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Low-energy electron beam radiation curing coating and use method thereof

A technology of electron beam radiation and curing coating, applied in the direction of coating, etc., can solve the problems of high heat, uneven printing coating, easy deformation of film and so on

Inactive Publication Date: 2010-09-29
恒昌涂料(惠阳)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, during wide-format high-speed printing, UV generates a lot of heat, which makes the printing coating uneven. When printing on some heat-sensitive film and other substrates, the film is easily deformed.
Due to the low energy of UV light-curing coatings during curing, there are many unreacted small molecular monomers left in the cured coating. At the same time, due to the photoinitiator in the formula, there are more migratory components in the coating and the odor is relatively large. , poor film performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] To prepare electron beam curing coatings, 1500 grams of reactive oligomers, epoxy acrylate oligomers, 300 grams of urethane acrylate oligomers, 300 grams of polyester acrylate oligomers, and 1000 grams of reactive monomers Propylene glycol ester TPGDA, 350 grams of trimethylolpropane triacrylate TMPTA, leveling aid 15 grams of silicone copolymer BYK333, stir and mix well.

[0021] Roll coating on the surface of the paper, the thickness of the coating film is about 4 microns, exposure to 150kV electron beam radiation, the dose is about 60kGy, and the sample is cured. The obtained coating has good abrasion resistance, scratch resistance and solvent resistance.

Embodiment 2

[0023] To prepare electron beam curing coatings, reactive oligomers 1500 g methacrylate oligomer, 300 g urethane acrylate oligomer, 300 g polyester acrylate oligomer, reactive monomer 1000 g trimethylol propane triacrylate, 350 grams of trimethylolpropane triacrylate TMPTA, leveling aid 15 grams of silicone copolymer BYK333, stir and mix evenly.

[0024] Roll coating on the surface of the paper, the thickness of the coating film is about 4 microns, exposure to 180kV electron beam radiation, the dose is about 60kGy, and the sample is cured. The obtained coating has good abrasion resistance, scratch resistance and solvent resistance.

Embodiment 3

[0026] To prepare electron beam curing coatings, reactive oligomers 1500 g methacrylate oligomer, 300 g urethane acrylate oligomer, 300 g polyester acrylate oligomer, reactive monomer 1000 g hexyl acrylate 1. 350 grams of trimethylolpropane triacrylate TMPTA, 15 grams of silicone copolymer BYK333 as a leveling aid, stir and mix evenly.

[0027] Roll coating on the surface of the paper, the thickness of the coating film is about 4 microns, exposure to 200kV electron beam radiation, the dose is about 60kGy, and the sample is cured. The obtained coating has good abrasion resistance, scratch resistance and solvent resistance.

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PUM

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Abstract

The invention discloses a low-energy electron beam radiation curing coating, which comprises the following components in percentage by weight: 40-90 percent of reactivity oligomer, 10-60 percent of reactivity monomer, 0.3-5 percent of additive, 0-30 percent of thermoplastic resin, 0-15 percent of photoinitiator and 0-30 percent of pigment and filler. The coating is particularly suitable for coating processing on substrate made of plastic or paper. A use method of the low-energy electron beam radiation curing coating comprises the following steps of: (a) printing at least one layer of the electron beam radiation curing coating on the plastic or paper substrate; (b) radiating the coating by adopting an electron beam of no more than 200+ / -10kV; or repeating the use steps. The coating has low cost and good environment protection property. The coating obtained by using the low-energy electron beam radiation curing coating has good abrasive resistance, scratching resistance and solvent resistance.

Description

technical field [0001] The invention relates to a low-energy electron beam radiation-cured coating and its application method, in particular to a low-energy electron beam radiation-cured coating applied to plastic or paper substrates and its application method. Background technique [0002] Now in the printing industry, UV curing is progressing rapidly. In many low to medium speed narrow web printing applications, light curing UV is a more economical processing method. However, during wide-format high-speed printing, UV generates a lot of heat, which makes the printing coating uneven, and when printing on substrates such as some heat-sensitive films, the film is easily deformed. Due to the low energy of UV light-curing coatings during curing, there are many unreacted small molecular monomers left in the cured coating. At the same time, due to the photoinitiator in the formula, there are more migratory components in the coating and the odor is relatively large. , poor film ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D4/06
Inventor 孙攀峰杨爱军
Owner 恒昌涂料(惠阳)有限公司
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