Preparation of cupric nitrate solution
A technology of copper nitrate and solution, applied in the direction of copper nitrate, etc., can solve the problems of large nitrogen oxide pollutants, difficult pollution control, large consumption of nitric acid, etc., and achieve reduction of consumption of nitric acid, obvious economic and environmental benefits, The effect of saving the cost of pollution control
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Embodiment 1
[0014] Example 1: Add 5kg of metal copper shavings into a stainless steel autoclave with a volume of 10L, add 9.5L of 12mol / L nitric acid, feed 0.2MPa industrial pure oxygen, and react at 40-50°C for 6 hours without stirring. After the end, liquid-solid separation was carried out to obtain 9.3L copper nitrate solution, the Ph value of the solution was 3.8, the reaction tail gas was 1.5L (volume when converted into an absolute pressure of 0.1MPa), and the nitrogen oxide concentration was 6.8mg / m 3 .
Embodiment 2
[0015] Embodiment 2: adding 500kg metal copper shavings to a volume of 1m 3 In a stainless steel autoclave, add 950L of 13mol / L nitric acid, introduce 0.1MPa industrial pure oxygen, stir and react at 40-60°C for 4 hours, perform liquid-solid separation after the reaction, and obtain 930L copper nitrate solution. The Ph value is 3.7, the reaction exhaust gas is 100L (converted to the volume when the absolute pressure is 0.1MPa), and the nitrogen oxide concentration is 6.1mg / m 3 .
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