Novel drying agent

A desiccant, a new type of technology, applied in other chemical processes, separation of dispersed particles, prevention of condensed water formation, etc., can solve problems such as difficult to increase production and large-scale touch production, pollute the environment, rise in raw material prices, etc., to achieve a good choice Type and selective adsorption characteristics, simple process operation, and easy implementation

Inactive Publication Date: 2009-09-30
DALIAN HAIXIN CHEM IND
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Problems solved by technology

[0008] However, with the improvement of environmental requirements, in the production process of 3A molecular sieve, ion exchange is carried out in the solution, and there are a large amount of K in each link of washing. + Ion pollution, polluting the environment, coupled with the international financial crisis, the prices of various raw materials continue to rise, to overcome the above defects, people have made continuous improvements in the preparation process
[0009] CN1579939A proposes to utilize natural mordenite to replace the preparation method of artificially synthesized zeolite, with natural mordenite as the main component element, but its defect is a large amount of work such as natural mordenite purification and grinding, it is difficult to improve output and large-scale touch production
Its disadvantage is that the inorganic active substance is chloride, which is mainly calcium chloride. Although the moisture absorption rate of calcium chloride is high, when the air humidity is extremely high, the desiccant is prone to deliquescence, which will completely corrode the insulating glass.
[0011] CN1736554A is for overcoming above technical deficiencies, adding sodium hydroxide, quicklime, diatomite and high alumina to form hollow glass desiccant in attapulgite clay, with sodium hydroxide, sodiumized attapulgite, replaces chlorination with quicklime Calcium, but the disadvantage is that it cannot be widely used as a unified product, and the product can only be distributed in the south of the country, and the different formulations used in the north are treated differently (see Table 1)
[0014] Thereby illustrate that this preparation method versatility is poor, and its product water-absorbing property, prevents hollow glass from appearing frost phenomenon and prevents O 2 and N 2 Adsorption performance is not ideal

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035]With 195kgA type molecular sieve (its chemical component and weight percentage are made up of: Al 2 o 3 34.97%, SiO 2 42.82%, Na 2 O 22.21%, 105kg mixed clay (wherein each component weight percent is: attapulgite 65%, bentonite 34%), mixes with 47kg water, in mixing process, adds 16kg chemical modification agent to carry out its structure Modification and modulation, the chemical modification and modulation agent is compounded with the following components by weight percentage: 25% NaOH, 68.8% silica sol, 6.2% aluminum sol, the above-mentioned uniformly mixed mixture is molded and granulated, and finally activated by roasting at 450-550 °C 2 ~6h, after testing the water content is ≤15%, packaged and put into the warehouse, and then made into color: light yellow, white, earthy red, appearance: spherical shape with various diameters from 0.1 to 10mm or strip shape with various diameters from 0.6 to 6mm Desiccant, the indicators tested are as follows:

[0036] Static wa...

Embodiment 2~8

[0042] Embodiment 2~8 preparation method is identical with embodiment 1, and concrete raw material formula sees table 2

[0043] Table 2: Desiccant formulations of Examples 1-8

[0044]

[0045]

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Abstract

The invention belongs to an inorganic micropore new-material drying agent. The novel drying agent is a silicate A-type molecular sieve which has the diffracting strength value I of more than 75 but less than or equal to 100 on the 110 surface at an angle of 10 degrees of the 2 theta angle of the XRD diffracting peak . Besides the properties of the glass drying agent in a 3A-type molecular sieve, the inorganic micropore new-material molecular-sieve drying agent prepared by new chemical modification technology of the invention has the structural characteristics that the diffracting strength of the peak structure of the 110 surface at an angle of 10 degrees of the 2 theta angle in the XRD diffracting plot is obviously stronger than that of the glass drying agent in a 3A-type molecular sieve, thus, the novel drying agent only absorbs water and little O2 but not N2 and has the property of excellent type selectivity and selective absorption.

Description

technical field [0001] The invention belongs to an inorganic microporous new material desiccant. Background technique [0002] Hollow glass doors and windows are used in transportation tools such as vehicles and ships and fixed buildings, which is a great initiative for human beings to save energy and protect the environment. Especially in today's global energy shortage situation, this energy-saving building material product has broad application and development prospects, especially in my country's energy supply and development lag far behind the speed of economic development. Workers have a living room, and vigorously promote energy-saving building materials and energy-saving buildings, which have important social and economic benefits in the economic construction and development of energy conservation and emission reduction, and green and environmental protection industrial chains. [0003] Reducing the energy consumption of the inner and outer walls of buildings, improvi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/28B01J20/18E06B7/12
Inventor 孙玉坤杜军金雷邓少亮
Owner DALIAN HAIXIN CHEM IND
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