Method for using chloromethane to inhibit methane discharging of consumer waste filling field

A domestic garbage and methyl chloride technology, applied in the direction of solid waste removal, etc., can solve the problems of low inhibitory concentration, unfavorable landfill stabilization, unsuitable for the inhibition of methanogens, etc., to achieve efficient inhibition and avoid the greenhouse effect , Inhibitory effect of high-efficiency methanogens

Inactive Publication Date: 2010-06-09
TONGJI UNIV
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  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, the anaerobic biological metabolic process is a process in which microorganisms transmit substances in series. To prevent the production of methane gas, the methanogenic bacteria must be suppressed. Many people protect themselves based on the fact that methanogenic bacteria cannot form spores in harsh environments The characteristics of methanogenic bacteria are killed by heating, microwave, ultraviolet and other methods, but the operation is complicated, and it is not suitable for the suppression of methanogenic bacteria in domestic waste landfills and other places
[0004] Although there are many methods for inhibiting methanogens reported at present, there are the following problems: 1. The inhibitory effect is not ideal, and some microbial inhibitors can only inhibit about 50% of methane production; Effectively inhibit the generation of methane in the landfill environment, but its concentration must reach at least 3000ppm to be effective; 3. It has good inhibitory effect and low inhibitory concentration, but it is not suitable for landfills, such as anthraquinone Because of its extremely low solubility, it is difficult to diffuse into the solid phase where the methanogenic bacteria in the garbage gather; monensin and lasalocid can inhibit the methanogenic bacteria and also inhibit the hydrolytic bacteria and acid-producing bacteria. Produces a strong inhibitory effect, which is not conducive to the stabilization of landfills

Method used

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  • Method for using chloromethane to inhibit methane discharging of consumer waste filling field
  • Method for using chloromethane to inhibit methane discharging of consumer waste filling field
  • Method for using chloromethane to inhibit methane discharging of consumer waste filling field

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Please refer to the attached figure 1 , 2 and 3.

[0019] After simply crushing domestic waste with a water content of 50-80%, weigh 50g and put it into a 150mL serum bottle. Then dilute chloroform with water to a solution with a chloroform content of 0.1% by weight. According to the ratio of adding 20 mg of chloromethane per kg of domestic waste, weigh 1 g of chloroform in the serum bottle to simulate domestic waste. In the anaerobic state of the landfill, the gas is collected by the method of depleting saturated saline, and then the content of methane and the composition and content of volatile acids in the gas are determined by gas chromatography. The inhibition rate is obtained by comparing the results, please refer to figure 2 with image 3 . In Example 1, the inhibitory effect of chloroform (scientific name chloroform) at this concentration was mainly investigated. When the content of chloroform is 20mg / kg, methane is completely suppressed, and the suppressi...

Embodiment 2

[0021] Replace chloroform with dichloromethane, then add 5 to 25 mg of dichloromethane per kg of household waste, and the rest are the same as in Example 1. Depend on figure 2 It can be seen that the highest inhibition rate is 80%. Because dichloromethane mainly relies on the level of chlorine element content to achieve inhibition, and there is no specific substrate inhibition of chloroform, the inhibition effect is poorer than that of chloroform.

Embodiment 3

[0023] Replace chloroform with tetrachloromethane (also known as carbon tetrachloride), and then add 5-25 mg of carbon tetrachloride to each kg of household waste, that is, the content of carbon tetrachloride is 5-25 mg / kg, and the rest is the same as the implementation Example 1 is the same. Depend on figure 2 It can be seen that the highest inhibition rate is 90%. Because carbon tetrachloride mainly relies on the level of chlorine element content to achieve inhibition, and there is no specific substrate inhibition of chloroform, it is therefore less effective than chloroform inhibition.

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Abstract

A method for restraining the methane discharge at a living garbage landfill field by using methyl chloride relates to a method which can stop the generation of the methane gas in the process of the anaerobic digestion of living garbage. Firstly, the methyl chloride of technical grade sold in the market is used as a depressor for the methane generating flora of the living garbage; then, each ton of living garbage is added with 5 to 25g of the methyl chloride and the water containing rate of the living garbage is 50 to 80 percent; then the methyl chloride is uniformly sprayed in the living garbage during the normal operation of the landfill field; finally, a measurement on the volatilization acid of the percolate of the living garbage is carried out; simultaneously the gas is collected by using a method of discharging the saturated salt water; a gas chromatography is used for detecting each component and content in the gas; the total capacity of the volatilization acid is 0.94 to 1.18g / kg; the ratio of monoprop to acetic acid is 0.73 to 1.24; the methane restraining effect can reach 100 percent. The invention has the low cost and the simple operation, which avoids the greenhouse effect caused by releasing the methane; and carries out control on the metabolizing of acid generating flora simultaneously when restraining the methane, which promotes the stabilization course of the landfill field.

Description

technical field [0001] The invention relates to a method capable of preventing the generation of methane gas in the anaerobic digestion process of domestic garbage, and belongs to the technical field of solid waste recycling and pollution prevention and control. Background technique [0002] Atmospheric methane is second only to CO 2 important greenhouse gases. Global methane emissions reach 5.35×10 per year 8 t, the amount of methane produced by human activities is 3.75×10 8 t. It is estimated that the contribution of methane will reach 50% by 2030, making it the number one greenhouse gas. It can be seen that controlling the emission of methane is very important for suppressing the greenhouse effect. Currently, the world is looking to reduce CO 2 However, insufficient attention has been paid to methane, which has led to an increase in the amount of methane, and the reduction of those chemical substances that can react with methane to reduce its content is not very cle...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B09B3/00
Inventor 赵由才赵天涛黄仁华陈浩泉柴晓利牛冬杰王星
Owner TONGJI UNIV
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