Method and device for accelerating powder method boronisation by alternating-current filed

A technology of alternating electric field and powder method, which is applied in the field of chemical heat treatment on the surface of metal parts. It can solve the problems of low utilization rate of boron supply agent, increase the difficulty of cleaning parts after infiltration, and affect the surface quality of parts. Simplicity and the effect of improving utilization rate

Inactive Publication Date: 2011-08-31
CHANGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The boron donors such as boron carbide and ferroboron used in the current process are expensive, but only part of the reaction is consumed in one boronizing treatment
In order to overcome the problem of low utilization rate of boron supplying agent, at present, it is generally used to add activator and infiltration catalyst to the old boronizing agent, and then use the boronizing agent in an appropriate proportion to increase the boron supplying agent. The utilization rate of the boronizing agent, but due to the decomposition products of some activators and infiltrating agents in the boronizing agent, the infiltration agent is compacted. The more repetitions, the more serious the compaction. The use of old infiltration agents will increase the difficulty of cleaning the parts after infiltration, and will also affect The surface quality of the parts, it is not suitable to use the old penetrating agent for multiple times
[0005] In addition, the generation of active boron atoms in the current solid powder boronizing is caused by the thermal decomposition and mutual reaction of the infiltrating agent under the action of high temperature. In order to increase the penetration rate and obtain a thick penetration layer, the current process adopts high temperature, high proportion of boron supply agent, adding penetration accelerator, prolonging the holding time, etc., not only the utilization rate of penetration agent is not high, At the same time, there are disadvantages such as high processing temperature, long processing time, and high cost.

Method used

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  • Method and device for accelerating powder method boronisation by alternating-current filed
  • Method and device for accelerating powder method boronisation by alternating-current filed

Examples

Experimental program
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Effect test

Embodiment 1

[0018] Material to be infiltrated: 45 steel; composition of boronizing agent: boron donor (iron boron, content 6%), activator and infiltration agent (potassium fluoroborate, 5%), loosening agent (charcoal, 2%), filler and activator (silicon carbide, balance).

[0019] Place two plate electrodes (6), (8) in parallel in the solid powder boronizing agent (5) composed of the above substances, and the distance between the infiltrated sample (7) and the electrodes (6), (8) on both sides is 15mm , the two electrodes (6), (8) are respectively connected to a 50Hz AC power system (9) whose voltage is continuously adjustable in the range of 0-250 volts by wires (4), and the plate electrodes (6), (8) and The infiltrated sample (7) and the powder boronizing agent (5) are sealed in the infiltration box (3) with the infiltration box cover (1) by the refractory mud sealing material (2), and the infiltration box is placed in the box furnace Heating, boronizing temperature: 800°C, when the fur...

Embodiment 2

[0022] Material to be infiltrated: 20 steel; composition of boronizing agent: boron donor (iron boron, content 3%), activator and infiltration agent (potassium fluoroborate, 5%;), loosening agent (charcoal, 2%), filler agent and activator (silicon carbide, balance).

[0023] The boronizing method and device are the same as in Example 1. The boronizing temperature is 800° C., the boronizing time is 4 hours, the distance between the sample to be infiltrated and the plate electrodes on both sides is 10 mm, and an AC electric field of 30 volts is applied between the plate electrodes. Test results: 20 steel has a boronizing layer of 90μm, and its hardness is 1200-1500HV 0.1 ; while using the same formulation of infiltrating agent, using the existing conventional powder method boronizing process, also after boronizing at 800 ° C for 4 hours, the thickness of the boronizing layer is only 20 μm.

Embodiment 3

[0025] Material to be infiltrated: 45 steel; composition of boronizing agent: boron donor (boron carbide, content 3%), activator and infiltration agent (potassium fluoroborate, 5%; ammonium chloride; 1%), loosening agent (charcoal , 2%), fillers and activators (silicon carbide, the balance).

[0026] The boronizing method and device are the same as in Example 1, the boronizing temperature is 600° C., and the boronizing time is 4 hours. The distance between the infiltrated sample and the plate electrodes on both sides is 10 mm, and an alternating electric field of 50 volts is applied between the plate electrodes and the infiltrated sample. Test results: 45 steel obtained a 30μm boronizing layer with a hardness of 1100-1500HV 0.1 ; while using the same formulation of infiltrating agent, using the existing conventional powder method boronizing process, the same boronizing at 600 ° C for 4 hours, basically no boronizing layer is formed on 45 steel.

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Abstract

The invention discloses a method and a device for accelerating powder method boronisation by an alternating-current filed and used for strengthening the surface of a metal part. Two parallel plate-shaped electrodes are placed in powdered boronizing agent and by leads, the two electrodes are respectively connected on a 50Hz alternating current power supply of which the voltage is continuously adjustable within the range of 0-250V; a treated part is positioned between the two electrodes; the electrodes and the part are sealed together with the boronizing agent in a boronisation box and placed in a heat treatment furnace to heat; after the temperature of the furnace achieves a set value, appropriate alternating voltage is applied between the two electrodes; and then the rapid boronisation of the part can be realized. Compared with the existing method, the method of the invention has the advantages that the boronisation can be accelerated by at least 0.3-3 times and the usage amount of the boronizing agent is reduced by above 70%. Therefore, the method and the device can accelerate the powder method boronisation of the metal part, improve the utilization rate of the boronizing agent, lower the temperature of boronisation and reduce deformation of the part.

Description

technical field [0001] The invention belongs to a method and a device for chemical heat treatment on the surface of a metal part, in particular to a method and a device for boronizing by an AC electric field accelerated powder method for strengthening the surface of a metal part. Background technique [0002] Boronizing is a chemical heat treatment process that infiltrates boron into the surface of metal workpieces. The boronizing layer has high hardness and wear resistance, as well as certain high-temperature oxidation resistance and corrosion resistance, so boronizing parts have a wide range of applications. Boronizing can be divided into solid, salt bath, electrolytic and vapor phase boronizing methods. [0003] At present, the most widely used solid powder method boronizing (referred to as powder method boronizing) is generally high-temperature boronizing at 850-950°C according to the performance requirements of the parts and the material of the parts. The commonly used...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C8/68
Inventor 谢飞孙力
Owner CHANGZHOU UNIV
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