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Polycarbonate/polyethylene terephthalate resin composition and preparation method

A technology of polyethylene terephthalate and ethylene glycol phthalate, which is applied in the field of polymer resin composition and preparation, can solve the problems of large cost investment, low added value, and low economic benefit, and achieve Good economic and social benefits, excellent mechanical properties and processing properties, reasonable preparation process

Inactive Publication Date: 2010-10-13
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] It can be seen from some of the above schemes that 1) the materials can be made more pure through alcoholysis, hydrolysis, acidolysis and other pyrolysis methods, but there is a large cost investment, and a large amount of waste such as solvents generated during the pyrolysis process will still be discharged. Seriously pollute the environment, and the economic benefits are not high; 2) It is more environmentally friendly to use through direct crushing, but the material performance cannot be guaranteed well, which affects later use, and can only be used for low-end products, and the economic benefits are not good; 3) Through crushing Simple modifications such as chain extension and enhancement also have mediocre product performance and can only be used in some low-end fields with low added value
4) Selective dissolution and purification, this scheme also has a large amount of waste discharge, and there will be a certain molecular weight reduction during the purification process, which will affect its later use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0032] A preparation method of polycarbonate / polyethylene terephthalate resin composition, the method may further comprise the steps:

[0033] (1) Material composition

[0034] Component A: waste polycarbonate (PC), recycled PC drinking buckets and PC sheets from the consumer market, thoroughly cleaned and broken;

[0035] Component B: waste polyethylene terephthalate (PET), recycled PET bottles from the consumer market, thoroughly washed and shredded;

[0036] Component C: impact modifier EXL2691A from Rohmhaas;

[0037] Component D: chain extender SAN-g-GMA, wherein GMA content is 5%, molecular weight is 50000, self-made;

[0038] Component E: Processing aids, including lubricant pentaerythritol stearate (PETS), phosphite antioxidant IRGAFOS 168. Hindered phenol IRGANOX245, triphenyl phosphite (TPP-i) and silicone mold release agent Dow Corning MB-50, the weight ratio of which is 2:2:2:1:1, the content of each component is shown in Table 1 shown.

[0039] (2) Use a ch...

Embodiment 5

[0061] A preparation method of polycarbonate / polyethylene terephthalate resin composition, the method may further comprise the steps:

[0062] (1) Prepare raw materials according to the following components and contents: waste polycarbonate resin (PC) 60kg, waste polyethylene terephthalate (PET) 30kg, impact modifier 4kg, chain extender 0.5kg, processing Auxiliary 0.1kg, of which waste polycarbonate resin comes from the consumer market, which is recycled PC drinking bucket, and has been thoroughly cleaned and broken; waste polyethylene terephthalate resin comes from the consumer market, which is recycled PET film After thorough cleaning and crushing, the impact modifier is bulk ABS, and the chain extender is a terpolymer of aromatic vinyl monomer, acrylonitrile monomer and glycidyl methacrylate (GMA). Auxiliary agent is lubricant pentaerythritol stearate and antioxidant 168, and the weight ratio is 1: 2;

[0063] (2) Use a chain extender to carry out chain extension granulati...

Embodiment 6

[0065] A preparation method of polycarbonate / polyethylene terephthalate resin composition, the method may further comprise the steps:

[0066] (1) Prepare raw materials according to the following components and contents: waste polycarbonate resin (PC) 75kg, waste polyethylene terephthalate (PET) 20kg, impact modifier 15kg, chain extender 1.5kg, processing Auxiliary 1.5kg, of which the waste polycarbonate resin comes from the consumer market, which is a recycled PC drinking bucket, which has been thoroughly cleaned and broken, and the waste polyethylene terephthalate resin comes from the consumer market, which is a recycled PET film And thoroughly cleaned and broken, the impact modifier is ACR, ASA, the weight ratio is 1:1, the chain extender is aromatic vinyl monomer, acrylonitrile monomer and glycidyl methacrylate (GMA) copolymerized The terpolymer formed, the processing aid is transesterification inhibitor phosphite, release agent silicone powder and colorant Fe 2 o 3 Red,...

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PUM

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Abstract

The invention relates to a polycarbonate / polyethylene terephthalate resin composition and a preparation method, the composition comprises the following components by weight percent (wt%): 60-75% of waste polycarbonate resin (PC), 20-30% of waste polyethylene terephthalate (PET), 4-15% of impact modifier, 0.5-1.5% of chain extender and 0.1-1.5% of processing aids, the chain extender is used for carrying out chain extension and granulation on the waste PC and the waste PET, then the PC and the PET after the chain extension, the impact modifier and the processing aids are pre-mixed in a high-speed mixer and then melted and extruded through a twin-screw extruder, and cooling and granulation are finally carried out for obtaining a product. The preparation process is reasonable, the chain extension is carried out on the waste PC material and the waste PET material, and then the alloying technology is further used for modification, thereby having excellent performances and simultaneously having short production cycle and low cost; furthermore, the whole process is more environment-friendly and has better economic benefits and social benefits.

Description

technical field [0001] The invention relates to a polymer resin composition and a preparation method, in particular to a polycarbonate / polyethylene terephthalate resin composition and a preparation method. Background technique [0002] PET (polyethylene terephthalate) resin is widely used to produce PET bottles, PET films and the like. With the improvement of human living standards, these PET bottles and PET films are used in large quantities and discarded after use, thereby causing serious environmental pollution. From the perspective of energy saving and environmental protection, developed countries such as Europe and the United States have carried out a lot of research and development on the recycling of PET resin, and domestic research and development in this area have also begun in recent years. There are many ways to recycle PET. 1) By alcoholysis, hydrolysis, acidolysis and other methods, PET waste resin is cracked into low-molecular compounds, which are used as poly...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L67/02C08L51/00C08K13/02
Inventor 罗明华李辉陈伶李文强李荣群辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS
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