Isocyanate alkyl substituted cyclohexane and preparation method as well as application thereof

A technology of isocyanate and cyclohexane, which is applied in the field of cyclohexane preparation, can solve the problems of harsh process conditions, difficult industrialization, high toxicity, etc.

Active Publication Date: 2010-08-04
浙江优创材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage of the phosgene method is that the process conditions are harsh, the toxicity is high, it is not easy to industrialize, the yield is low, the side reaction is easy to occur, and it brings inconvenience to the post-treatment, such as the reaction between the generated isocyanate and the raw material amine

Method used

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  • Isocyanate alkyl substituted cyclohexane and preparation method as well as application thereof
  • Isocyanate alkyl substituted cyclohexane and preparation method as well as application thereof
  • Isocyanate alkyl substituted cyclohexane and preparation method as well as application thereof

Examples

Experimental program
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Effect test

preparation example Construction

[0129] In one embodiment of the preparation method of the second aspect of the present invention, the following steps are adopted: add xylene in the hydrogenation autoclave, then add Pd (5%) / activated carbon catalyst, add dimer acid, and the amount of dimer acid in the mixture The concentration is 10-50% based on the total amount of solvent, and the weight ratio of dimer acid to palladium is 99:1, heated to 150-200°C, reacted at 1.5-2.0MPa for 6 hours, after the hydrogenation absorption is completed, cool down and stop Stir, filter the catalyst, apply mechanically, and dry the reaction mixture.

[0130] Add more than 1.05mol of acyl chloride agent to the above dried reaction mixture, react at 20-70°C for 6-8 hours, and distill off unreacted acyl chloride agent.

[0131] Add 2.2 moles of sodium azide to the above reaction mixture from which the acyl chlorination agent has been removed, react at 80° C. for 16 hours, and filter out the generated sodium chloride.

[0132] The rea...

specific Embodiment approach

[0137] The present invention is further illustrated below through specific intermediates and examples, but it should be understood that these intermediates and examples are only used for more detailed description, and should not be interpreted as being used to limit the present invention in any form. invention.

[0138] The present invention provides general and / or specific descriptions of the materials and test methods used in the tests. While many of the materials and methods of manipulation which are employed for the purposes of the invention are well known in the art, the invention has been described here in as much detail as possible. It will be clear to those skilled in the art that in the following, unless otherwise specified, the materials and operation methods used in the present invention are well known in the art. In particular, the dimer acid of the starting material formula Ia-1 or Ib-1 used in the present invention is prepared by Diels-Alder reaction with octade...

Embodiment 1

[0139] Embodiment 1,1-pentyl-2-heptyl-3, the preparation of 4-two (8-isocyanate octyl)-cyclohexane

[0140] Raw materials: dimer acid is a dimer acid of the following structure:

[0141]

[0142] step 1: Put 350g xylene and 30g Pd (5%) / activated carbon catalyst (wet: dry weight 15g, 0.45g Pd) suspension into 2 liters of hydrogenation autoclave, then add 320g dimer acid (98%), draw separately Vacuum, nitrogen replacement, hydrogen replacement. The reaction mixture was stirred at 170-190° C., 1.5-2.0 Mp for about 7.5 hours, until the hydrogen absorption was complete, and the stirring was stopped. The material was filtered off under nitrogen pressure, leaving the catalyst in the filter. Use 350g xylene to backwash the catalyst into the reactor, add 320g dimer acid, repeat the hydrogenation, the catalyst activity does not decrease, carry out the hydrogenation 5 times in the same way, and reuse the catalyst 4 times, the obtained reaction mixture Heated and dehydrated to ob...

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Abstract

The invention relates to a compound shown in formula Ia or Ib, wherein one of p and q is equal to 0, and the other one of p and q is equal to 1; m and y are respectively equal to integers from 0 to 12 independently, and the sum of m and y is equal to 12; and n and x are respectively equal to integers from 0 to 12 independently, and the sum of n and x is equal to 12. The invention also relates to a preparation method of the compound shown in formula Ia or Ib and application of the compound shown in formula Ia or Ib as a component for producing polyurethane lacquer, paint, elastomers, adhesives, textile finishing agents or rocket propellants.

Description

technical field [0001] The present invention relates to isocyanate alkyl-substituted cyclohexane, and the invention also relates to a preparation method of the isocyanate alkyl-substituted cyclohexane and their use. Background technique [0002] Aliphatic isocyanates, such as 1-pentyl-2-heptyl-3,4-bis(9-isocyanate nonyl)-cyclohexane (abbreviated as DDI1410), are used in the production of polyurethane varnishes, coatings, elastomers, adhesives, textiles An important component of finishing agents, rocket propellants, etc. [0003] In the literature that has been retrieved, there are mainly low-molecular-weight fatty acids or amines to prepare corresponding isocyanates, such as 1-pentyl-2-heptyl-3,4-bis(9-isocyanate nonyl)-cyclohexane (DDI1410 ) method, but the phosgene method is generally used for preparation. The disadvantages of the phosgene method are harsh process conditions, high toxicity, difficult industrialization, low yield, prone to side reactions, and inconvenienc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C265/04C07C263/00C09D175/04C09J175/00D06M15/564C08G18/00
Inventor 刘林学王研陈宝绒张海燕赵彬侠
Owner 浙江优创材料科技股份有限公司
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