Synthesized micromolecule compound capable of conveying bioactivator and application thereof
A technology of biologically active substances and small molecule compounds, applied in the field of small molecule compounds, can solve the problems of oral delivery of hydrophilic macromolecular drugs, unreachable, poor stability, etc., achieve convenient oral administration, improve absorption rate, The effect of improving stability
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[0033] (1) Examples of Preparation Methods of Small Molecular Compounds
[0034]
[0035] Preparation of compound 5: 1-(3-dimethylaminopropyl)-3-ethyl Carbodiimide hydrochloride (1.0 equivalents) and 4-dimethylaminopyridine (2 equivalents), the solution was stirred at 0°C for 20 minutes, and the solution was added to the solution containing methyl 4-aminobutyrate (1.0 equivalents). ) in dichloromethane (10 mL), after addition, the reaction mixture was gradually warmed to room temperature and stirred at room temperature for 12 hours.
[0036] The solution was transferred to a separatory funnel, washed with 1 N hydrochloric acid solution (2×20 ml), water (2×20 ml), saturated sodium bicarbonate solution (2×20 ml), and saturated brine (40 ml) respectively, It was dried over anhydrous magnesium sulfate, filtered, and concentrated in vacuo. Subsequently, the residue was dissolved in tetrahydrofuran (30 mL) and sodium hydroxide solution (2 eq.) was added. The mixture was stirre...
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