23results about How to "Good process repeatability" patented technology

This invention belongs to the field of core-shell material technology and discloses a core-shell material based on nickel-manganese oxide / nickel-manganese organic framework and its preparation method, including the following steps: mixing nickel salt, manganese salt and organic ligand solution, and carrying out a hydrothermal reaction under alkaline conditions to synthesize a nickel-manganese organic framework precursor; subjecting the nickel-manganese organic framework precursor to programmed temperature heat treatment in a mixture of inert gas and oxygen to obtain a heterogeneous nanostructured nickel-manganese oxide / nickel-manganese organic framework core-shell material. By precisely controlling the concentration of the organic ligand solution and the pH value of the reaction system, and by optimizing the synthesis conditions, uniform and controllable growth of the nickel-manganese organic framework core is achieved.

The invention relates to a high-sensitivity MEMS flow sensor and a manufacturing method thereof.The high-sensitivity MEMS flow sensor comprises a sensor chip, a metal base and a measuring runner, the sensor chip comprises a substrate, and a porous silicon area is formed in the substrate; the first dielectric layer is formed on the substrate and the upper surface of the porous silicon region; the heating resistor array is formed on the upper surface of the first dielectric layer and is positioned right above the porous silicon region; the thermopile array is formed on the upper surface of the first dielectric layer and located over the porous silicon area, and the thermopile array and the heating resistor array are alternately arranged in the direction of the gas flow channel; the electric isolation layer covers the heating resistor array and the thermopile array; the metal interconnection structure is formed on the upper surface of the electric isolation layer and is connected with the thermopile array; the electrode is connected with the metal interconnection structure; and the second dielectric layer covers the electrical isolation layer and the metal interconnection structure. A multi-pair symmetrical distribution structure in which the thermopiles and the heaters are alternately arranged is adopted, so that the measurement sensitivity of the flowmeter is remarkably improved.

The invention discloses a temperature control method for processing graphite by using double plasma sources, and relates to the technical field of plasma material processing, in particular to a temperature control method for processing graphite by using double plasma sources, which comprises the following steps: adopting a cylindrical reactor, and arranging a plasma source I and a plasma source II up and down along the axial direction on two sides of the cylindrical reactor, and an outlet of the powder feeding mechanism directly faces a core high-temperature area of the plasma source I, so that graphite powder directly enters a heating area. The two sources are connected in series up and down to construct a continuous relay type high-temperature path. The center distance between the powder feeding port and the source I is limited not to exceed half of the outlet diameter of the reactor, the center distance between the two sources is 1-2.5 times of the outlet diameter, and the center distance between the source II and the outlet is larger than 5 times of the diameter; the flow of the second source is 1.2-1.8 times that of the first source, the temperature of the core area is maintained to be 8000-10000 K by adjusting the flow ratio, and the total power does not exceed 100 kilowatts. The total retention time of the graphite powder in a two-source high-temperature area is longer than 0.2 second, the diameter of an outlet of the reactor is 100-400 mm, the reactor is made of high-temperature-resistant stainless steel or graphite, and accurate control over the graphite treatment temperature is achieved.

A laser-plasma synergistic surface treatment method for CFRP / titanium alloy heterojunctions belongs to the field of heteromaterial bonding technology. First, nanosecond pulsed lasers are used to etch the surfaces of CFRP and titanium alloy to be bonded, constructing a micro-nano composite structure. Then, atmospheric pressure cold plasma is used to activate the etched surfaces, grafting polar functional groups. Finally, the two are bonded and cured using an adhesive. This invention achieves a dual enhancement effect of "mechanical interlocking" and "chemical bonding" by organically combining "laser etching to construct micro-nano physical structures" and "plasma activation to introduce chemical functional groups," significantly improving the interfacial bonding strength of CFRP / titanium alloy heterojunctions. Compared with single treatment methods, this invention can increase the joint shear strength by more than 38%, and the failure mode changes from interfacial failure to cohesive failure. It has advantages such as environmentally friendly process, good controllability, and significant effects, and has broad application prospects in aerospace, high-end equipment manufacturing, and other fields.

This invention belongs to the field of engineered wood products manufacturing, specifically a method for preparing low-formaldehyde finger-jointed boards based on bio-based modified adhesives. The method includes preparing an adhesive composed of modified soybean protein, non-formaldehyde crosslinking agents, micro / nano cellulose, nano-silica, and epoxidized vegetable oil elastomers; pre-treating the wood and cutting the finger joints; applying a sealing liquid via atomization for end-face damping treatment; performing quantitative adhesive application and stepped butt joint molding; and employing a multi-stage hot-pressing process involving preheating penetration, high-temperature curing, and cooling and pressure holding. Through the above technical solution, this application can achieve the formation of a dense adhesive film at the finger joint interface, significantly improving bonding strength and stability while reducing formaldehyde release.

This invention relates to the field of organic compound preparation technology, specifically a method for preparing 11-triglycerides of carbonate via low-temperature acylation. This method uses glycerol and undecanoyl chloride as raw materials, employing a synergistic system of a "composite acid-binding agent + Lewis acid catalyst," and combines in-situ dehydration technology and a stepwise heating strategy in a dual-solvent environment to achieve efficient synthesis. The specific steps include: under nitrogen protection, dissolving glycerol in a dichloromethane-toluene dual solvent, adding a composite acid-binding agent of pyridine and N,N-diisopropylethylamine, anhydrous zinc chloride catalyst, and 4A molecular sieve for in-situ dehydration; dropwise adding undecanoyl chloride at a low temperature of 5-10°C, followed by sequential heating to 30°C for 2-3 hours and then reacting at 50°C for 12-16 hours; and post-processing using a combined process of filtration-multi-stage extraction-membrane separation-column chromatography. This invention provides mild reaction conditions, effectively suppresses side reactions, produces high-purity products, increases molar yield, and reduces solvent toxicity and purification costs.

The application discloses a kind of carbon black supported iron manganese composite oxide cluster catalyst's Joule heat preparation method and its application in electrocatalytic nitrate reduction preparation ammonia, belong to electrocatalytic ammonia preparation technical field.The catalyst Ketjenblack EC-600JD carbon black is used as carbon carrier, iron manganese composite oxide cluster is uniformly dispersed on the surface of carbon carrier, and the carbon carrier is worm-like mesoporous structure, with high specific surface area and high defect concentration.The application uses sodium citrate as complexing agent, acetylacetone iron and manganese acetate as metal precursor, after complexing, loading, gelation, freeze drying, the target catalyst is prepared by Joule heat instantaneous heat treatment under nitrogen atmosphere;The preparation process has high heat conversion efficiency, low energy consumption, can realize atomic dispersion of iron manganese composite oxide cluster, effectively improves the exposure degree of catalytic active site.The catalyst shows high catalytic activity, high selectivity and excellent stability in electrocatalytic nitrate reduction preparation ammonia reaction, and the ammonia preparation faraday efficiency can reach more than 85%, and the preparation process does not need noble metal and toxic reagent, and the process is green and efficient, easy to scale production, can efficiently convert nitrate wastewater into ammonia, with environmental governance and nitrogen resource recycling value.

This invention discloses a two-step pulse electrodeposition method for preparing a nickel-tungsten-cobalt ternary metal oxygen evolution electrode and its application. Specifically, it addresses the Ni... 2+ Co 2+ With W 6+ The large differences in reduction potential and the mismatch in reduction kinetics lead to elemental segregation in single-step deposition. This invention addresses this problem by employing a two-step pulsed electrodeposition strategy: first depositing a Ni-W metal layer, then depositing a Ni-Co metal layer. This strategy optimizes the plating bath composition and pulse parameters step-by-step to accommodate the reduction requirements of different metal ions. The method includes: pretreatment of the nickel-based substrate; performing a first-step pulsed electrodeposition in a solution containing nickel and tungsten salts; and then performing a second-step pulsed electrodeposition in a solution containing nickel and cobalt salts, followed by drying. This invention, through specific two-step deposition and the periodic regulation of the pulsed current, effectively optimizes the loading and dispersion of nickel, tungsten, and cobalt, resulting in a high-performance oxygen evolution electrode with stable and reliable performance, meeting the application requirements of large-scale industrial production.

The application discloses a pulse current-based crack-free heat treatment method for additive manufacturing of high-temperature alloy, and belongs to the technical field of heat treatment of additive manufacturing of high-temperature alloy. The application aims to solve the technical problem that nickel-based high-temperature alloy manufactured by additive manufacturing is prone to cracking during the heating process of stress relief heat treatment. The application directly heats the workpiece by using pulse current, and the average heating rate of the workpiece is not less than 100 DEG C / s by applying high-density pulse current, so that the superfast heating far exceeding traditional furnace heat treatment is realized, thereby the precipitation of harmful phase at the grain boundary during the heating process is inhibited, and the cracking problem in the stress relief heat treatment process is fundamentally avoided. The method is especially suitable for nickel-based high-temperature alloy such as IN738LC.

The application relates to a high-lubricity bearing journal surface structure and a method for obtaining the same, wherein the friction surface of the bearing journal is uniformly staggered with hardened areas of protrusions and relatively recessed journal base material softening areas, the hardness of the hardened areas is 15-25 HRC higher than that of the journal base material, and the protrusion height of the hardened areas is 5-30 mu m. The friction surface with the alternately soft and hard and staggered high and low areas is wear-resistant, improves bearing elasticity, reduces vibration load, can improve the oil capacity of the journal surface, increase the lubricating oil film thickness under low-speed and high-speed conditions, reduce the friction coefficient, improve the lubricating performance, and prolong the journal fatigue life. The journal structure is realized through an electrolytic plasma local heat treatment method, the manufacturing process can be automated, the process is energy-saving, environment-friendly and efficient, and the risk of overall deformation of large journal parts is eliminated.

The present application relates to the technical field of biological nanomaterials, in particular to a multi-level structure calcium phosphate nanomaterial, a preparation method and application thereof.The present application prepares small-scale calcium phosphate nanoparticles through a biomimetic mineralization strategy, and then crosslinks the same with L-lysine or cystamine dihydrochloride through an EDC / NHS-mediated amide coupling method to form a size-controllable multi-level structure aggregate.Compared with the small-scale calcium phosphate nanoparticles, the multi-level structure, as a doping matrix of metal ions such as Cu and Mn, significantly improves the catalytic efficiency of the metal ions, as a drug carrier, improves the loading capacity of the drug, and the multi-level structure shows a higher tumor accumulation effect.The present application has a simple preparation method, can realize the size regulation of the multi-level structure calcium phosphate nanomaterial, and can realize the tumor microenvironment-responsive disintegration of the multi-level structure.The method has good process repeatability and high batch stability, is suitable for developing high-performance nanodrugs, and has good application potential in the biomedical field.

This invention belongs to the field of wet electronic chemical purification, specifically relating to a membrane chromatography filter membrane for removing charged ions from liquids and its preparation method, including the following steps: S1, preparing casting solutions: preparing positively charged layer casting solutions, neutral layer casting solutions, and negatively charged layer casting solutions separately; S2, using a three-layer die to sequentially extrude the positively charged layer casting solutions, neutral layer casting solutions, and negatively charged layer casting solutions onto a polyester film; S3, exposing the casting solutions under set temperature, humidity, and airflow conditions to allow for initial phase separation; S4, immersing the coated film in a pure water coagulation bath to complete phase separation and solidification; S5, rinsing, drying, and then winding to obtain the membrane chromatography filter membrane. By designing a special three-layer composite structure with a "positively charged layer-neutral layer-negative layer," the filter membrane can simultaneously adsorb anions and cations in the solution during a single filtration process, overcoming the limitation of traditional single-charge membranes that can only remove one type of ion, thus improving purification efficiency.

The invention discloses a titanium alloy surface laser cladding wear-resistant and self-lubricating coating suitable for a high-load environment and a preparation method thereof. The method comprises the following steps: 1, grinding, polishing, cleaning and preheating the surface of a titanium alloy substrate; secondly, titanium powder, titanium carbide powder and silver powder are subjected to ball-milling mixing and then dried, and composite powder is obtained; thirdly, the composite powder is conveyed to a titanium alloy base material cladding area, laser cladding is conducted, and a cladding piece is obtained; and fourthly, the cladding part is subjected to slow cooling treatment, and the wear-resistant and self-lubricating coating is obtained. By controlling the content of each component and adopting the high-energy ball milling and laser cladding processes, a fine Ag lubricating phase is uniformly introduced into a high-hardness Ti-TiC coating system, dispersed distribution of Ag elements is realized, microscopic segregation is remarkably inhibited, and the composite coating which is uniform and compact in structure, high in hardness and low in friction coefficient is prepared on the surface of the titanium alloy. And the service reliability and the service life of the titanium alloy key component under the high-load working condition are remarkably improved.

The application discloses a mesoporous hollow sphere assembly structure catalyst and a preparation method and application thereof, and belongs to the technical field of hydrogen production by methane decomposition. The preparation method comprises the following steps: dissolving Ni salt, Al salt and Ce salt in a solvent, and controlling the molar ratio of Ni, Al and Ce to be 7:(1-2.5):(0.5-2); obtaining atomized liquid drops through atomization, and performing a decomposition reaction on the atomized liquid drops at 400-500 DEG C; collecting reaction products, drying, and then calcining by heating to 550-700 DEG C to obtain a catalyst precursor; and performing reduction treatment on the catalyst precursor in a reducing atmosphere, and the mesoporous hollow sphere assembly catalyst with a cerium-doped regulated interface is obtained. The catalyst exhibits remarkable high mass space velocity long-term stability and anti-coking performance in the methane catalytic decomposition reaction.

This invention discloses a high-temperature resistant and creep-resistant asbestos-free composite sealing board and its preparation method. The board is made from raw materials comprising 30-50 parts inorganic fibers, 10-20 parts high-temperature resistant organic fibers, 25-45 parts high-temperature resistant functional fillers, and 8-18 parts composite binder. The composite binder is pre-mixed from liquid phenolic resin and nano-silica sol at a dry weight ratio of 1:(0.5-2). The board has a localized inorganic reinforcing network formed by the accumulation and curing of nano-silica sol in the pores and interfaces of the fiber network. The preparation method includes: fiber dispersion and pulping, composite slurry preparation, wet paper forming, supplementary impregnation and pre-curing, segmented hot pressing curing, and post-heat treatment. This invention, by combining an organic-inorganic composite bonding system with a specific process, significantly improves the board's resistance to compression creep and sealing durability at high temperatures, solving the technical problem of easy loosening and leakage of traditional asbestos-free sealing materials under extreme conditions.

This invention discloses an automatically target-changing pulsed laser deposition apparatus and method. The apparatus includes a process chamber, a transfer valve, and a buffer chamber. The process chamber is connected to the buffer chamber via the transfer valve and is configured as an internal vacuum chamber. The buffer chamber has a door at its upper part and operates as a vacuum chamber. A sample stage is located on the upper inner side of the process chamber. Two neck tubes are located on the two sides of the process chamber for guiding an external laser source and mounting a laser detection device, respectively. The process chamber also includes a rotatable target stage for loading and unloading targets from the buffer chamber. The buffer chamber includes a rotating target stage mechanism and a vision camera for placing the target material and recording the bottom features of the target material, respectively. This invention provides an automatically target-changing pulsed laser deposition apparatus and method with a compact structure, precise positioning, and automatic target changing capabilities, enabling fully automated deposition of ultrapure thin films.

This invention relates to the field of magnesium alloy smelting technology, and in particular to a smelting process and apparatus for a semi-solid non-dendritic slurry of rare earth AS-based magnesium alloy. Using AS magnesium alloy as the base material and a Ce-La-Nd ternary rare earth mixture as the rare earth modifier, the process involves vacuum melting, electromagnetic stirring, and stepped cooling to obtain an ingot. A three-dimensional curve is plotted based on the JMAK equation to determine the critical temperature. Using a rheological casting apparatus, through internal cooling gradient, stirring-assisted slurry preparation, and ultrasonic-assisted isothermal treatment, combined with three-level quality judgment and defect closed-loop adjustment, a slurry with controllable liquid phase content, fine and rounded grains, and uniform rare earth distribution is prepared. The process exhibits high repeatability and meets the requirements of high-end semi-solid forming.

This invention discloses a nystatin microsphere with targeted enhanced antifungal function, its preparation method, and its application. The microsphere uses sodium alginate as a carrier, internally encapsulating the antifungal drug nystatin. The surface is covalently modified with the β-glucan binding domain of the Dectin-1 protein, constructing a smart drug delivery system with fungal targeting function. The microsphere preparation process is simple and reproducible, and can be scalable using an emulsion-ionic crosslinking method combined with protein coupling technology. In vitro characterization shows that the microspheres have uniform particle size and stable dispersion, and Dectin-1 modification significantly enhances their specific binding ability against Candida albicans. This targeted delivery system, while successfully preserving drug activity, significantly improves the antifungal efficiency of nystatin through Dectin-1-mediated targeting, achieving efficacy close to that of free drug, and providing a new strategy for constructing highly efficient and long-acting antifungal agents.

The application provides an epsilon phase gallium oxide based material and a crystal student growth method and use thereof, the crystal student growth method comprising epitaxial growth of the epsilon phase gallium oxide based material on a substrate with a polar surface, so that the epsilon phase gallium oxide based material has the same polarization direction as the polar surface. The application selects a substrate with a specific surface polarity and controls the growth of high-quality crystals through substrate and template engineering, thereby guiding controllable polarity growth by using the specific substrate as a template. Thus, active regulation of the polarization direction of the epsilon phase gallium oxide based material can be supported, the bottleneck of single polarization characteristics of the material system is broken, a key material foundation for developing a new generation of high-performance functional devices based on polarization engineering is laid, and the application has important scientific and application values.

The application discloses a polyoxometalate composite solid electrolyte membrane and a preparation method thereof and a solid-state battery, and belongs to the technical field of solid-state lithium metal batteries. The polyoxometalate composite solid electrolyte membrane comprises a polyionic liquid and lithium silicotungstate; the polyionic liquid is composed of polydiallyl dimethyl ammonium cations and lithium salt anions; and the mass ratio of the lithium silicotungstate to the polyionic liquid is (4-25):(75-96). The application utilizes strong electrostatic coupling between polyoxometalate anions and polymer cation chains to construct an ion transmission network with ordered structure. The composite structure effectively promotes lithium salt dissociation and lithium ion directional migration, significantly improves the room temperature ionic conductivity, lithium ion transference number and mechanical strength of the electrolyte membrane, and simultaneously enhances the interface compatibility and electrochemical stability of the electrolyte membrane with a lithium metal negative electrode.

This invention provides a method for preparing LaBi(00l) single-crystal thin films using molecular beam epitaxy (MBE), belonging to the field of thin film preparation technology. The method involves heating a lanthanum (La) and bismuth (Bi) evaporation source to a certain temperature, then co-depositing the La and Bi molecular beams onto a Si(001) substrate heated to a certain temperature, thereby forming a LaBi thin film. Subsequently, the film is annealed while keeping the Bi evaporation source on, and then cooled to room temperature. The LaBi(00l) single-crystal thin film prepared by this method exhibits a [00l] orientation. The method provided by this invention offers controllable processes and good repeatability, providing an effective approach for preparing high-quality LaBi thin films.

This invention relates to the field of metallization technology for membrane materials, specifically disclosing a method for preparing a PTFE membrane by sputtering and electroplating a metal layer. The method includes: PTFE membrane pretreatment, magnetron sputtering of a transition layer, selective electroplating of a metal layer, and post-treatment. This invention combines multi-target magnetron sputtering with multi-metal selective electroplating, resulting in a simplified process with controllable parameters. The sputtering transition layer exhibits excellent adhesion to the PTFE membrane and each metal coating. The resulting coating meets the 5B grade requirement of the ASTM D3359 standard's cross-cut adhesion test. The coating is uniform and dense, achieving high conductivity and strong corrosion resistance, while retaining the original flexibility and temperature resistance of the PTFE membrane. It is suitable for diverse applications such as electromagnetic shielding, chemical corrosion protection, and flexible electronic packaging.