Multifunctional anti-incrustation corrosion inhibitor and preparation method thereof

A technology of scale and corrosion inhibitor and preparation method, applied in complex/solubilizer treatment and other directions, can solve problems such as single function, inability to use negative hard water, equipment corrosion, etc., and achieve high concentration ratio, water saving and low cost. Effect

Inactive Publication Date: 2011-08-17
HANDAN AOBO WATER TREATMENT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, people need to deal with scaling of industrial circulating cooling water system, heating network system and boiler water under the condition of shutting down and stopping production. The descaling of the former two requires acid cleaning, which not only affects normal production Corrosion of the equipment itself is caused, and the boiler is treated with alkali to soften the scale, which not only has a certain degree of corrosion, but sometimes requires manual hammering and shoveling to remove it, which is time-consuming and laborious
In addition, in the existing water treatment agents, different treatment agents are used to remove scale in different systems, and the functions are single, such as: those with anti-scaling functions have no anti-scaling function, and those with anti-scaling functions have no anti-scaling function. Those used in cooling water cannot be used in heating networks or low-pressure boilers, those used in surface water cannot be used in groundwater, those used in high alkali and high hard water cannot be used in negative hard water, and those used in low concentration ratios cannot be used in high concentration. magnification, etc. Therefore, the existing water treatment agent formulations are varied, causing a lot of inconvenience in the process of use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Add 188L of water to the reaction vessel, weigh 50kg of sodium tripolyphosphate added with phosphates and stir to dissolve, then add 50kg of sulfamic acid with sulfonates and stir to dissolve, and then add phosphonates of aminotrimethyl in the solution. 450kg liquid of ethylene diamine tetramethylene phosphonic acid and 250kg liquid of polycarboxylic acid polyacrylic acid are stirred and mixed, and finally 12kg of azole benzotriazole is added, and the preparation is placed under normal temperature conditions and continuously stirred to obtain Brownish yellow or orange yellow transparent liquid finished product.

[0036] After testing, it meets the standards of DL / T806-2002 "Scale and Corrosion Inhibitor for Circulating Cooling Water of Thermal Power Plants" and SH260407-2003 "Petrochemical Industry". The list is as follows:

[0037] DL / T806-2002 standard

[0038] Test items

[0039] Density (20℃), g / cm 3

[0040] Note: SH260407-2003 "Petrochemical Industry" product indi...

Embodiment 2

[0042] Add 290L of water to the reaction vessel, weigh 100 kg of trisodium phosphate added with phosphates and stir to dissolve, then take 100 kg of alkyl sulfonic acid sulfonates and stir to dissolve, and then add phosphonate ethylene dichloride to the solution. Amine tetramethylene phosphonic acid and hydroxy ethylidene diphosphonic acid 350kg liquid, polycarboxylic acid sodium polyacrylate and hydrolyzed polymaleic anhydride 150kg liquid, stir and mix, and finally add azole methyl benzothiazole 10kg, prepare and store at room temperature Under the conditions, keep stirring evenly to obtain brownish yellow or orange yellow transparent liquid finished product.

Embodiment 3

[0044] Add 392L of water into the reaction vessel, weigh 150kg of sodium tripolyphosphate added with phosphates and stir to dissolve, then add 150kg of sulfonate alkyl sulfonic acid, stir to dissolve, and then add phosphonate aminotrimethyl in the solution 250kg liquid of phosphonium phosphonic acid and hydroxyethylidene diphosphonic acid, 50kg of hydrolyzed polymaleic anhydride of polycarboxylic acid, stir and mix, and finally add 8kg of mercaptobenzothiazole of azoles, prepare and place under normal temperature conditions, keep stirring uniformly, get Brownish yellow or orange yellow transparent liquid finished product.

[0045] The finished products of Examples 2 and 3 are tested to meet the product index standards shown in Example 1 (specific data omitted)

[0046] The product of the present invention tried an industrial production system, and achieved good scale inhibition and descaling effects:

[0047] For example: a coal mine power plant in Shanxi: 2×50mw generator set, the ...

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PUM

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Abstract

The invention discloses a multifunctional anti-incrustation corrosion inhibitor and a preparation method thereof. The multifunctional anti-incrustation corrosion inhibitor is used as a water treatment agent for industrial circulating cooling water, a heating network system and a low-pressure boiler and is prepared from the following components in percentage by mass: phosphate, sulfonate, phosphonate, polycarboxylic acid, azoles and water. The preparation method comprises the following steps of: sequentially adding the components into a reaction vessel at normal temperature, and then stirring,dissolving and mixing to form a finished product. The multifunctional anti-incrustation corrosion inhibitor confirms to the national DL / T806-2002 (electric power) and SH 260407-2003 (petrochemistry) standards of the anti-incrustation corrosion inhibitor for circulating cooling water, can be applied to various water treatment systems and used as the water treatment agent for water with various qualities, and can be directly applied to the water treatment system to play the roles of anti-incrustation, incrustation removal, corrosion mitigation and concentration ratio increase, thereby achievingthe purposes of incrustation prevention and removal as well as water saving.

Description

Technical field [0001] The invention relates to a multifunctional scale and corrosion inhibitor and a preparation method thereof, which are used as a water treatment agent for industrial circulating cooling water, heating network systems and low-pressure boilers. Background technique [0002] At present, people's treatment of industrial circulating cooling water system, heating network system and boiler water scaling needs to be carried out under shutdown or production shutdown. The first two need to be cleaned with acid, which will not only affect normal production, but also It causes the corrosion of the equipment itself, and the boiler is treated with alkali to soften the scale. It is not only corrosive, but sometimes requires manual hammering to remove it, which is time-consuming and labor-intensive. In addition, in the existing water treatment agents, different treatment agents are used to remove scales in different systems, which have a single function, such as: anti-scalin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F5/08
Inventor 董兆祥
Owner HANDAN AOBO WATER TREATMENT
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