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Infrared dual-band window protection film and manufacturing method thereof

A protective film and dual-band technology, applied in optics, instruments, optical components, etc., can solve problems such as high cost, low transmittance, and poor process repeatability, so as to improve impact resistance, increase overall hardness, and improve controllability sexual effect

Active Publication Date: 2010-08-18
NO 717 INST CHINA MARINE HEAVY IND GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The advantage of this infrared dual-band window protection film is that it has a high transmittance, and the disadvantages are:
[0006] ① Poor protection effect: Since only a hard film (diamond-like film) with a thickness of less than 100nm is plated, the hardness of the film is not high, and the ability to resist damage in harsh environments is poor;
[0007] ②Complicated process flow: At least two kinds of equipment are required for plating in the process, and the process flow is complicated
The advantage of this infrared dual-band window protection film is that the protection effect is excellent, and the disadvantages are:
[0009] ①Low transmittance: the average transmittance in medium-wave infrared and long-wave infrared can only reach 80%;
[0010] ②High cost and poor environmental protection: BP film needs to use two highly toxic gases, borane and phosphine, during the plating process. Improper treatment will cause environmental pollution, high equipment fixed investment and maintenance costs
[0012] ①Poor process repeatability: When the germanium carbide film is deposited by chemical vapor deposition, the refractive index control stability is poor, which directly affects the process repeatability; The germanium carbide film process is out of control;
[0013] ②High cost and poor environmental protection: Germanium carbide film needs to use germane, a highly toxic gas, during the plating process. Improper treatment will cause environmental pollution, high equipment investment and maintenance costs

Method used

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  • Infrared dual-band window protection film and manufacturing method thereof
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  • Infrared dual-band window protection film and manufacturing method thereof

Examples

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Embodiment 1

[0044]As shown in Figure 1, an infrared dual-band window protective film is a film system composed of a substrate 1 and at least one group of intermediate protective composite films 2 and an outermost protective film 3 that are sequentially attached to the substrate 1; The above-mentioned intermediate protective combination film 2 is composed of a germanium carbide film and an upper film 2.2 of a bottom layer film, or is composed of a diamond-like film of a bottom layer film 2.1 and a germanium carbide film of an upper layer film 2.2; the outermost layer The protective film 3 is a diamond-like carbon film, which is a diamond-like carbon film superimposed on the uppermost layer of the intermediate protective composite film 2, or is the uppermost diamond-like carbon film 2.2 of the intermediate protective composite film 2. The refractive index of the germanium carbide film is 3.0-3.9; the diamond-like film in the intermediate protective composite film 2 is the bottom film 2.1 or ...

Embodiment 2

[0045] Embodiment 2: Different from the above embodiment 1, the material of the base 1 is germanium, the intermediate protective composite film 2 is 6 groups, and the thicknesses of the upper layer films (diamond-like film) of the first group to the sixth group are respectively 43.89 nm, 59nm, 30nm, 802nm, 293nm and 2000nm. The uppermost diamond-like film is also the outermost protective film 3; the refractive index of the germanium carbide film is 3.9.

Embodiment 3

[0046] Embodiment 3: Different from the above-mentioned embodiments 1 and 2, the material of the base 1 is zinc sulfide; the intermediate protective composite film 2 is 1 to 6 groups, and the bottom film 2.1 of each group is a germanium carbide film and the upper film 2.2 is The diamond-like film is 10-2000nm. In this embodiment, the intermediate protective composite film 2 is divided into 2 groups. The bottom film 2.1 of the first group is a germanium carbide film and the upper film 2.2 is a diamond-like film with a thickness of 1563nm. The bottom film 2.1 of the second group is a carbonized film. The thickness of the germanium film and the diamond-like film of which the upper film 2.2 is the outermost protective film 3 is 100nm. The germanium carbide film has a refractive index of 3.5.

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Abstract

The invention relates to a dual waveband infrared window protection film and a manufacturing method thereof. The protection film is a film system consisting of a substrate, an intermediate protection combined film and an outermost layer protection film; the intermediate protection combined film consists of a bottom layer film which is a germanium carbide film and an upper layer film which is a diamond-like film or consists of a bottom layer film which is the diamond-like film and an upper layer film which is the germanium carbide film; and the outermost layer protection film is the diamond-like film. The manufacturing method comprises the following steps: determining the substrate, selecting the materials of the bottom layer film, the upper layer film and the outmost layer protection film, optimizing the film system and the like. The dual waveband infrared window protection film has the advantages of high light transmittance, being capable of resisting damages caused by severe environmental factors such as blown sand, sea water, high speed, salt mist and the like, high shock resistance, and improving the overall rigidity of the film system, as well as good process controllability and good process repeatability.

Description

Technical field: [0001] The invention relates to an infrared dual-band window protective film and a manufacturing method thereof, which belongs to the technical field of optical thin films, and is particularly suitable for common window optical systems. Background technique: [0002] With the changes in the application environment of optical system equipment and devices, especially high-precision optoelectronic systems are developing towards multi-band integration, such as field operations, especially in military and other fields, the application of some common-window optical systems is becoming more and more Among them, the optical system with a common window of mid-wave infrared (3-5 μm) and long-wave infrared (8-12 μm) has the broadest application prospects in the fields of guidance, tracking, and warning. Compared with the single-band infrared system, the dual-band infrared system is easier to distinguish small nearby targets (such as birds) from large distant targets, w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G02B1/10B32B7/02B32B9/00G02B1/14
Inventor 熊长新李钱陶何光宗吴小丽杨林峰朱谧
Owner NO 717 INST CHINA MARINE HEAVY IND GRP
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