtering, recycling the catalyst, cooling the filtrate, filtering out a wet product, and drying the wet product to obtain the finished guanidine nitrate product. Ammonium nitrate is excess, thus urea can be completely reacted, side reactions such as the polymerization or sublimation of urea and decomposition can be reduced, the product yield can be increased and simultaneously the product quality can be increased. The production method has safety; and in order to ensure that the reaction has higher safety, the reaction kettle is connected with a temperature-pressure integrated fire device. The content of the obtained guanidine nitrate can meet the standard of the high-class product. The method has the advantages of simple technology and cheap and common raw material, and is economical and efficient.

The invention provides a zinc-system phosphating solution additive and a use method thereof and belongs to the field of industrial phosphating solution. The zinc-system phosphating solution additive comprises an inorganic promoter, an organic promoter, ligand, a buffering agent and a surface active agent, wherein the inorganic promoter is zinc nitrite, NaClO3 and H2O2; the organic promoter is tartrate, guanidine nitrate and nitrobenzene sulfonate; the ligand is organic carboxylate; and the surface active agent is sodium lauriminodipropionate and zinc dihydrogen phosphate. The zinc-system phosphating solution additive is suitable for preparing low-temperature phosphating solution; and due to matching use of the organic promoter and the inorganic promoter, the film-forming speed is fast; due to complexing of the ligand and metal cations, the crystalline grain is refined, simultaneously the deposited slag of the phosphating solution is reduced, the quality of the phosphating film is guaranteed, and the film layer is uniform and fine; due to the buffering agent and the surface active agent, the phosphating solution has better corrosion resistance, and the adhesive force between all metal parts and a coating layer is enhanced. The additive is wide in application range, low in cost and convenient in use, is energy-saving and environmental-friendly, and is beneficial to industrial production.

The invention relates to a phosphorization processing liquid for the surface of carbon steel and a nickel plating enclosure method, belonging to the technical field of chemical conversion film processing for the surface of metal. The phosphorization processing liquid comprises the following components: 2.0-7.0 g/L ZnO, 10-40 g/L PO4<3->, 2.0-17 g/L NiSO4*6H2O, 0.4-0.8 g/L of guanidine nitrate, 10-30 g/L of sodium nitrate and 0.4-0.8 g/L of Ce<4+> rare-earth ions, and the pH value of the phosphorization processing liquid is 2.7-2.9. The nickel plating enclosure method comprises the following steps: polishing a carbon steel sheet, removing oil by using acetone, soaking the carbon steel sheet in 5 g/L of surface correction liquor for surface correction, and then putting the carton steel sheet into the phosphorization processing liquid; controlling the temperature of the phosphorization processing liquid to be about 45 DEG C and carrying out phosphorization reaction for 15 mins; cleaning and blowing for drying after the phosphorization reaction; placing the phosphorized carbon steel sheet into nickel plating liquid, and plating nickel for 1 minute at room temperature and constant current; and cleaning and blowing for drying after nickel plating enclosure is finished. A phosphorization film generated after phosphorization treatment and nickel plating enclosure treatment has better corrosion resistance, and a generated film is uniform and compact.

The invention discloses a continuous synthesis process of guanidine nitrate. The method comprises the following steps: (1), continuously adding materials into a melting kettle according to a proportion, controlling the temperature of the melting kettle, overflowing the materials to enter a primary reaction kettle after the materials are molten; (2), controlling the temperature and the retention time of the primary reaction kettle, continuously ventilating an ammonia gas into the primary reaction kettle, and overflowing the reacted materials to enter a secondary reaction kettle; and (3), controlling the temperature and the retention time of the secondary reaction kettle, continuously ventilating the ammonia gas into the secondary reaction kettle, and cooling, slicing and packaging the reacted materials to obtain a guanidine nitrate finished product. The synthesis process disclosed by the invention is continuously carried out for the whole process and stable to operate, so that the operation strength is greatly lowered, the product yield is high, the quality is good and the yield is high.

The invention belongs to the technical field of metal surface treatment, and particularly relates to black phosphating liquid for phosphating the surface of alloy steel which does not need to be acid cleaned in preliminary treatment. The black phosphating liquid comprises components with the following weight percentage: 2 percent to 5 percent of acidic manganese phosphate, 2 percent to 4 percent of diammonium hydrogen phosphate, 1 percent to 3 percent of cobalt nitrate, 1 percent to 2 percent of guanidine nitrate, 0.5 percent to 1.5 percent of hydroquinone, 0.2 percent to 1 percent of hydroxylamine sulfate, 0.5 percent to 2 percent of phosphoric acid with the mass concentration being 80 percent to 90 percent, and the rest is pure water. Due to the use of the black phosphating liquid, the operation is simple, the stability is good, the film forming speed is high, a formed film is fine and uniform, the color is black, the film forming strength is high, the corrosion resistance is strong and the like, and the black phosphating liquid is applicable to the surface treatment of alloy steel parts of various models.

The invention relates to a gas generating agent composition, a method for preparing the same and a gas generator with the gas generation agent composition. The gas generating agent composition comprises, by weight, 40%-60% of guanidine nitrate, 25%-40% of alkali copper nitrate, 1%-20% of strontium nitrate, 1%-10% of ammonium perchlorate, 5.5%-10% of strontium titanate and 0.6%-10% of talc powder.The gas generating agent composition, the method and the gas generator have the advantages that the strontium titanate and the talc powder are jointly used as shape keeping agents, synergistic effectscan be realized by the strontium titanate and the talc powder, accordingly, pre-combustion shapes of tablets can be effectively kept after the tablets are combusted, and gas bags can be prevented from being burnt due to melting and splashing of the combusted tablets; the strontium nitrate is used as an auxiliary oxidizing agent, the usage amount of the alkali copper nitrate is reduced, and accordingly molten copper residues can be reduced; the ammonium perchlorate is used as an ignition performance regulator, accordingly, the low-temperature ignition performance of the gas generating agent composition can be obviously improved, the combustion speeds can be increased, and the gas generating agent composition mainly can be used for gas generators for supplementary restraint systems of automobiles.

The invention discloses a high-burning rate gas generating agent and a granulation method thereof. The granulation method comprises adding guanidine nitrate, basic copper nitrate, auxiliaries and water into a container, carrying out heating under control of the temperature in a range of 70-90 DEG C, stirring to disperse the mixture through a dispersing device to obtain a uniform mixture, drying the mixture through an atomizing device to obtain dry particles 1, finishing the dry particles 1 to obtain particles 2, drying the particles 2 to obtain particles 3, and tabletting the particles 3. Thehigh-burning rate gas generating agent has a high combustion speed and satisfies the performance requirements of side gasbags to a generating device with special speed requirements. The granulation method can reduce a raw material cost, is free of drying and crushing treatment on raw materials before use, guarantees full contact and mixing of components, improves product stability and consistency,realizes full dissolution of soluble raw materials through a heating dissolution method, utilizes a basket mill and unbaked wet basic copper nitrate to grind and disperse so that a uniform material is obtained, is easy to operate and has high production efficiency.

The invention relates to an air bag restraint system gas generant based cracking barrel and a near-people blasting method thereof. The cracking barrel comprises a gas generant shell and a gas generant, wherein the gas generant needs certain pressure to trigger combustion; the gas generant comprises an oxidant, an acrylate cross-linking agent, a plasticizer, a vinyl trisilane lubricant, a combustion agent guanidine nitrate and a catalyst iron oxide; the gas generant shell has certain pressure therein, is further equipped with a resistance wire; the resistance wire is connected with a plug through a delayer outside the gas generant shell; and pins for connecting external circuits are further arranged on the plug. The cracking barrel cannot trigger and combust the safe environment-friendly type gas generant under atmospheric pressure, and is convenient and efficient to operate.

The invention discloses a method for synthesizing imidacloprid employing cascade reaction. The method comprises the following steps: with 2-chlorine-5-chloromethyl pyridine, ethidene diamine and guanidine nitrate as raw materials, mixing 2-chlorine-5-chloromethyl pyridine, ethidene diamine and guanidine nitrate with a certain amount of solvent ethanol; adding a little of ionic liquid as a catalyst, controlling the pH value of the reaction process to be about 6 with a little of hydrochloric acid; heating, warming, and slowly dropwise adding a certain amount of ethidene diamine, reacting, heating for a certain period of time, stopping heating, and cooling to a room temperature; and purifying and drying to obtain an imidacloprid product. Due to adoption of one-pot cascade reaction, an intermediate product 2-degree amine is high in activity, and easily forms a heterocyclic ring together with nitroguanidine; byproducts can be prevented; and the high-purity imidacloprid is synthesized. Compared with an original two-step technology, the method for preparing the imidacloprid disclosed by the invention is simple in reaction step; the yield and the purity of the product are greatly improved; the yield reaches more than or equal to 95%; the purity of a reaction product through gas chromatography reaches more than or equal to 90%.