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A combined binder for preparing silicon carbide powder sintered porous body and its application method

A silicon carbide powder and binder technology, applied in the chemical field, can solve the problems of high strength, high temperature resistance, and low bonding strength of silicon carbide porous bodies, and achieve easy removal at low temperature, good high temperature resistance, and high The effect of intensity

Inactive Publication Date: 2011-12-14
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The binder can solve the problem of low bonding strength of aluminum metaphosphate in the process of pressing and forming at room temperature, so that the silicon carbide powder compact has higher strength in the process of pressing and forming, and the silicon carbide porous body formed after sintering has high strength. Good high temperature resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Dissolve aluminum hydroxide powder in 85% concentrated phosphoric acid at 140°C to obtain aluminum metaphosphate with a phosphorus-to-aluminum ratio of 23, add water and dilute to 5000 ml to obtain an aluminum metaphosphate solution with a concentration of 0.007 g / ml, add it to 7000 g In 10μm silicon carbide powder, stir evenly, dry at 200°C for 24 hours, pass through a 200 mesh sieve, add 1000 ml of polyvinyl alcohol aqueous solution with a concentration of 0.14 g / ml, grind evenly, dry at 80°C for 24 hours, and sieve (200 In order to obtain a silicon carbide porous body, it was sintered at 800° C. for 3 h after compression molding.

Embodiment 2

[0014] Dissolve aluminum hydroxide powder in 85% concentrated phosphoric acid at 140°C to obtain aluminum metaphosphate with a phosphorus-aluminum ratio of 23, add water and dilute to 5000 ml to obtain an aluminum metaphosphate solution with a concentration of 0.014 g / ml, add it to 7000 g In 10μm silicon carbide powder, stir evenly, dry at 200°C for 24 hours, pass through a 200 mesh sieve, add 1000 ml of polyvinyl alcohol aqueous solution with a concentration of 0.105 g / ml, grind evenly, dry at 80°C for 24 hours, and sieve (200 mesh), after compression molding, sintering at 800°C for 3h to obtain porous SiC

Embodiment 3

[0016] Dissolve aluminum hydroxide powder in 85% concentrated phosphoric acid at 140°C to obtain aluminum metaphosphate with a phosphorus-to-aluminum ratio of 23, add water and dilute to 5000 ml to obtain an aluminum metaphosphate solution with a concentration of 0.028 g / ml, add it to 7000 g In 10μm silicon carbide powder, stir evenly, dry at 200°C for 24 hours, pass through a 200 mesh sieve, add 1000 ml of polyvinyl alcohol aqueous solution with a concentration of 0.07 g / ml, grind evenly, dry at 80°C for 24 hours, and sieve (200 mesh), and then sintered at 800°C for 3 hours to obtain a silicon carbide porous body.

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PUM

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Abstract

The invention discloses a combined binder for preparing a silicon carbide powder sintered porous body and a use method thereof. The combined binder is composed of aluminum metaphosphate and polyvinyl alcohol. The method of using the combined binder is as follows: firstly add an aqueous solution of aluminum metaphosphate with a concentration of 0.007-0.056 g / ml to the silicon carbide powder, dry at 200°C and sieve, then add a solution with a concentration of 0.035-0.14 g / ml polyvinyl alcohol aqueous solution, dried at 80°C, sieved, molded, and sintered to obtain a silicon carbide porous body; the added amount of aluminum metaphosphate is 0.5-4wt% of silicon carbide powder, and the added amount of polyvinyl alcohol It is 0.5-2wt% of silicon carbide powder. The obtained silicon carbide molded billet has a smooth surface and good molding quality. After sintering at 800°C for 3 hours, the obtained silicon carbide porous body has high strength and good high temperature resistance.

Description

technical field [0001] The invention relates to a combined binder for preparing a silicon carbide powder sintered porous body and a use method thereof, belonging to the field of chemistry. Background technique [0002] Silicon carbide porous body has the characteristics of high specific surface area, high temperature resistance, corrosion resistance, high porosity, high strength and wear resistance, etc. It can be widely used in many industrial fields such as catalyst carrier, fluid purification, filtration, etc. Skeleton structure of composite materials. However, pure silicon carbide has a high sintering temperature and is difficult to sinter. In order to sinter at a lower temperature, it is usually necessary to add silicon dioxide or sodium silicate as a binder. When silica is used as a binder, the strength of the silicon carbide porous body is low; when sodium silicate is used as a binder, it is easy to diffuse to the surface layer with water during the drying process of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/565C04B35/63C04B38/00
Inventor 陈康华祝昌军方华婵彭国胜
Owner CENT SOUTH UNIV