Polycarbonate/polyethylene terephthalate resin composition and preparation method
A technology of polyethylene terephthalate and ethylene glycol phthalate, which is applied in the field of polymer resin composition and preparation, can solve the problems of large cost investment, low added value, and low economic benefit, and achieve Good economic and social benefits, excellent mechanical properties and processing properties, reasonable preparation process
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Embodiment 1-4
[0032] A preparation method of polycarbonate / polyethylene terephthalate resin composition, the method may further comprise the steps:
[0033] (1) Material composition
[0034] Component A: waste polycarbonate (PC), recycled PC drinking buckets and PC sheets from the consumer market, thoroughly cleaned and broken;
[0035] Component B: waste polyethylene terephthalate (PET), recycled PET bottles from the consumer market, thoroughly washed and shredded;
[0036] Component C: impact modifier EXL2691A from Rohmhaas;
[0037] Component D: chain extender SAN-g-GMA, wherein GMA content is 5%, molecular weight is 50000, self-made;
[0038] Component E: Processing aids, including lubricant pentaerythritol stearate (PETS), phosphite antioxidant IRGAFOS 168. Hindered phenol IRGANOX245, triphenyl phosphite (TPP-i) and silicone mold release agent Dow Corning MB-50, the weight ratio of which is 2:2:2:1:1, the content of each component is shown in Table 1 shown.
[0039] (2) Use a ch...
Embodiment 5
[0061] A preparation method of polycarbonate / polyethylene terephthalate resin composition, the method may further comprise the steps:
[0062] (1) Prepare raw materials according to the following components and contents: waste polycarbonate resin (PC) 60kg, waste polyethylene terephthalate (PET) 30kg, impact modifier 4kg, chain extender 0.5kg, processing Auxiliary 0.1kg, of which waste polycarbonate resin comes from the consumer market, which is recycled PC drinking bucket, and has been thoroughly cleaned and broken; waste polyethylene terephthalate resin comes from the consumer market, which is recycled PET film After thorough cleaning and crushing, the impact modifier is bulk ABS, and the chain extender is a terpolymer of aromatic vinyl monomer, acrylonitrile monomer and glycidyl methacrylate (GMA). Auxiliary agent is lubricant pentaerythritol stearate and antioxidant 168, and the weight ratio is 1: 2;
[0063] (2) Use a chain extender to carry out chain extension granulati...
Embodiment 6
[0065] A preparation method of polycarbonate / polyethylene terephthalate resin composition, the method may further comprise the steps:
[0066] (1) Prepare raw materials according to the following components and contents: waste polycarbonate resin (PC) 75kg, waste polyethylene terephthalate (PET) 20kg, impact modifier 15kg, chain extender 1.5kg, processing Auxiliary 1.5kg, of which the waste polycarbonate resin comes from the consumer market, which is a recycled PC drinking bucket, which has been thoroughly cleaned and broken, and the waste polyethylene terephthalate resin comes from the consumer market, which is a recycled PET film And thoroughly cleaned and broken, the impact modifier is ACR, ASA, the weight ratio is 1:1, the chain extender is aromatic vinyl monomer, acrylonitrile monomer and glycidyl methacrylate (GMA) copolymerized The terpolymer formed, the processing aid is transesterification inhibitor phosphite, release agent silicone powder and colorant Fe 2 o 3 Red,...
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